João Freire de Medeiros Neto

Drag is one of the main energy-dissipating phenomena in engineering applications. Drag-reduction mechanisms have been studied to reduce this cost. Superhydrophobic surfaces (SHS) have high water repellency and have been studied as an alternative mechanism for reducing drag. The high level of repellency is due to the hierarchical structures in the micro- and nano-scales, making these surfaces able to trap air layers that impose the condition of slipping. The present work investigated the phenomenon of drag reduction on surfaces made of Sylgard^® 184 elastomer and modified by low-pressure plasma treatments. Atmospheres with 40% Argon and 60% Acetylene, and 20% Argon and 80% Acetylene were used, varying the treatment times from 10 to 15 min of exposure to Acetylene. The surface, morphological and chemical modifications were confirmed by XPS and AFM analyses, showing the impression of a rough structure on the nanometric scale with deposition of chemical elements from the gas plasma. Furthermore, the obtained SHS showed lower resistance to flow, tested by the imposition of flow in channels.

In this work, the plasma was used in the dielectric barrier discharge (DBD) technique for modifying the high-density polyethylene (HDPE) surface. The treatments were performed via argon or oxygen, for 10 min, at a frequency of 820 Hz, voltage of 20 kV, 2 mm distance between electrodes, and atmospheric pressure. The efficiency of the plasma was determined through the triple Langmuir probe to check if it had enough energy to promote chemical changes on the material surface. Physicochemical changes were diagnosed through surface characterization techniques such as contact angle, attenuated total reflection to Fourier transform infrared spectroscopy (ATR-FTIR), X-ray excited photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). Plasma electronics temperature showed that it has enough energy to break or form chemical bonds on the material surface, impacting its wettability directly. The wettability test was performed before and after treatment through the sessile drop, using distilled water, glycerin, and dimethylformamide, to the profile of surface tensions by the Fowkes method, analyzing the contact angle variation. ATR-FTIR and XPS analyses showed that groups and bonds were altered or generated on the surface when compared with the untreated sample. The AFM showed a change in roughness, and this directly affected the increase of wettability.