Hoyoung Jang

The advent of two-dimensional moiré systems has revolutionized the exploration of phenomena arising from strong correlations and nontrivial band topology. Recently, a moiré superstructure formed by two coexisting charge density waves with slightly mismatched wavevectors has been realized. These incommensurate charge density waves can collectively exhibit commensurability, forming a jointly commensurate charge density wave that provides a paradigm for controlling moiré potential and periodicity. Here, we use time-resolved diffraction to probe the light-induced dynamics of the jointly commensurate charge density wave in EuTe ₄ . Our measurements distinguish the instantaneous quenching of its amplitude, as verified by time-resolved photoemission spectroscopy, from the slower evolution of phase fluctuations. Moreover, while the wavevector remains locked upon photoexcitation, the correlation length decreases exclusively perpendicular to the wavevector, revealing the formation of shear-type defects. Together, our multimodal approach reconstructs the temporal evolution of the jointly commensurate charge density wave, highlighting its robustness out of equilibrium and providing insights into the optical manipulation of moiré materials through defect control.

An X-ray ionization beam position monitor (XIBPM) has been developed and evaluated for beam position diagnostics at a soft X-ray free-electron laser (FEL). The redesign was guided by electrostatic simulations and focused on mitigating electric-field distortions near the microchannel plate (MCP) and improving the internal electrode geometry and structural stability. The introduction of a conductive shielding cover effectively suppressed electric-field distortion from the MCP lead, substantially reducing displacement errors and improving measurement stability. A mesh-free electrode structure was also investigated, reducing photo-ion loss and increasing photo-ion transmission; however, under high-intensity FEL operation, the enhanced signal amplitude occasionally led to saturation effects. Beam position measurements were performed at photon energies of 500–1100 eV in both pink-beam and mono-beam modes. Under optimized conditions, a beam position resolution of approximately 24–25 µm was achieved for pulse-by-pulse analysis and improved to approximately 10–12 µm when averaging over ten pulses. The transverse ion profiles were found to be significantly broader than the actual photon beam size, reflecting intrinsic ion-transport dynamics and detector point-spread effects that dominate over the intrinsic photon beam size. These results demonstrate that the shielding cover represents the most significant improvement for accurate and stable beam position monitoring, while the electrode configuration can be selected flexibly depending on the operating regime. The improved XIBPM provides a practical, non-invasive solution for beam position diagnostics in soft X-ray FEL beamlines.

The intricate competition between coexisting charge density waves (CDWs) can lead to rich phenomena, offering unique opportunities for phase manipulation through electromagnetic stimuli. Leveraging time-resolved x-ray diffraction, we demonstrate ultrafast control of a CDW in EuTe_{4} upon optical excitation. At low excitation intensities, the amplitude of one of the coexisting CDW orders increases at the expense of the competing CDW, whereas at high intensities, it exhibits a nonmonotonic temporal evolution characterized by both enhancement and reduction. This transient bidirectional controllability, tunable by adjusting photoexcitation intensity, arises from the interplay between optical quenching and phase-competition-induced enhancement. Our findings, supported by phenomenological time-dependent Ginzburg-Landau theory simulations, not only clarify the relationship between the two CDWs in EuTe_{4}, but also highlight the versatility of optical control over order parameters enabled by phase competition.

In kagome lattice materials, quantum interplay between charge, spin, orbital, and lattice degrees of freedom gives rise to a remarkably rich set of emergent phenomena, ranging from unconventional charge order and superconductivity to topological magnetism. While the exact nature of these exotic orders is often challenging to comprehend in static experiments, time-resolved techniques can offer critical insights by disentangling coupled degrees of freedom on the time-axis. In this work, we demonstrate that the nature of charge orders in two representative kagome metals – nonmagnetic ScV6Sn6 and magnetic FeGe – which has been highly controversial in static studies, can be directly deciphered in the time-domain through their fundamentally distinct order parameter dynamics measured via time-resolved X-ray scattering at an X-ray free electron laser. In nonmagnetic ScV6Sn6, the dynamics are characterized by ultrafast melting and coherent amplitudon oscillations, typical of a phonon-coupled charge order. In stark contrast, magnetic FeGe exhibits resilient metastable charge order dynamics, hitherto unobserved in any other charge-ordered system – this unique time-domain behavior directly signifies an unconventional magnetism-interlocked charge order state realized in this kagome magnet. Our results not only provide a model case where unconventional nature of electronic order, hidden in equilibrium, is directly unraveled in the time-domain, but also pave the way for future out-of-equilibrium engineering of novel quantum orders in kagome lattice platforms.

Optically excited quantum materials exhibit non-equilibrium states with remarkable emergent properties, but these phenomena are usually transient, decaying on picosecond timescales and limiting practical applications. Advancing the design and control of non-equilibrium phases requires the development of targeted strategies to achieve long-lived, metastable phases. Here we report the discovery of symmetry-protected electronic metastability in the model cuprate ladder Sr₁₄Cu₂₄O₄₁. Using femtosecond resonant X-ray scattering and spectroscopy, we show that this metastability is driven by a transfer of holes from chain-like charge reservoirs into the ladders. This ultrafast charge redistribution arises from the optical dressing and activation of a hopping pathway that is forbidden by symmetry at equilibrium. Relaxation back to the ground state is, hence, suppressed after the pump coherence dissipates. Our findings highlight how dressing materials with electromagnetic fields can dynamically activate terms in the electronic Hamiltonian, and provide a rational design strategy for non-equilibrium phases of matter.

The formation of a star-of-David charge density wave superstructure, resulting from the coordinated displacements of vanadium ions on a corner-sharing triangular lattice, has garnered significant attention to comprehend the influence of electron–phonon interaction within geometrically intricate lattice of Kagome metals, specifically AV₃Sb₅ (where A represents K, Rb, or Cs). However, understanding of the underlying mechanism behind charge density wave formation, coupled with symmetry-protected lattice vibrations, remains elusive. Here, from femtosecond time-resolved X-ray scattering experiments, we reveal that the phonon mode, associated with cesium ions’ out-of-plane motion, becomes frustrated in the charge density wave phase. Furthermore, we observed the photoinduced emergence of a metastable charge density wave phase, facilitated by alleviating the frustration. By not only elucidating the longstanding puzzle surrounding the intervention of phonons but introducing the phononic frustration, this research offers insights into the competition between phonons and periodic lattice distortions, a phenomenon widespread in other correlated quantum materials including layered high-temperature superconductors.

The Hubbard model is believed to capture the essential physics of cuprate superconductors. However, recent theoretical studies suggest that it fails to reproduce a robust and homogeneous superconducting ground state. Here, using resonant inelastic x-ray scattering and density matrix renormalization group calculations, we show that magnetic excitations in the prototypical cuprate ladder Sr 14 Cu 24 O 41 are inconsistent with those of a simple Hubbard model. The magnetic response of hole carriers, contributing to an emergent branch of spin-flip excitations, is strongly suppressed. This effect is the consequence of strong d -wavelike pairing, enhanced by nearly an order of magnitude through a large nearest-neighbor attractive interaction and persisting up to at least 260 K. The close connection between the physics of cuprate ladders and that of the two-dimensional compounds suggests that such an enhanced hole pairing may be a universal feature of superconducting cuprates. Published by the American Physical Society 2025

The Pohang Accelerator Laboratory X-ray Free-Electron Laser (PAL-XFEL) operates hard X-ray and soft X-ray beamlines for conducting scientific experiments providing intense ultrashort X-ray pulses based on the self-amplified spontaneous emission (SASE) process. The X-ray free-electron laser is characterized by strong pulse-to-pulse fluctuations resulting from the SASE process. Therefore, online photon diagnostics are very important for rigorous measurements. The concept of photo-absorption and emission using solid materials is seldom considered in soft X-ray beamline diagnostics. Instead, gas monitoring detectors, which utilize the photo-ionization of noble gas, are employed for monitoring the beam intensity. To track the beam position at the soft X-ray beamline in addition to those intensity monitors, an X-ray ionization beam position monitor (XIBPM) has been developed and characterized at the soft X-ray beamline of PAL-XFEL. The XIBPM utilizes ionization of either the residual gas in an ultra-high-vacuum environment or injected krypton gas, along with a microchannel plate with phosphor. The XIBPM was tested separately for monitoring horizontal and vertical beam positions, confirming the feasibility of tracking relative changes in beam position both on average and down to single-shot measurements. This paper presents the basic structure and test results of the newly developed non-invasive XIBPM.