Mayla Alheli Ramos-Vázquez

Sediment geochemistry and 165 detrital zircon grains U–Pb ages are analyzed from the Ventosa beach sediments in the Gulf of Tehuantepec, Mexican Pacific. The objective is to investigate the sediment weathering condition, compositional variations, and to locate the source areas delivering sediments to the coast. Weathering indices reveal a moderate chemical weathering, indicating that the sediments are chemically immature. The SiO2 content (~72–78 wt. %) and the trace element concentrations indicate that the beach sediments are dominantly derived from the felsic igneous rocks. The rare earth element (REE) patterns of the Ventosa sediments are homogeneous and are depleted relative to the average upper continental crust (UCC) values. The environmental indices reveal a “moderately severe enrichment” for Cu content (Enrichment Factor EF = 5.62–8.87; and Geo Accumulation Index Igeo = 1.41–1.98). Anthropogenic enrichment in Pb, Ba, and Zn contents with the possibility of adverse aquatic biota effect is also observed. Th/U ratios in zircon grains are >0.3, indicate an igneous origin. Two major U–Pb age groups are identified i.e. (1) Miocene (~23–12.9 Ma) and (2) Proterozoic (Neoproterozoic: ~999–545 Ma; Mesoproterozoic: ~2549–1006 Ma). These ages suggest that the zircon grains were originated from the nearby source terranes, most likely from the Cenozoic plutons exposed along the southern Oaxaca coastal region, as well as the volcanic and sedimentary rocks of the Todos Santos Formation.

The Salina Cruz and Puerto Ángel beach areas in the Gulf of Tehuantepec, Mexican Pacific coast represent an important economic sector of the region. In this study, the mineralogy and geochemistry of bulk sediments, and geochronology of 400 detrital zircons recovered from the beach sediments were analysed to investigate their origin. The sediments are abundant in quartz, feldspar, ilmenite, cordierite, aragonite and anorthite. The chemical index of weathering revealed a moderate to intense weathering in the source area. The chondrite normalized REE patterns of bulk sediments are similar to the found in the Upper Continental Crust, suggesting the derivation of sediments from felsic igneous rocks. The REE patterns of zircons and the trace elemental ratios reveal a continental crust origin. Zircon U–Pb ages in the Salina Cruz beach were represented by Proterozoic (~545.1–1314.1 Ma; n = 170) and Cenozoic (~0.01–66 Ma; n = 20). The Puerto Ángel beach was abundant in Proterozoic zircon grains (~600.9–1171.4 Ma; n = 109) and followed by Mesozoic grains (~73.78–246.9 Ma; n = 40). The comparison of zircon U–Pb ages of this study with probable source rocks reveals that the Oaxaquia Terrane and Chiapas Massif Complex were the major contributors of Proterozoic zircons to the coastal areas. Similarly, the results indicate that the Cenozoic zircons were contributed by the Chiapas Massif Complex, coastal batholith and Cuicateco Terrane. The Mesozoic zircons are very few, derived from the nearby Xolapa Complex and the Chuacús Terrane.

In this study, we report Scanning Electron Microscopy (SEM) images of quartz grains in the Acapulco beach, Mexican Pacific. The morphology of quartz grains is angular, sub-angular, sub-rounded, rounded, and well-rounded. The variations in the morphology of quartz grains are indicating both nearby and distance sources. The rounded and well-rounded grains support for a long transport distance and a distal source. Microtextures of mechanical and chemical origins are identified in quartz grains. The mechanical features include, bulbous edges (ble), elongated depression (ed), parallel striations, crater, meandering ridges (mr), arcuate steps, conchoidal fractures (cf), v-shaped marks (v-s), and broken grain. These mechanical features indicate the combination of fluvial, aeolian, and subaqueous environments. The conchoidal fractures are characteristic of crystalline rocks. Arcuate steps and meandering ridges are indicating a high wave energy. The striations on grain surfaces are due to collision between two grains, probably during an aeolian transport. The chemical features include adhered particles (ap), solution pit (sp), silica globule, crystal overgrowth (crg), precipitation, and trapped diatoms. The solution pits and precipitation are indicating the diagenetic processes in a silica saturated coastal environment. A few grains are associated with both mechanical and chemical features, suggesting a dual environment, probably littoral and marine. Trapped diatoms identified in quartz grains are Cocconeis guttata and coccolith.

The mineralogy, bulk sediment geochemical composition, and U–Pb ages of detrital zircons retrieved from the Barra del Tordo (Tordo) and Tesoro beach sediments in the northwestern Gulf of Mexico were analyzed to determine their provenance. The beach sediments are mainly composed of quartz, ilmenite, magnetite, titanite, zircon, and anorthite. The weathering proxies such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA), reveal a moderate-to-high intensity of weathering in the source area. The chondrite-normalized rare earth element (REE) patterns are similar to felsic igneous rocks, with large negative europium anomaly (Eu/Eu^* = ~ 0.47–0.80 and ~ 0.57–0.67 in the Tordo and Tesoro beach sediments, respectively).Three major zircon U–Pb age groups are identified in the Tordo and Tesoro beach sediments, i.e., Proterozoic (~ 2039–595 Ma), Mesozoic (~ 244–70.3 Ma), and Cenozoic (~ 65.9–1.2 Ma). The differences of the zircon age spectrum between the Tordo and Tesoro beach sediments are not significant. The comparison of zircon U–Pb ages in this study with ages of potential source terranes suggests that the Mesozoic and Cenozoic zircons of the studied Tordo and Tesoro beach sediments were derived from the Eastern Alkaline Province (EAP) and Mesa Central Province (MCP). Similarly, the likely sources for the Proterozoic zircons were the Sierra Madre Oriental (SMOr) and Oaxaquia in the northwestern Gulf of Mexico. The results of this study further indicate that the sediments delivered to the beaches by rivers and redistributed by longshore currents were crucial in determining the sediment provenance.