John F. Pernet-Fisher

Understanding when lunar granitoids formed remains a long-standing challenge hampering efforts to place these rock types into the wider context of the geological evolution of the Moon. In particular, it is poorly understood what their relationship is to KREEP-rich mafic lithologies such as alkali gabbronorites that have been linked to the generation of felsic melts through processes such as crustal underplating. Here we report in situ Rb-Sr, U-Pb, and Pb isotope systematics for lunar granitoid and alkali gabbronorite clasts from a range of Apollo landing sites. Our data indicate that the dates derived from the Rb-Sr, U-Pb, and Pb isotope systematics recorded by plagioclase, K-feldspar, Ca-phosphates, and glass most likely reflect impact resetting events rather than initial crystallisation ages. Granitoid and alkali gabbronorite samples 67975,9011, 14303,330, 72275,520, and 73255,9083 record dates consistent with the Imbrium impact event at 3.92 Ga, whereas samples 14305,111, 73235,73, and 14305,102 record modification by younger impacts at ∼3.5 to ∼3.6 Ga. Currently, zircon U-Pb isotope dates provide the most robust constraints on the formation ages of Apollo sampled granitoids. The majority of zircon dates are significantly older than those calculated from crater counting for lunar silicic domes (mostly between ca. 4 to 3.6 Ga). Consequently, it is not evident that mechanisms for generating large volumes of evolved melt by processes such as crustal underplating of mafic lithologies are needed. Formation within granophyre layers in magmatic layered intrusions or differentiated impact melt sheets cannot be ruled out.

Rocks of the lunar granulite suite are the product of high‐temperature metamorphism within the Moon's crust. However, to date, their formation conditions have few constraints. Here, we combine Ti‐in‐pyroxene element diffusion modeling and two‐pyroxene thermometry with thermal modeling of the lunar crust in order to assess potential heat sources that could generate granulite metamorphism within the lunar highland crust. For the samples investigated in this study, the pyroxene crystals experienced peak metamorphic temperatures between ∼1,027 and 1,091°C over timescales ranging from ∼153 years to ∼15.1 Kyrs. To best satisfy these temperature and timescale constraints, hot (∼2,300°C) impact melt sheets with thickness ranging from 350 m to 3.35 km—equating to impact crater diameters between ∼60 and 280 km—have the potential to heat the underlying anorthositic crust. Deep (>20 km) igneous bodies, such as the large (>10 km thick) sills observed by the GRAIL mission near the base of the lunar crust, also have the potential to generate the required peak metamorphic temperatures; however, the thermal equilibration timescales in this scenario are modeled to be much larger (>100 Kyrs) than was witnessed by the granulites investigated. Our modeling highlights that while lunar granulites are only a minor component within the Apollo and meteorite collection, they are likely an important and ubiquitous lithology within the lunar highland crust.

Thermally metamorphosed rocks on the Moon are an important, yet under-studied, suite of lithologies that have been identified within the Apollo and lunar meteorite collections. These rocks, with granoblastic and poikilitic textures, are generally referred to as granulites. However, unlike their terrestrial counterparts, which are the metamorphic products of both high temperatures and high pressures, lunar granulites are thought to be the products of only high-temperature (>1000°C) thermal metamorphism, which completely recrystallized their protoliths. We summarize the range of textures and chemical systematics reported from lunar granulites. These data enable constraints to be placed on the thermal conditions in the lunar crust required for high-temperature metamorphism to have taken place. Most studies indicate that impact melt sheets have the relevant thermal properties to sustain high temperatures over the timescales required to fully recrystallize the surrounding crustal lithologies. However, the roles of alternative heat sources, such as magmatic intrusions into the crust, have not been extensively investigated and, as such, cannot be ruled out. In addition, the chemical data yield important insights into the protoliths of the granulite suite. By identifying the protoliths, we greatly enhance our understanding of the range of lithologies that make up the primary lunar crust. In turn, this enables crustal formation models to be better constrained. Supplementary material: All the geochemical data discussed within this review are available at: https://doi.org/10.6084/m9.figshare.c.5623326

The Moon is the only planetary body other than the Earth for which samples have been collectedin situby humans and robotic missions and returned to Earth. Scientific investigations of the first lunar samples returned by the Apollo 11 astronauts 50 years ago transformed the way we think most planetary bodies form and evolve. Identification of anorthositic clasts in Apollo 11 samples led to the formulation of the magma ocean concept, and by extension the idea that the Moon experienced large-scale melting and differentiation. This concept of magma oceans would soon be applied to other terrestrial planets and large asteroidal bodies. Dating of basaltic fragments returned from the Moon also showed that a relatively small planetary body could sustain volcanic activity for more than a billion years after its formation. Finally, studies of the lunar regolith showed that in addition to containing a treasure trove of the Moon’s history, it also provided us with a rich archive of the past 4.5 billion years of evolution of the inner Solar System. Further investigations of samples returned from the Moon over the past five decades led to many additional discoveries, but also raised new and fundamental questions that are difficult to address with currently available samples, such as those related to the age of the Moon, duration of lunar volcanism, the lunar paleomagnetic field and its intensity, and the record on the Moon of the bombardment history during the first billion years of evolution of the Solar System. In this contribution, we review the information we currently have on some of the key science questions related to the Moon and discuss how future sample-return missions could help address important knowledge gaps.

We present reaction balancing and thermodynamic modeling based on microtextural observations and mineral chemistry, to constrain the history of phosphate crystallization within two lunar mare basalts, 10003 and 14053. Phosphates are typically found within intercumulus melt pockets (mesostasis), representing the final stages of basaltic crystallization. In addition to phosphates, these pockets typically consist of Fe-rich clinopyroxene, fayalite, plagioclase, ilmenite, SiO₂, and a residual K-rich glass. Some pockets also display evidence for unmixing into two immiscible melts: A Si-K-rich and an Fe-rich liquid. In these cases, the crystallization sequence is not always clear. Despite petrologic complications associated with mesostasis pockets (e.g., unmixing), the phosphates (apatite and merrillite) within these areas have been recently used for constraining the water content in the lunar mantle. We compute mineral reaction balancing for mesostasis pockets from Apollo high-Ti basalt 10003 and high-Al basalt 14053 to suggest that their parental magmas have an H₂O content of 25 ± 10 ppm, consistent with reported estimates based on directly measured H₂O abundances from these samples. Our results permit to constrain in which immiscible liquid a phosphate of interest crystallizes, and allows us to estimate the extent to which volatiles may have partitioned into other phases such as K-rich glass or surrounding clinopyroxene and plagioclase using a non-destructive method.

Miller Range (MIL) 13317 is a heterogeneous basalt‐bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near‐surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al₂O₃ 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare‐highland boundary that is KREEP‐rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low‐Ti to low‐Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon‐bearing phases and Ca‐phosphate grains in basalt clasts and matrix grains yield ²⁰⁷Pb/²⁰⁶Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient ²⁰⁷Pb/²⁰⁶Pb ages indicate that the meteorite has sampled a range of Pre‐Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.

This study presents the petrography, mineralogy, and bulk composition of lunar regolith breccia meteorite Northwest Africa (NWA) 7948. We identify a range of lunar lithologies including basaltic clasts (very low‐titanium and low‐titanium basalts), feldspathic lithologies (ferroan anorthosite, magnesian‐suite rock, and alkali suite), granulites, impact melt breccias (including crystalline impact melt breccias, clast‐bearing impact melt breccias, and glassy melt breccias), as well as regolith components (volcanic glass and impact glass). A compositionally unusual metal‐rich clast was also identified, which may represent an impact melt lithology sourced from a unique Mg‐suite parent rock. NWA 7948 has a mingled bulk rock composition (Al₂O₃ = 21.6 wt% and FeO = 9.4 wt%) and relatively low concentrations of incompatible trace elements (e.g., Th = 1.07 ppm and Sm = 2.99 ppm) compared with Apollo regolith breccias. Comparing the bulk composition of the meteorite with remotely sensed geochemical data sets suggests that the sample was derived from a region of the lunar surface distal from the nearside Th‐rich Procellarum KREEP Terrane. Our investigations suggest that it may have been ejected from a nearside highlands‐mare boundary (e.g., around Mare Crisium or Orientale) or a cryptomare region (e.g., Schickard‐Schiller or Mare smythii) or a farside highlands‐mare boundary (e.g., Mare Australe, Apollo basin in the South Pole–Aitken basin). The distinctive mineralogical and geochemical features of NWA 7948 suggest that the meteorite may represent lunar material that has not been reported before, and indicate that the lunar highlands exhibit wide geological diversity.

Our understanding of the formation and evolution of the primary lunar crust is based on geochemical systematics from the lunar ferroan anorthosite (FAN) suite. Recently, much effort has been made to understand this suite’s petrologic history to constrain the timing of crystallisation and to interpret FAN chemical diversity. We investigate the shock histories of lunar anorthosites by combining Optical Microscope (OM) ‘cold’ cathodoluminescence (CL)-imaging and Fourier Transform Infrared (FTIR) spectroscopy analyses. In the first combined study of its kind, this study demonstrates that over ~4.5 Ga of impact processing, plagioclase is on average weakly shocked (30 GPa; maskelynite) are uncommon. To investigate how plagioclase trace-element systematics are affected by moderate to weak shock (~5 to 30 GPa) we couple REE+Y abundances with FTIR analyses for FAN clasts from lunar meteorite Northwest Africa (NWA) 2995. We observe weak correlations between plagioclase shock state and some REE+Y systematics (e.g., La/Y and Sm/Nd ratios). This observation could prove significant to our understanding of how crystallisation ages are evaluated (e.g., plagioclase-whole rock Sm-Nd isochrons) and for what trace-elements can be used to differentiate between lunar lithologies and assess magma source compositional differences.

Fourier transform infrared (FTIR) spectroscopy and cathodoluminescence (CL) imaging techniques, combined with electron microprobe analyses, have been used to determine the physical state of feldspathic phases that have been subject to varying levels of shock in the grouped lunar meteorites Miller Range 090034, 090070, and 090075. Six feldspathic phases have been identified based on spectral, textural, and chemical properties. A specific infrared wavelength band ratio (1064/932 cm⁻¹ equivalent to 9.40/10.73 μm), chosen because it can distinguish between some of the feldspathic phases, can be used to estimate the pressure regimes experienced by these phases. In addition, FTIR spatial mapping capabilities allow for visual comparison of variably shocked phases within the samples. By comparing spectral and compositional data, the origin and shock history of this lunar meteorite group has been determined, with each of the shocked feldspathic phases being related to events in its geological evolution. As such, we highlight that FTIR spectroscopy can be easily employed to identify shocked feldspathic phases in lunar samples; estimate peak shock pressures; and when compared with chemical data, can be used to investigate their shock histories.