Bayan Kaidar
Bayan Kaidar has a total of 49 co-authors. Here are the top co-authors by number of shared publications:
- Gaukhar Smagulova
Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty 050012, Kazakhstan
13 shared publications - Aigerim Imash
Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty 050012, Kazakhstan
11 shared publications - Zulkhair Aimukhametovich Mansurov
Al-Farabi Kazakh National University, Almaty, Kazakhstan
9 shared publications - Aruzhan Keneshbekova
International Chinese-Belorussian Scientiffc Laboratory on Vacuum Plasma Technology, Nanjing University of Science and Technology, 200 Xiaolingwei str., Nanjing 210094, China
5 shared publications - Aidos Lesbayev
Institute of Energy and Mechanical Engineering, Satbayev University, 22a Satpaev Str., Almaty 050013, Kazakhstan
4 shared publications - Ramazan Kazhdanbekov
Faculty of Chemistry and Chemical Technology, Al Farabi Kazakh National University, 71 Al-Farabi Ave., Almaty 050040, Kazakhstan
4 shared publications
Latest Publications
- Open Access
- 14 April 2026
- Published by Royal Society of Chemistry (RSC) in RSC Advances
- Vol. 16 (22) , 20131-20142
Room-temperature chemiresistive CO detection by PANi/GO nanocomposite sensors
Against the backdrop of growing environmental and industrial risks, particularly those associated with toxic CO emissions, the development of highly sensitive gas sensors capable of operating stably at room temperature is of strategic importance.
- 14 April 2026
- Published by Royal Society of Chemistry (RSC) in RSC Advances
- Vol. 16 (22) , 20131-20142
Open AccessRoom-temperature chemiresistive CO detection by PANi/GO nanocomposite sensors
Against the backdrop of growing environmental and industrial risks, particularly those associated with toxic CO emissions, the development of highly sensitive gas sensors capable of operating stably at room temperature is of strategic importance.
- Open Access
- 16 September 2025
- Published by IOS Press
- p. 124-134
Temporal Analysis of Indoor Air Quality Parameters in Metro Systems: A Focus on Diurnal Changes
Air quality in public transportation systems, particularly in subway networks, has become an important factor in passenger health and well-being. The development of advanced monitoring technologies, such as IoT sensors, has enabled the real-time measurement of air quality parameters like CO2, PM2.5, and PM10, allowing for a better understanding of environmental conditions in enclosed spaces. However, the impact of varying passenger density on air quality throughout the day, especially during peak hours, has not been sufficiently studied. This study addresses this gap by comparing air quality measurements in subway stations during peak hours and quieter periods. Here, we show that air quality parameters, including CO2, PM2.5, and PM10, significantly worsen during peak hours due to the higher passenger density, which contrasts with prior assumptions that air quality remains relatively constant throughout the day. These findings expand our understanding of how crowded conditions affect air quality, highlighting the need for more effective air circulation and filtration systems during peak times. This research emphasizes the importance of incorporating real-time air quality monitoring into subway system management to improve health outcomes for passengers and workers. Ultimately, the integration of advanced sensor networks could lead to the development of more efficient, responsive systems for managing air quality in urban transit environments.
- 16 September 2025
- Published by IOS Press
- p. 124-134
Open AccessTemporal Analysis of Indoor Air Quality Parameters in Metro Systems: A Focus on Diurnal Changes
Air quality in public transportation systems, particularly in subway networks, has become an important factor in passenger health and well-being. The development of advanced monitoring technologies, such as IoT sensors, has enabled the real-time measurement of air quality parameters like CO2, PM2.5, and PM10, allowing for a better understanding of environmental conditions in enclosed spaces. However, the impact of varying passenger density on air quality throughout the day, especially during peak hours, has not been sufficiently studied. This study addresses this gap by comparing air quality measurements in subway stations during peak hours and quieter periods. Here, we show that air quality parameters, including CO2, PM2.5, and PM10, significantly worsen during peak hours due to the higher passenger density, which contrasts with prior assumptions that air quality remains relatively constant throughout the day. These findings expand our understanding of how crowded conditions affect air quality, highlighting the need for more effective air circulation and filtration systems during peak times. This research emphasizes the importance of incorporating real-time air quality monitoring into subway system management to improve health outcomes for passengers and workers. Ultimately, the integration of advanced sensor networks could lead to the development of more efficient, responsive systems for managing air quality in urban transit environments.
- Open Access
Chemoresistive Gas Sensors Based on Electrospun 1D Nanostructures: Synergizing Morphology and Performance Optimization
Gas sensors are essential for safety and quality of life, with broad applications in industry, healthcare, and environmental monitoring. As urbanization and industrial activities intensify, the need for advanced air quality monitoring becomes critical, driving the demand for more sensitive, selective, and reliable sensors. Recent advances in nanotechnology, particularly 1D nanostructures like nanofibers and nanowires, have garnered significant interest due to their high surface area and improved charge transfer properties. Electrospinning stands out as a promising technique for fabricating these nanomaterials, enabling precise control over their morphology and leading to sensors with exceptional attributes, including high sensitivity, rapid response, and excellent stability in harsh conditions. This review examines the current research on chemoresistive gas sensors based on 1D nanostructures produced by electrospinning. It focuses on how the morphology and composition of these nanomaterials influence key sensor characteristics—sensitivity, selectivity, and stability. The review highlights recent advancements in sensors incorporating metal oxides, carbon nanomaterials, and conducting polymers, along with their modifications to enhance performance. It also explores the use of fiber-based composite materials for detecting oxidizing, reducing, and volatile organic compounds. These composites leverage the properties of various materials to achieve high sensitivity and selectivity, allowing for the detection of a wide range of gases in diverse conditions. The review further addresses challenges in scaling up production and suggests future research directions to overcome technological limitations and improve sensor performance for both industrial and domestic air quality monitoring applications.
Open AccessChemoresistive Gas Sensors Based on Electrospun 1D Nanostructures: Synergizing Morphology and Performance Optimization
Gas sensors are essential for safety and quality of life, with broad applications in industry, healthcare, and environmental monitoring. As urbanization and industrial activities intensify, the need for advanced air quality monitoring becomes critical, driving the demand for more sensitive, selective, and reliable sensors. Recent advances in nanotechnology, particularly 1D nanostructures like nanofibers and nanowires, have garnered significant interest due to their high surface area and improved charge transfer properties. Electrospinning stands out as a promising technique for fabricating these nanomaterials, enabling precise control over their morphology and leading to sensors with exceptional attributes, including high sensitivity, rapid response, and excellent stability in harsh conditions. This review examines the current research on chemoresistive gas sensors based on 1D nanostructures produced by electrospinning. It focuses on how the morphology and composition of these nanomaterials influence key sensor characteristics—sensitivity, selectivity, and stability. The review highlights recent advancements in sensors incorporating metal oxides, carbon nanomaterials, and conducting polymers, along with their modifications to enhance performance. It also explores the use of fiber-based composite materials for detecting oxidizing, reducing, and volatile organic compounds. These composites leverage the properties of various materials to achieve high sensitivity and selectivity, allowing for the detection of a wide range of gases in diverse conditions. The review further addresses challenges in scaling up production and suggests future research directions to overcome technological limitations and improve sensor performance for both industrial and domestic air quality monitoring applications.
- Open Access
MXene/Carbon Nanocomposites for Water Treatment
One of the most critical problems faced by modern civilization is the depletion of freshwater resources due to their continuous consumption and contamination with different organic and inorganic pollutants. This paper considers the potential of already discovered MXenes in combination with carbon nanomaterials to address this problem. MXene appears to be a highly promising candidate for water purification due to its large surface area and electrochemical activity. However, the problems of swelling, stability, high cost, and scalability need to be overcome. The synthesis methods for MXene and its composites with graphene oxide, carbon nanotubes, carbon nanofibers, and cellulose nanofibers, along with their structure, properties, and mechanisms for removing various pollutants from water, are described. This review discusses the synthesis methods, properties, and mechanisms of water purification using MXene and its composites. It also explores the fundamental aspects of MXene/carbon nanocomposites in various forms, such as membranes, aerogels, and textiles. A comparative analysis of the latest research on this topic shows the progress in this field and the limitations for the practical application of MXene/carbon nanocomposites to solve the problem of drinking water scarcity. Consequently, this review demonstrates the relevance and promise of the material and underscores the importance of further research and development of MXene/carbon nanocomposites to provide effective water treatment solutions.
Open AccessMXene/Carbon Nanocomposites for Water Treatment
One of the most critical problems faced by modern civilization is the depletion of freshwater resources due to their continuous consumption and contamination with different organic and inorganic pollutants. This paper considers the potential of already discovered MXenes in combination with carbon nanomaterials to address this problem. MXene appears to be a highly promising candidate for water purification due to its large surface area and electrochemical activity. However, the problems of swelling, stability, high cost, and scalability need to be overcome. The synthesis methods for MXene and its composites with graphene oxide, carbon nanotubes, carbon nanofibers, and cellulose nanofibers, along with their structure, properties, and mechanisms for removing various pollutants from water, are described. This review discusses the synthesis methods, properties, and mechanisms of water purification using MXene and its composites. It also explores the fundamental aspects of MXene/carbon nanocomposites in various forms, such as membranes, aerogels, and textiles. A comparative analysis of the latest research on this topic shows the progress in this field and the limitations for the practical application of MXene/carbon nanocomposites to solve the problem of drinking water scarcity. Consequently, this review demonstrates the relevance and promise of the material and underscores the importance of further research and development of MXene/carbon nanocomposites to provide effective water treatment solutions.
- Open Access
- 31 July 2024
- Published by MDPI AG in Nanomaterials
- Vol. 14 (15) , 1291
Magnetite-Incorporated 1D Carbon Nanostructure Hybrids for Electromagnetic Interference Shielding
The increasing reliance on electronic technologies has elevated the urgency of effective electromagnetic interference (EMI) shielding materials. This review explores the development and potential of magnetite-incorporated one-dimensional (1D) carbon nanostructure hybrids, focusing on their unique properties and synthesis methods. By combining magnetite’s magnetic properties with the electrical conductivity and mechanical strength of carbon nanostructures such as carbon nanotubes (CNTs) and carbon fibers (CFs), these hybrids offer superior EMI shielding performance. Various synthesis techniques, including solvothermal synthesis, in situ growth, and electrostatic self-assembly, are discussed in detail, highlighting their impact on the structure and properties of the resulting composites. This review also addresses the challenges in achieving homogeneous dispersion of nanofillers and the environmental and economic considerations of large-scale production. The hybrid materials’ multifunctionality, including enhanced mechanical strength, thermal stability, and environmental resistance, underscores their suitability for advanced applications in aerospace, electronics, and environmental protection. Future research directions focus on optimizing synthesis processes and exploring new hybrid configurations to further improve electromagnetic properties and practical applicability.
- 31 July 2024
- Published by MDPI AG in Nanomaterials
- Vol. 14 (15) , 1291
Open AccessMagnetite-Incorporated 1D Carbon Nanostructure Hybrids for Electromagnetic Interference Shielding
The increasing reliance on electronic technologies has elevated the urgency of effective electromagnetic interference (EMI) shielding materials. This review explores the development and potential of magnetite-incorporated one-dimensional (1D) carbon nanostructure hybrids, focusing on their unique properties and synthesis methods. By combining magnetite’s magnetic properties with the electrical conductivity and mechanical strength of carbon nanostructures such as carbon nanotubes (CNTs) and carbon fibers (CFs), these hybrids offer superior EMI shielding performance. Various synthesis techniques, including solvothermal synthesis, in situ growth, and electrostatic self-assembly, are discussed in detail, highlighting their impact on the structure and properties of the resulting composites. This review also addresses the challenges in achieving homogeneous dispersion of nanofillers and the environmental and economic considerations of large-scale production. The hybrid materials’ multifunctionality, including enhanced mechanical strength, thermal stability, and environmental resistance, underscores their suitability for advanced applications in aerospace, electronics, and environmental protection. Future research directions focus on optimizing synthesis processes and exploring new hybrid configurations to further improve electromagnetic properties and practical applicability.
- Open Access
- 31 July 2024
- Published by MDPI AG in Applied Sciences
- Vol. 14 (15) , 6680
Valorization of Grass Clipping Waste: A Sustainable Approach to Cellulose Extraction and Paper Manufacturing
This study investigates the physical, mechanical, and structural characteristics of handmade paper samples derived from cellulose extracted from grass clippings using two distinct methods as follows: (1) alkali treatment and (2) alkali treatment followed by bleaching, coupled with the incorporation of barium sulfate as a mineral filler. Our investigation revealed that the handmade paper samples’ densities, moisture contents, and thicknesses varied within the ranges of 0.436 to 0.549 g/cm3, 5.60 to 2.51%, and 0.41 to 0.50 mm, respectively. The tensile strength and folding endurance of the papers produced through alkali treatment with barium sulfate were notably superior to those produced from bleached pulp and barium sulfate. Our analysis indicates that several critical factors, including paper density, thickness, the crystallinity index, and the microfibrillar structure of cellulose, intricately influence the mechanical and strength properties of the samples. Using Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) techniques, we identified characteristic cellulose bonds and examined cellulose’s crystalline and amorphous phases. Additionally, the crystallinity index of the samples was determined using both the Segal and peak deconvolution methods. Scanning electron microscopy (SEM) micrographs revealed interconnected networks of cellulose fibers with varying thicknesses and lengths, along with incorporated mineral filler within the cellulose fiber structure. Variations in mineral particle retention were attributed to the presence or absence of cellulose microfibrils. These findings contribute to our understanding of the observed strength characteristics of the paper samples and underscore the potential applications of cellulose derived from grass clippings, especially when combined with barium sulfate as a mineral filler in paper production.
- 31 July 2024
- Published by MDPI AG in Applied Sciences
- Vol. 14 (15) , 6680
Open AccessValorization of Grass Clipping Waste: A Sustainable Approach to Cellulose Extraction and Paper Manufacturing
This study investigates the physical, mechanical, and structural characteristics of handmade paper samples derived from cellulose extracted from grass clippings using two distinct methods as follows: (1) alkali treatment and (2) alkali treatment followed by bleaching, coupled with the incorporation of barium sulfate as a mineral filler. Our investigation revealed that the handmade paper samples’ densities, moisture contents, and thicknesses varied within the ranges of 0.436 to 0.549 g/cm3, 5.60 to 2.51%, and 0.41 to 0.50 mm, respectively. The tensile strength and folding endurance of the papers produced through alkali treatment with barium sulfate were notably superior to those produced from bleached pulp and barium sulfate. Our analysis indicates that several critical factors, including paper density, thickness, the crystallinity index, and the microfibrillar structure of cellulose, intricately influence the mechanical and strength properties of the samples. Using Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) techniques, we identified characteristic cellulose bonds and examined cellulose’s crystalline and amorphous phases. Additionally, the crystallinity index of the samples was determined using both the Segal and peak deconvolution methods. Scanning electron microscopy (SEM) micrographs revealed interconnected networks of cellulose fibers with varying thicknesses and lengths, along with incorporated mineral filler within the cellulose fiber structure. Variations in mineral particle retention were attributed to the presence or absence of cellulose microfibrils. These findings contribute to our understanding of the observed strength characteristics of the paper samples and underscore the potential applications of cellulose derived from grass clippings, especially when combined with barium sulfate as a mineral filler in paper production.
- Open Access
- 7 November 2023
- Published by MDPI AG in Technologies
- Vol. 11 (6) , 156
Pitch/Metal Oxide Composite Fibers via Electrospinning for Environmental Applications
This study investigates the synthesis and application of composite electrospun fibers incorporating coal tar pitch (CTP) and various nanomaterial additives, with a specific focus on their potential for eco-bio-applications. The research underscores the environmentally viable aspects of CTP following a thermal treatment process that eliminates volatile components and sulfur, rendering it amenable for fiber electrospinning and subsequent carbonization. Composite fibers were fabricated by integrating CTP with nanomaterials, including nickel oxide (NiO), titanium dioxide (TiO2), activated carbon (AC), and magnetite (Fe3O4). The C/NiO composite fibers exhibit notable acetone sensing capabilities, specifically displaying a rapid response time of 40.6 s to 100 ppm acetone at 220 °C. The C/TiO2 composite fibers exhibit a distinct “beads-on-a-string” structure and demonstrate a high efficiency of 96.13% in methylene blue decomposition, highlighting their potential for environmental remediation applications. Additionally, the C/AC composite fibers demonstrate effective adsorption properties, efficiently removing manganese (II) ions from aqueous solutions with an 88.62% efficiency, thereby suggesting their utility in water purification applications. This research employs an interdisciplinary approach by combining diverse methods, approaches, and materials, including the utilization of agricultural waste materials such as rice husks, to create composite materials with multifaceted applications. Beyond the immediate utility of the composite fibers, this study emphasizes the significance of deploying environmentally responsible materials and technologies to address pressing eco-bio-challenges.
- 7 November 2023
- Published by MDPI AG in Technologies
- Vol. 11 (6) , 156
Open AccessPitch/Metal Oxide Composite Fibers via Electrospinning for Environmental Applications
This study investigates the synthesis and application of composite electrospun fibers incorporating coal tar pitch (CTP) and various nanomaterial additives, with a specific focus on their potential for eco-bio-applications. The research underscores the environmentally viable aspects of CTP following a thermal treatment process that eliminates volatile components and sulfur, rendering it amenable for fiber electrospinning and subsequent carbonization. Composite fibers were fabricated by integrating CTP with nanomaterials, including nickel oxide (NiO), titanium dioxide (TiO2), activated carbon (AC), and magnetite (Fe3O4). The C/NiO composite fibers exhibit notable acetone sensing capabilities, specifically displaying a rapid response time of 40.6 s to 100 ppm acetone at 220 °C. The C/TiO2 composite fibers exhibit a distinct “beads-on-a-string” structure and demonstrate a high efficiency of 96.13% in methylene blue decomposition, highlighting their potential for environmental remediation applications. Additionally, the C/AC composite fibers demonstrate effective adsorption properties, efficiently removing manganese (II) ions from aqueous solutions with an 88.62% efficiency, thereby suggesting their utility in water purification applications. This research employs an interdisciplinary approach by combining diverse methods, approaches, and materials, including the utilization of agricultural waste materials such as rice husks, to create composite materials with multifaceted applications. Beyond the immediate utility of the composite fibers, this study emphasizes the significance of deploying environmentally responsible materials and technologies to address pressing eco-bio-challenges.
- Open Access
- 31 October 2023
- Published by MDPI AG in Journal of Composites Science
- Vol. 7 (11) , 452
Investigations of Activated Carbon from Different Natural Sources for Preparation of Binder-Free Few-Walled CNTs/Activated Carbon Electrodes
In this study, we present another approach to fabricating high-performance supercapacitor electrodes by combining activated carbon particles with carbon nanotubes (AC/CNT). We synthesized activated carbon from diverse biomass sources using a carbonization process and chemical activation with KOH. By incorporating carbon nanotubes, we significantly augmented the electrode’s surface area, resulting in exceptional ion transport and a substantial increase in specific capacitance. Our investigation reveals that the optimized composition, 85:10:5 of AC, CNT, and conductive additive, achieved outstanding specific capacitance values, notably 125.6 F g−1 at 1 mV s−1 and 118 F g−1 at 1 A g−1, along with a maximum energy density of 4 Wh kg−1. Electrochemical impedance spectroscopy (EIS) further demonstrated the superior charge transfer capabilities of these electrodes, notably at a frequency range from 100 kHz to 10 mHz. Additionally, our research highlights the influence of different biomass precursors, such as apricot kernels, walnut shells, and rice husks, on the electrochemical behavior of these electrodes. Overall, this study provides valuable insights into the development of high-performance supercapacitors, emphasizing the potential of diverse biomass sources in optimizing electrode materials.
- 31 October 2023
- Published by MDPI AG in Journal of Composites Science
- Vol. 7 (11) , 452
Open AccessInvestigations of Activated Carbon from Different Natural Sources for Preparation of Binder-Free Few-Walled CNTs/Activated Carbon Electrodes
In this study, we present another approach to fabricating high-performance supercapacitor electrodes by combining activated carbon particles with carbon nanotubes (AC/CNT). We synthesized activated carbon from diverse biomass sources using a carbonization process and chemical activation with KOH. By incorporating carbon nanotubes, we significantly augmented the electrode’s surface area, resulting in exceptional ion transport and a substantial increase in specific capacitance. Our investigation reveals that the optimized composition, 85:10:5 of AC, CNT, and conductive additive, achieved outstanding specific capacitance values, notably 125.6 F g−1 at 1 mV s−1 and 118 F g−1 at 1 A g−1, along with a maximum energy density of 4 Wh kg−1. Electrochemical impedance spectroscopy (EIS) further demonstrated the superior charge transfer capabilities of these electrodes, notably at a frequency range from 100 kHz to 10 mHz. Additionally, our research highlights the influence of different biomass precursors, such as apricot kernels, walnut shells, and rice husks, on the electrochemical behavior of these electrodes. Overall, this study provides valuable insights into the development of high-performance supercapacitors, emphasizing the potential of diverse biomass sources in optimizing electrode materials.
- Open Access
- 23 October 2023
- Published by Institute of Combustion Problems in Горение и Плазмохимия
- Vol. 21 (3) , 147-157
Magnetite nanoparticles obtained by solution combustion synthesis
This research presents a comprehensive investigation into the synthesis and characterization of magnetite nanoparticles through solution combustion reactions ignited by conventional means. In addition to the structural and compositional findings, this study's main investigation results include the specific surface area measurements conducted using the BET method. The analysis revealed specifi c surface area values for the synthesized magnetite nanoparticles at varying propellant-to-oxidant ratios, demonstrating a substantial decrease in specific surface area as the ratio increased. Specifically, specific surface areas of 72.203 m2/g for the 1:1 ratio, 22.240 m2/g for the 1:1.5 ratio, and 9.204 m2/g for the 1:2 ratio were determined. Furthermore, calculations based on the BET results and assuming spherical magnetite nanoparticles provided average particle sizes of 16±1 nm for the 1:1 ratio, 51±2 nm for the 1:1.5 ratio, and 125±4 nm for the 1:2 ratio. These findings highlight the impact of synthesis parameters on the nanoparticles' surface area and size, shedding light on their potential applications in various fields, including nanomedicine and magnetic diagnostics. Overall, this research contributes valuable insights into the synthesis, characterization, and tunable properties of magnetite nanoparticles, offering potential avenues for their utilization across diverse industries.
- 23 October 2023
- Published by Institute of Combustion Problems in Горение и Плазмохимия
- Vol. 21 (3) , 147-157
Open AccessMagnetite nanoparticles obtained by solution combustion synthesis
This research presents a comprehensive investigation into the synthesis and characterization of magnetite nanoparticles through solution combustion reactions ignited by conventional means. In addition to the structural and compositional findings, this study's main investigation results include the specific surface area measurements conducted using the BET method. The analysis revealed specifi c surface area values for the synthesized magnetite nanoparticles at varying propellant-to-oxidant ratios, demonstrating a substantial decrease in specific surface area as the ratio increased. Specifically, specific surface areas of 72.203 m2/g for the 1:1 ratio, 22.240 m2/g for the 1:1.5 ratio, and 9.204 m2/g for the 1:2 ratio were determined. Furthermore, calculations based on the BET results and assuming spherical magnetite nanoparticles provided average particle sizes of 16±1 nm for the 1:1 ratio, 51±2 nm for the 1:1.5 ratio, and 125±4 nm for the 1:2 ratio. These findings highlight the impact of synthesis parameters on the nanoparticles' surface area and size, shedding light on their potential applications in various fields, including nanomedicine and magnetic diagnostics. Overall, this research contributes valuable insights into the synthesis, characterization, and tunable properties of magnetite nanoparticles, offering potential avenues for their utilization across diverse industries.
- Open Access
- 21 October 2023
- Published by MDPI AG in Journal of Composites Science
- Vol. 7 (10) , 444
Biomass Derived High Porous Carbon via CO2 Activation for Supercapacitor Electrodes
In this study, we systematically study the efficient production method and electrochemical characteristics of activated carbons (AC) derived from rice husk (RH) and walnut shell (WS). In particular, the effectiveness of physical activation using carbon dioxide (CO2) was investigated and compared with the more common chemical activation method using potassium hydroxide (KOH). The results show that the KOH–activated samples have remarkable specific capacities, reaching 157.8 F g−1 for RH and 152 F g−1 for WS at 1 A g−1. However, the rate capability of AC obtained via KOH decreases significantly as the scanning rate increases, retaining only 51.5% and 68% of their original capacities for RH–KOH and WS–KOH, respectively, at 20 A g–1. In contrast, CO2–activated samples show a superior rate performance with a capacity retention of 75.6% for WS and 80% for RH at the same current density. In addition, electrochemical impedance spectroscopy (EIS) analysis shows that AC obtained via CO2 has a lower charge transfer resistance compared to its KOH counterparts. CO2–activated RH and WS electrodes show Rct values of 0.1 Ω and 0.24 Ω, respectively, indicating improved ion transport kinetics and surface area utilization. These results highlight the importance of activation techniques in tailoring the electrochemical behavior of biomass–derived carbon. This study not only expands the understanding of the interaction between activation, morphology, and performance but also indicates the potential of CO2 activation as an environmentally friendly and efficient alternative. As the field of sustainable energy storage advances, this work provides valuable guidance for the development of high–performance supercapacitor electrodes with less environmental impact.
- 21 October 2023
- Published by MDPI AG in Journal of Composites Science
- Vol. 7 (10) , 444
Open AccessBiomass Derived High Porous Carbon via CO2 Activation for Supercapacitor Electrodes
In this study, we systematically study the efficient production method and electrochemical characteristics of activated carbons (AC) derived from rice husk (RH) and walnut shell (WS). In particular, the effectiveness of physical activation using carbon dioxide (CO2) was investigated and compared with the more common chemical activation method using potassium hydroxide (KOH). The results show that the KOH–activated samples have remarkable specific capacities, reaching 157.8 F g−1 for RH and 152 F g−1 for WS at 1 A g−1. However, the rate capability of AC obtained via KOH decreases significantly as the scanning rate increases, retaining only 51.5% and 68% of their original capacities for RH–KOH and WS–KOH, respectively, at 20 A g–1. In contrast, CO2–activated samples show a superior rate performance with a capacity retention of 75.6% for WS and 80% for RH at the same current density. In addition, electrochemical impedance spectroscopy (EIS) analysis shows that AC obtained via CO2 has a lower charge transfer resistance compared to its KOH counterparts. CO2–activated RH and WS electrodes show Rct values of 0.1 Ω and 0.24 Ω, respectively, indicating improved ion transport kinetics and surface area utilization. These results highlight the importance of activation techniques in tailoring the electrochemical behavior of biomass–derived carbon. This study not only expands the understanding of the interaction between activation, morphology, and performance but also indicates the potential of CO2 activation as an environmentally friendly and efficient alternative. As the field of sustainable energy storage advances, this work provides valuable guidance for the development of high–performance supercapacitor electrodes with less environmental impact.