Mervat El-Haddad

In this paper, a thorough radio- and chem-ecological evaluation of ElSibai-Abu ElTiyur granites located within Egypt’s crystalline basement rocks was conducted for risk and dose assessments. Twenty granitic samples from the study area’s various lithological units were analyzed using high-resolution γ-ray spectrometry to determine the natural radioisotopes (U-238, Th-232, and K-40) concentrations. The average concentrations of U-238, Th-232, and K-40 were 38.72, 38.23, and 860.71 Bq/kg, respectively, exceeding the GAV (global average value) documented by UNSCEAR (Scientific Committee on the Effects of Atomic Radiation, Vienna, Austria). The radiological parameters and indices judging the usage of ElSibai-Abu ElTiyur granites in homes were computed. The obtained results showed that ElSibai-Abu ElTiyur granites are safe to be used by inhabitants as superficial building materials, as per the globally accepted values and the recommended safety limits approved by UNSEAR, WHO (World Health Organization, Geneva, Switzerland), ICRP (International Commission on Radiological Protection, Ottawa, ON, Canada), and EC (European Commission, Luxembourg). Further, the samples were subjected to ICP-MS (inductively coupled plasma mass spectrometry) analysis for quantifying radionuclide variations with chemical composition. Geochemically based on the ICP-MS results, the studied granites proved to be highly evolved A-type granites. They span the metaluminous to peralkaline fields. The REE patterns are characterized by the enrichment of the light rare earths (LREE) over the heavy ones (HREE) where (La/Yb)_n = 5.2, (Gd/Yb)_n = 1.63 with pronounced negative Eu-anomalies (Eu/Eu*)_n = 0.49. The albite granite exhibits the highest concentrations of Ga, Nb, Ta, U, and Y, and REE (Gd, Dy, Ho, Yb) than the Na-metasomatic granites. Finally, the obtained data serve as a valuable future database for finding out the compatibility of the geochemical data with the natural radioactivity levels of granites.

The naturally occurring radionuclides (radium-226, thorium-232, potassium-40 and radon-222) were investigated in the alkaline rocks of Abu Khuruq Ring, southern Eastern Desert, Egypt. A high-resolution germanium detector was used for the detection of ⁴⁰K, ²³²Th, and ²²⁶Ra (Canberra, GR4020 model) while ²²²Rn concentration was measured by the Alpha-Guard Saphymo GmbH system, model PQ 2000 (AG). Major and rare earth elements (REEs) were assessed using the inductively coupled plasma mass spectrometry and atomic emission spectrometry techniques. Positive correlations were observed between REEs, indicating symmetrical chemical properties and their overall presence in the parent material—also, a positive correlation was observed between effective radium content and radon concentrations pointing to the strong linear dependency between both contents in the studied rocks. The average values of activity concentration of ⁴⁰K, ²³²Th, ²²⁶Ra, and ²²²Rn were less than the suggested level by a factor of 1.38%, 3.16%, 2.09%, and 1.16%, respectively. Significant variations were found among the radiological hazards parameters, e.g., the mean value of the annual effective dose (0.55 mSv y⁻¹) was more than the global reference value (0.41 mSv y⁻¹) by a factor of 1.34. The calculated average value of the gamma index was 0.90, and that of the alpha index was 0.37. H_ex, H_in and Ra_eq showed fewer average values than the standard values of unity and 370 Bq kg⁻¹, respectively.

This paper investigates the distribution of four natural radioisotopes ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K in one hundred twenty-five granitic samples covering sixteen mountainous areas situated at the northern, central and southern parts of the Eastern Desert of Egypt (EDE). The concentrations of the examined radioisotopes in the collected samples were recognized utilizing a HPGe detector based gamma spectrometry. The average concentrations of these radioisotopes were higher when compared with the worldwide reference values. The radiation risk indicators including the radium equivalent activity index (Ra_eq), external and internal hazard indicators (H_ex and H_in), external and internal level indicators (I_α and I_γ), absorbed dose rate (ADR), annual effective dose rate (AEDR), annual gonadal dosage equivalent (AGDE), and excess lifetime cancer risk (ELCR), associated with these radioisotopes have been calculated and compared with their recommended global values and safety limits. These indicators showed that the granites from most studied areas exceeded the universal standards pointing to the difficulty of using them as building materials. This study together with future investigations will serve to develop an essential database for future environmental monitoring surveys.