Alexander Mikkelsen

Effective concealment in natural backgrounds is an important capability in the animal kingdom and warfare alike. The main purpose of camouflage is to blend in with the environment and attract a minimum of attention from any given observer or sensor. Effective camouflage is normally achieved through matching with the characteristic background, resulting in minimized contrasts between camouflage materials and natural constituents in the background of relevance. Spectrally, this means reducing material contrast to the background by capturing the background reflectance and transmittance properties, ensuring that the camouflage material and the background reflects and transmits light similarly over any relevant wavelength range.^{1 – 5} Spatial matching with the background is normally ensured through frequency and orientation optimization.^{5 – 10}

Droplets covered with densely packed solid particles, often called Pickering droplets, are used in a variety of fundamental studies and practical applications. For many applications, it is essential to understand the mechanics of such particle-laden droplets subjected to external stresses. Several research groups have studied theoretically and experimentally the deformation, relaxation, rotation, and stability of Pickering droplets. Most of the research concerns spherical Pickering droplets. However, little is known about non-spherical Pickering droplets with arrested particle shells subjected to compressive stress. The experimental results presented here contribute to filling this gap in research. We deform arrested non-spherical Pickering droplets by subjecting them to electric fields, and study the effect of droplet geometry and size, as well as particle size and electric field strength, on the deformation and yielding of arrested non-spherical Pickering droplets. We explain why a more aspherical droplet and/or a droplet covered with a shell made of larger particles required higher electric stress to deform and yield. We also show that an armored droplet can absorb the electric stress differently (i.e., through either in-plane or out-of-plane particle rearrangements) depending on the strength of the applied electric field. Furthermore, we demonstrate that particle shells may fail through various crumpling instabilities, including ridge formation, folding, and wrinkling, as well as inward indentation.

Electrically insulating objects immersed in a weakly conducting liquid may Quincke rotate when subjected to an electric field. Experimental and theoretical investigations of this type of electrorotation typically concern rigid particles and particle-free droplets. This work provides the basic features of electric field-induced rotation of particle-covered droplets that expand the current knowledge in this area. Compared to pure droplets, we show that adding particles to the droplet interface considerably changes the parameters of electrorotation. We study in detail deformation magnitude (D), orientation (β) and rotation rate (ω) of a droplet subjected to a DC E-field. Our experimental results reveal that both the critical electric field (for electrorotation) and the rotational rate depend on droplet size, particle shell morphology (smooth vs. brush-like), and composition (loose vs. locked particles). We also demonstrate the importance of the electrical parameters of the surface particles by comparing the behavior of droplets covered by (insulating) polymeric particles and droplets covered by (non-ohmic) clay mineral particles. The knowledge acquired from the electrorotation experiments is directly translated into practical applications: (i) to form arrested droplets with shells of different permeability; (ii) to study solid-to-liquid transition of particle shells; (iii) to mix particles on shells; and (iv) to increase the formation efficiency of Pickering emulsions.

Similar to the human skin, a monolayer of packed particles capillary bound to a liquid interface wrinkles when subjected to compressive stress. The induced wrinkles absorb the applied stress and do not disappear unless the stress is removed. Experimental and theoretical investigations of wrinkle formation typically concern flat particle monolayers subjected to uniaxial stress. In this work, we extend the results on wrinkling of particle-covered interfaces to the investigation of mechanical properties of particle films on a curved interface, that is, we study particle shells formed on droplets and subjected to hoop stress. Opposed to flat particle layers where liquid buoyancy alone acts as the effective stiffness, the mechanical properties of particle layers on small droplets are also affected by the surface curvature. We show here that this leads to formation of wrinkles with different characteristic wavelengths compared to those found at flat interfaces. Our experimental results also reveal that the wrinkle wavelength of particle shells is proportional to the square root of particle size and the size of the droplets on which the shells are formed. Wrinkling of particle layers composed of microparticles with diameters ranging from around 1–100 μm was induced using a novel approach combining electrodeformation and electrohydrodynamic flows. We demonstrate that our contactless approach for studying the mechanical properties of particle shells enables estimation of elasticity, particle film thickness, and bending stiffness of particle shells. The proposed approach is insensitive to both particle coverage and electric field strength. In addition, it enables manipulation of particle packing that is intimately linked with formation of wrinkling patterns. With a wide range of applications depending on accurate mechanical properties (e.g., drug-delivery capsules to self-healing materials), this work provides a valuable method to characterize the mechanical properties of shells and tailor their surface properties (i.e., permeability and roughness).

Utilizing electric fields, we have experimentally investigated the mechanics of particle-covered silicone oil drops suspended in castor oil, as well as particle assembly at drop surfaces.

Being able to systematically modify the electric properties of nano- and microparticles opens up new possibilities for the bottom-up fabrication of advanced materials such as the fabrication of one-dimensional (1D) colloidal and granular materials. Fabricating 1D structures from individual particles offers plenty of applications ranging from electronic sensors and photovoltaics to artificial flagella for hydrodynamic propulsion. In this work, we demonstrate the assembly of 1D structures composed of individual microparticles with modified electric properties, pulled out of a liquid environment into air. Polystyrene particles were modified by sulfonation for different reaction times and characterized by dielectric spectroscopy and dipolar force measurements. We found that by increasing the sulfonation time, the values of both electrical conductivity and dielectric constant of the particles increase, and that the relaxation frequency of particle electric polarization changes, causing the measured dielectric loss of the particles to shift towards higher frequencies. We attributed these results to water adsorbed at the surface of the particles. With sulfonated polystyrene particles exhibiting a range of electric properties, we showed how the electric properties of individual particles influence the formation of 1D structures. By tuning applied voltage and frequency, we were able to control the formation and dynamics of 1D structures, including chain bending and oscillation.

Different natural clay minerals, including halloysite, montmorillonite and kaolinite, have been proven to be efficient drug carriers providing for high and long lasting drug concentrations owing to their adsorption capacity and ion exchange property. Synthetic clays, however, are advantageous over the natural clay minerals in terms of purity of composition and controllable cation exchange capacity, factors that contribute to improve reproducibility of the host system. Here we studied a synthetic smectite clay as a candidate for high adsorption and controlled release rate. Via X-ray powder diffraction we verified that, under acidic conditions, the antibiotic ciprofloxacin was successfully incorporated in the synthetic clay fluorohectorite, while via UV-VIS spectroscopy we showed that the degree of the drug incorporation is at least 25% higher than for other systems reported in the literature. Furthermore, temperature dependent release studies allowed us to show that the release process is thermally activated and diffusion-controlled. Finally, via bacterial and toxicological tests, we demonstrated that the effectiveness and toxicity of pure ciprofloxacin is unaffected in the clay–drug complex.

Fluid drops coated with particles, so-called Pickering drops, play an important role in emulsion and capsule applications. In this context, knowledge of mechanical properties and stability of Pickering drops are essential. Here we prepare Pickering drops via electric field-driven self-assembly. We use direct current (DC) electric fields to induce mechanical stress on these drops, as a possible alternative to the use of, for example, fluid flow fields. Drop deformation is monitored as a function of the applied electric field strength. The deformation of pure silicone oil drops is enhanced when covered by insulating polyethylene (PE) particles, whereas drops covered by conductive clay particles can also change shape from oblate to prolate. We attribute these results to changes in the electric conductivity of the drop interface after adding particles, and have developed a fluid shell description to estimate the conductivity of Pickering particle layers that are assumed to be non-jammed and fluid-like. Retraction experiments in the absence of electric fields are also performed. Particle-covered drops retract slower than particle-free drops, caused by increased viscous dissipation due to the presence of the Pickering particle layer.

A designed assembly of particles at liquid interfaces offers many advantages for development of materials, and can be performed by various means. Electric fields provide a flexible method for structuring particles on drops, utilizing electrohydrodynamic circulation flows, and dielectrophoretic and electrophoretic interactions. In addition to the properties of the applied electric field, the manipulation of particles often depends on the intrinsic properties of the particles to be assembled. Here, we present an easy approach for producing polystyrene microparticles with different electrical properties. These particles are used for investigations into electric field-guided particle assembly in the bulk and on surfaces of oil droplets. By sulfonating polystyrene particles, we produce a set of particles with a range of dielectric constants and electrical conductivities, related to the sulfonation reaction time. The paper presents diverse particle behavior driven by electric fields, including particle assembly at different droplet locations, particle chaining, and the formation of ribbon-like structures with anisotropic properties.