Nino Dimitrov

Microplastics (MP), consisting of particles under 5 mm in size, and fibrous microplastics (FMPs), which originate from textiles and are shed during the washing process, are acknowledged as a new and expanding category of pollutants. This study aimed to conduct an analytical evaluation of the defragmentation process of polyester fabrics featuring a prominent tri-color pile surface. The evaluation involved washing the fabrics with detergent and water and employing various methods to assess the fabric, wastewater, and filter cake both prior to, and following, cryogenization. The specificity of a pile polyester fabric provided a baseline for evaluating the detergent and water system. Subjecting the polyester fabric to five cycles of washing in a detergent solution and water resulted in a measurable loss of mass. The pristine polyester fabric was analyzed microscopically and by FTIR, while the fabrics before and after washing were subjected to gravimetric analysis. The physico–chemical characteristics of the wastewater, such as the conductivity, turbidity, and chemical oxygen demand, were impacted by the composition of the washing bath. The application of pyrolysis, combined with gas chromatography and mass spectrometry (Py-GC/MS), on the filter cake demonstrated the value of using blank samples. The results indicated that both the detergent and the water significantly affected the release of FMPs during the washing process. Polyester fabric sample 1, which was washed in a detergent solution for five cycles, exhibited a mass loss of 1619 mg kg⁻¹. In contrast, sample 2, consisting of a polyester fabric washed solely in water, showed a mass loss of 1707 mg kg⁻¹ over the same number of cycles.

The continuous growth in the production, unsustainable use, and disposal of plastics in recent decades has led to the emergence of a new type of pollutant, microplastics (MPs). In this article, the focus is on the form of MPs, which are produced by the fragmentation of textile fibres during washing processes. The problems associated with the characterisation and quantification of MPs in this type of sample are related to the wide range of concentrations, forms, and degree of degradation as well as physico-chemical and biological properties. Although the basic principles for the analysis of microplastics present in the environmental samples are known, there is the lack of standardised methods for the analysis of MPs in laundry effluents and domestic washing. Therefore, the continuous development of sophisticated analytical techniques and methodologies is required for the reliable collection and isolation, quantification, and characterisation of one of the most challenging analytes. The aim of this review is to outline the key steps of MPs analysis in laundry effluents and domestic washing, focusing on those steps that are underestimated in the current literature: sampling and sample preparation for analysis. Precisely these analytical steps, which can become the main source of analytical measurement system errors, ensure the quality of the analysis. This paper emphasises the importance of monitoring background contamination and presents guidelines to ensure quality control specifically for this type of analyte.

Plastic contamination has become one of the most pressing environmental issues due to rapidly increasing production of disposable plastic products, their fragmentation into smaller pieces, and long persistence in the environment, which affects all living organisms, including plants. In this study, Allium cepa roots were exposed to 0.01, 0.1, and 1 g L⁻¹ of commercial polystyrene (PS-MPs) and polymethyl methacrylate microparticles (PMMA-MPs) for 72 h. Dynamic light scattering (DLS) analyses showed high stability of both types of MPs in ultrapure water used for A. cepa treatment. Morphometric analysis revealed no significant change in root length compared to control. Pyrolysis hyphenated to gas chromatography and mass spectrometry (Py-GC-MS) has proven PS-MPs uptake by onion roots in all treatments, while PMMA-MPs were recorded only upon exposure to the highest concentration. Neither MPs induced any (cyto)toxic effect on root growth and PMMA-MPs even had a stimulating effect on root growth. ROS production as well as lipid and protein oxidation were somewhat higher in PS-MP treatments compared to the corresponding concentrations of PMMA-MP, while neither of the applied MPs induced significant damage to the DNA molecule assayed with a Comet test. Significantly elevated activity of H₂O₂ scavenging enzymes, catalase, and peroxidases was measured after exposure to both types of MPs. Obtained results suggest that onion roots take up PS-MPs more readily in comparison to PMMA-MPs, while both types of MPs induce a successful activation of antioxidant machinery in root cells that prevented the occurrence of toxic effects.

Research on the sources of microplastics (MP) in the environment and the parameters that lead to the loss of microfibers from synthetic textiles during washing have recently attracted public attention. Considering the involvement of a variety of structural and process parameters, it is important to choose methods for quantifying fibers as MP pollutants that migrated during the washing process. In the research to date, various sampling techniques and analytical protocols for the identification of polymers from washed synthetic textiles have been applied. In the present research, pyrolysis coupled with gas chromatography and mass spectrometry (Py-GC/MS), was applied to verify the composition of the filter residue isolated from washing and rinsing effluents. A comparison with bases of polymeric materials has proven the presence of potential environmental pollutants in the form of microfibers released during the washing process. The investigation confirmed that fragments of cotton cellulose residues predominate in relation to polyester. Based on the list of identified compounds generated by Py-GC/MS results and their retention times the multivariate data analysis proved the influence in the bath composition.

The dominant type of polymer particles in water, sediment, and various organisms partly derives from natural and synthetic fibres released in the washing process. Pollution of aquatic recipients with these particles poses an interdisciplinary problem throughout the world. Wastewater from washing represents a dispersion system with different particle sizes that is also loaded with the source of the particles. Due to this complex system, the qualification and quantification of this type of pollution is difficult. In this paper, the laser diffraction technique was applied to characterize particles in effluents from washing and rinsing materials made of a mixture of cotton and polyester. The results obtained through the analysis prove that the laser diffraction technique is acceptable for the characterization of a composite effluent sample. The advanced statistical technique of multivariate analysis confirmed the interrelationship of the parameters of this complex dispersion system.