Qingyue Yu
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Previous Organizations / Institutes
The organizations / institutes from the scholar's other articles in the past ten years
Research Subjects
Qingyue Yu has a total of 11 co-authors. Here are the top co-authors by number of shared publications:
- Lijun Xue
School of Chemical and Material Engineering, Nanjing Polytechnic Institute, Nanjing 210048, P.R. China
1 shared publication - Mark J. Schulz
Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, OH 45221, USA
1 shared publication - Mark R. Haase
Department of Chemical and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221-0012, USA
1 shared publication - Noe. T. Alvarez
Department of Chemistry, University of Cincinnati, Ohio 45221, United States of America
1 shared publication - Peter Miller
Department of Biomedical, Chemical and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221, USA
1 shared publication - Qingrong Yu
Hailing Middle School of Haian, Nantong 226600, China
1 shared publication
Latest Publications
- Open Access
Selective Synthesis of 1,4-Dioxane from Oxirane Dimerization over ZrO2/TiO2 Catalyst at Low Temperature
We report a route to produce 1,4-dioxane from oxirane by using ZrO2/TiO2 as catalyst. The composite oxide ZrO2/TiO2 was prepared by a coprecipitation method and the catalytic performance was tested through the synthesis of 1,4-dioxane from oxirane in a pipe reactor. The X-ray diffraction (XRD) shows that ZrO2 and TiO2 are in crystal form. When the mass percentage of ZrO2 is 25%, the composite oxide ZrO2/TiO2 presents as an amorphous form. The sample 25%ZrO2/TiO2 exhibits a specific surface area of 269.5 m2·g−1 and pore volume of 1.34 mL·g−1. The catalyst has 670 µmol·g−1 of NH3-TPD acid, and the characterization of ammonia infrared spectroscopy (NH3-FTIR) shows that both Brønsted and Lewis acids are present on the surface of the catalyst. The reaction mechanism was analyzed according to the distribution of product. The test of catalytic performance showed 100.0% conversion of oxirane and 86.2% selectivity of 1,4-dioxane at the optimal operation conditions: atmospheric pressure, reaction temperature 75 °C and gaseous hourly space velocity of 1200.0 h−1. The catalyst exhibits good catalytic performance stability after continuous use for 720 h.
Open AccessSelective Synthesis of 1,4-Dioxane from Oxirane Dimerization over ZrO2/TiO2 Catalyst at Low Temperature
We report a route to produce 1,4-dioxane from oxirane by using ZrO2/TiO2 as catalyst. The composite oxide ZrO2/TiO2 was prepared by a coprecipitation method and the catalytic performance was tested through the synthesis of 1,4-dioxane from oxirane in a pipe reactor. The X-ray diffraction (XRD) shows that ZrO2 and TiO2 are in crystal form. When the mass percentage of ZrO2 is 25%, the composite oxide ZrO2/TiO2 presents as an amorphous form. The sample 25%ZrO2/TiO2 exhibits a specific surface area of 269.5 m2·g−1 and pore volume of 1.34 mL·g−1. The catalyst has 670 µmol·g−1 of NH3-TPD acid, and the characterization of ammonia infrared spectroscopy (NH3-FTIR) shows that both Brønsted and Lewis acids are present on the surface of the catalyst. The reaction mechanism was analyzed according to the distribution of product. The test of catalytic performance showed 100.0% conversion of oxirane and 86.2% selectivity of 1,4-dioxane at the optimal operation conditions: atmospheric pressure, reaction temperature 75 °C and gaseous hourly space velocity of 1200.0 h−1. The catalyst exhibits good catalytic performance stability after continuous use for 720 h.
- Open Access
Mechanical Strength Improvements of Carbon Nanotube Threads through Epoxy Cross-Linking
Individual Carbon Nanotubes (CNTs) have a great mechanical strength that needs to be transferred into macroscopic fiber assemblies. One approach to improve the mechanical strength of the CNT assemblies is by creating covalent bonding among their individual CNT building blocks. Chemical cross-linking of multiwall CNTs (MWCNTs) within the fiber has significantly improved the strength of MWCNT thread. Results reported in this work show that the cross-linked thread had a tensile strength six times greater than the strength of its control counterpart, a pristine MWCNT thread (1192 MPa and 194 MPa, respectively). Additionally, electrical conductivity changes were observed, revealing 2123.40 S·cm−1 for cross-linked thread, and 3984.26 S·cm−1 for pristine CNT thread. Characterization suggests that the obtained high tensile strength is due to the cross-linking reaction of amine groups from ethylenediamine plasma-functionalized CNT with the epoxy groups of the cross-linking agent, 4,4-methylenebis(N,N-diglycidylaniline).
Open AccessMechanical Strength Improvements of Carbon Nanotube Threads through Epoxy Cross-Linking
Individual Carbon Nanotubes (CNTs) have a great mechanical strength that needs to be transferred into macroscopic fiber assemblies. One approach to improve the mechanical strength of the CNT assemblies is by creating covalent bonding among their individual CNT building blocks. Chemical cross-linking of multiwall CNTs (MWCNTs) within the fiber has significantly improved the strength of MWCNT thread. Results reported in this work show that the cross-linked thread had a tensile strength six times greater than the strength of its control counterpart, a pristine MWCNT thread (1192 MPa and 194 MPa, respectively). Additionally, electrical conductivity changes were observed, revealing 2123.40 S·cm−1 for cross-linked thread, and 3984.26 S·cm−1 for pristine CNT thread. Characterization suggests that the obtained high tensile strength is due to the cross-linking reaction of amine groups from ethylenediamine plasma-functionalized CNT with the epoxy groups of the cross-linking agent, 4,4-methylenebis(N,N-diglycidylaniline).