Enchen Jiang

Bio-oil is a potential source for the production of alternative fuels and chemicals. In this work, Ni-V bimetallic zeolite catalysts were synthesized and evaluated in in situ catalytic hydrodeoxygenation (HDO) of pyrolysis volatiles of pine nut shell for upgraded bio-oil products. The pH and lower heating value (LHV) of the upgraded bio-oil products were improved by in situ catalytic HDO, while the moisture content and density of the oil decreased. The O/C ratio of the upgraded bio-oil products decreased significantly, and the oxygenated compounds in the pyrolysis volatiles were converted efficiently via deoxygenation over Ni-V zeolite catalysts. The highest HDO activity was obtained with NiV/MesoY, where the obtained bio-oil had the lowest O/C atomic ratio (0.27), a higher LHV (27.03 MJ/kg) and the highest selectivity (19.6%) towards target arenes. Owing to the more appropriate pore size distribution and better dispersion of metal active sites, NiV/MesoY enhanced the transformation of reacting intermediates, obtaining the dominant products of phenols and arenes. A higher HDO temperature improved the catalytic activity of pyrolysis volatiles to form more deoxygenated arenes. Higher Ni loading could generate more metal active sites, thus promoting the catalyst’s HDO activity for pyrolysis volatiles. This study contributes to the development of cost-efficient and eco-friendly HDO catalysts, which are required for producing high-quality biofuel products.

A modified γ‐Al₂O₃‐supported nickel‐based Ni/HZSM‐5 catalyst prepared by the impregnation method was characterized by physical adsorption of N₂, X‐ray diffraction, temperature‐programmed desorption of ammonia, thermogravimetric analysis, and scanning electron microscopy. The influence of temperature, pressure, flow, and space velocity on the hydrodeoxygenation (HDO) of light components in bio‐oil was studied, and a lifespan test was performed on the Ni/HZSM‐5‐γ‐Al₂O₃ catalyst. The results showed that at a reaction temperature of 380°C, pressure of 2 MPa, flow rate of 380 ml min⁻¹, and mass space velocity of 0.78 h⁻¹, the hydrocarbon content of the upgraded oil was the highest, reaching 89.49%. Long‐chain alkanes were the main hydrocarbons in the upgraded oil. The results of a lifespan experiment show the good stability of the Ni/HZSM‐5‐γ‐Al₂O₃ catalyst in the HDO of bio‐oil over 5 h of reaction. The HDO reaction pathway of bio‐oil mainly resulted in conversion into long‐chain alkanes through a condensation reaction, a decarbonylation/decarboxylation reaction and hydrogenation. This study provides a reference for the preparation of high‐quality liquid fuels from biomass. [Correction added on June 18, 2021, after first online publication: 89.47% changed to 89.49%]

Background: Biomass fuel has been used to supply heat or crude materials in industry to replace the traditional fossil fuel which was one of the chief causes of climate warming. However, the large-scale utilization of biomass fuel was restricted due to the low density and high hydrophilicity of biomass, which causes the problem of transportation and storage. Therefore, pelletization of biomass was used to improve its fuel density. At present, the biomass pellet was widely used to supply heat, gas or electricity generation via gasification, which supplied clean and sustainable energy for industry. However, the energy consumption during pelletization and high hydrophilicity of pellets were still the problem for the large-scale application of biomass pellet. In this study, hydrothermal carbonization and surfactant played the role of permeation, adsorption and wetting in the solution, which was expected to improve the fuel properties and pelletization effectivity of corn stover. Results: In the article, surfactant (PEG400, Span80, SDBS) was chosen to be combined with wet torrefaction to overcome the drawbacks and improve the pelletization and combustion properties of Corn stover (CS). Especially, hydrothermal carbonization (HTC) combined with surfactant improves the yield of solid products and reduces the ash content of solid product, which was beneficial for reducing the ashes of furnace during gasification. Meanwhile, surfactant promotes the formation of pseudo-lignin and the absorption for oil with low O and high C during HTC, which improves the energy density of solid product. Furthermore, the oil in solid product plays the role of lubricant and binder, which reduces the negative effect of high energy consumption, low bulk density and weak pellets strength caused by HTC during pelletization. HTC combined with surfactant improved the hydrophobicity of pellet as well as grindability due to the modification of solid product. Moreover, surfactant combined with HTC improved the combustion characteristic of solid product such as ignition and burning temperature as well as kinetic parameters due to the bio-oil absorbed and the improvement of surface and porosity. Conclusions: The study supplied a new, less-energy intensive and effective method to improve the pelletization and combustion properties of corn stover via hydrothermal carbonization combined with surfactant, and provided a promising alternative fuel from corn stover .

Torrefaction pretreatment has recently gained attention for the potential improvement in biomass properties. Otherwise, visible image-processing technology for analyzing properties of torrefied biomass was evaluated for possible use in the future online process control. In this study, torrefied rice husk from different torrefaction temperatures (180–330 °C) was obtained. After torrefaction, the biochar was characterized to determine the effects of torrefaction temperature on the properties, including the proximate analysis, solid yield (SY), and higher heating values. In addition, the color values, including red-green-blue (RGB) values, and grayscale (GS) of torrefied rice husk, were measured. The results show that the fixed carbon and ash increased from 17.39 to 35.13 and 7.06 to 38.41%, respectively, while volatile matters decreased from 71.47% to a minimum of 22.89% with the increase of torrefaction temperature from 105 to 330 °C. The SY remained higher than 46% even at the most severe torrefaction condition because of the high ash content and high remaining lignin. Moreover, the higher heating values of torrefied rice husk were increased from 14.80 to 17.82 MJ/kg when increased the pretreatment temperature. RGB values were decreased with the increase of torrefaction temperature. The GS analysis results show that the color of torrefied rice husk changed from yellow to brown at light torrefaction and black at severe torrefaction. GS of torrefied rice husk shows a good correlation (R = 0.9998) with torrefaction temperature. Prediction equations with higher fitting degree between GS and proximate analysis (R² > 0.9900), high heat values (R² = 0.9999), and SY (R² = 0.9979), which are developed to reflect the changing characteristics of torrefied rice husk. The results show that the prediction method based on GS is a promising technology to measure the properties of torrefied rice husk.