Lipeng Zhang

Plate tectonics drives the compositional diversity of Earth’s convecting mantle through subduction of lithosphere. In this context, the role of evolving global geodynamics and plate (re)organization on the spatial and temporal distribution of compositional heterogeneities in the convecting mantle is poorly understood. Here, using the geochemical compositions of intracontinental basalts formed over the past billion years, we show that intracontinental basalts with subchondritic initial neodymium-144/neodymium-143 values become common only after 300 million years, broadly coeval with the global appearance of kimberlites with geochemically enriched isotopic signatures. These step changes in the sources of intraplate magmatism stem from a rapid increase in the supply of deeply subducted lithosphere during the protracted formation of Pangea following the widespread onset of “modern” (cold and deep) subduction in the late Neoproterozoic. We argue that the delay (~300 million years) in the appearance of enriched intraplate magmas reflects the time required for the sinking and (re)incorporation of slabs into the sources of mantle-derived magmas.

Determining the evolutionary history of mantle oxygen fugacity (fo₂) is crucial, as it controls the fo₂ of mantle-derived melts and regulates atmospheric composition through volcanic outgassing. However, the evolution of mantle fo₂ remains controversial. Here, we present a comprehensive dataset of plume-derived komatiites, picrites, and ambient mantle-derived (meta)basalts, spanning from ~3.8 Ga to the present, to investigate mantle thermal and redox states evolution. Our results indicate that fo₂ of both mantle plume-derived and ambient mantle-derived melts was lower during the Archean compared to the post-Archean period. This increase in the fo₂ of mantle-derived melts over time correlates with decreases in mantle potential temperature and melting depth. By normalizing fo₂ to a constant reference pressure (potential oxygen fugacity), we show that the fo₂ of both the mantle plume and ambient upper mantle has remained constant since the Hadean. These findings suggest that secular mantle cooling reduced melting depth, increasing the fo₂ of mantle-derived melts and contributing to atmospheric oxygenation.

The Cuonadong Sn–W–Be polymetallic deposit in the Himalayan leucogranite belt is a representative hydrothermal deposit. The role of fluid exsolution directly from magma and the fluid reaction with surrounding rocks for ore-forming element enrichment is still controversial. Tourmaline is a significant B-bearing mineral in the hydrothermal deposit, and its geochemical and B isotopic signatures can record the source and evolution of the ore-forming fluid. Two types of hydrothermal tourmaline in the hydrothermal quartz vein (Tur-1) and skarn (Tur-2) were used in this study. Both Tur-1 and Tur-2 have low X-site occupancy and mainly belong to the alkali group. Tur-1 plots in the schorl field, whereas Tur-2 is largely Mg-rich dravite. The B isotope analyses of Tur-1 have δ¹¹B values of −13.7 to −13.2‰, whereas Tur-2 has higher δ¹¹B values of −11.1 to −9.3‰. The distinct contact relationship and geochemical compositions suggest that Tur-1 in the hydrothermal vein was formed from a magmatic-hydrothermal fluid with little influence from surrounding rocks and had a genetic relationship with the Cuonadong leucogranite, whereas Tur-2 in the skarn involved more fluid from surrounding rocks with high δ¹¹B values and strong metasomatic texture. The higher ore-forming element contents in Tur-2 than those in Tur-1 indicate that the reaction between the magmatic exsolution fluid and the surrounding rock is essential for the enrichment and precipitation of ore-forming elements.

Several gold ore-concentrated areas have been recognized in the destruction zone of the North China Craton (NCC). However, the deposits in the western part of the destruction zone have received less attention. Miaoan, a typical Au-polymetallic deposit in the northern Taihang Mountain, provides a good sample for deepening our understanding of the genesis of gold deposits in the western destruction zone. In this study, detailed ore geology, pyrite Rb-Sr age, trace element and S-C-O isotopes of Au-bearing ores were conducted to constrain the source of ore-forming materials and their tectonic setting. The pyrites obtain an Rb-Sr isochron age of 129.5 ± 2.5 Ma, consistent with those of magmatic rocks in this deposit, suggesting their genetic relationship. The δ³⁴S values ranging from −5.5‰ to 1.6‰ and the high Co/Ni and Y/Ho ratios of pyrites indicate the mantle-crust mixing characteristics of ore-forming fluids. The δ¹³C (−6.3‰ to −2.0‰) and δ¹⁸O (9.3‰ to 17.6‰) values of Au-bearing ores and calcites suggest mixing characteristics as well. Geochronologically, the Miaoan Au-polymetallic deposit was formed during the destruction of the NCC. We propose that the Miaoan Au-polymetallic deposit is a decratonic gold deposit and that its ore-forming materials have a mixed source of mantle and crust.