Andrzej Kulczycki

The aviation sector is accelerating the transition toward low-carbon propulsion, and Sustainable Aviation Fuels (SAFs) represent a key leverage to reduce lifecycle emissions without modifying existing turbine architectures. Microturbines offer an effective and low-cost platform for assessing SAF behaviour under engine-representative conditions. In this work, a zero-dimensional performance and emission model of the GTM-140 microturbine was developed in GSP and validated against experimental data at 70,000–112,000 rpm for Jet A-1 and HEFA paraffinic blends. The model reproduces thrust and fuel-flow trends with good fidelity, with deviations typically below 6% across all operating points. Introducing 50% HEFA consistently reduces fuel consumption, leading to a TSFC decrease of 3–6%, with the strongest effect at high rotational speed, where compressor efficiency is highest. CO emission indices decrease by 6–9% at mid-load and converge at full power due to enhanced oxidation, while NO_x increases by 6–15%, driven by the higher adiabatic flame temperature associated with HEFA’s increased H/C ratio and heating value. These results confirm that simplified 0D modelling can reliably capture performance and emission trends of SAF-fuelled microturbines and demonstrate the dual effect of HEFA: improved combustion efficiency and CO reduction, at the expense of moderately higher NO_x formation.

This study investigates the effect of the concentration of sustainable jet fuel components on selected physicochemical properties of blends with fossil Jet A-1 fuel, as well as on parameters characterizing the combustion process in aircraft turbine engines. The analyzed physicochemical properties were density, net heat of combustion, and fractional composition (50% recoverey temperature and viscosity at −20 °C) of the fuel blends. The combustion process was examined using test rigs equipped with GTM 140 and DGEN 380 engines operated at different rotational speeds. For each engine speed, the fuel mass flow rate and the combustion chamber temperature were determined. The functions mf = Ae^(−Ea/RT) were derived, corresponding to the kinetic equations of the complete combustion reaction chain. The (Ea/R)mf values obtained using the trend line method for the GTM 140 engine were found to be linearly related to those obtained for the DGEN 380 engine. A deviation from linearity was observed for blends containing 5% of various synthetic components. These findings support a new hypothesis that the same intermolecular interactions between liquid fuel components that account for the non-additivity of physicochemical properties also contribute to the parameters of combustion kinetics in turbine engines. Tests on the turbine engine provided preliminary validation of this hypothesis.

Drop-in fuels for aviation gas-turbine engines have been introduced recently to mitigate global warming. Despite their similarity to the fossil fuel Jet A-1, their combustion in traditional combustors should be thoroughly analyzed to maintain engine health and low emissions. The paper introduces criteria for assessing the impact of the chemical composition of fuels on combustion in the DEGN 380 turbofan. Based on previous emission-test results, the power functions of carbon monoxide and its emission index were adopted as the model of combustion. Based on the general notation of chemical reactions leading to the production of CO in combustion, the regression coefficients were given a physical meaning by linking them with the parameters of the kinetic equations, i.e., the reaction rate constant of CO and CO₂ formation expressed as exponential functions of combustor outlet temperature and the concentration of O₂ in the exhaust gas, as well as stoichiometric combustion reactions. The obtained empirical functions show that, in the entire range of engine operating parameters, synthetic components affect the values of the rate constants of CO and CO₂ formation. It can be explained by the change in activation energy determined for all chain-of-combustion reactions. The activation energy for the CO formation chain changes in the range between 8.5 kJ/mol for A0 and 24.7 kJ/mol for A30, while for the CO₂ formation chain between 29.8 kJ/mol for A0 and 30.8 kJ/mol for A30. The reactivity coefficient lnα_iCOA_COD_CO changes between 2.29 for A0 and 6.44 for A30, while lnα_iCO2A_CO2D_CO2 changes between 7.90 for A0 and 8.08 for A30.

The aim of this article is to experimentally determine the role of the environment, consisting of a base oil (PAO), carbon nanomaterials, and optional other additives, as well as the kind of metal in contact with the lubrication film, in the stimulation of zinc dialkyldithiophosphate (ZDDP) additives’ effectiveness during protective film formation. This paper focuses on the role of carbon nanostructures in energy transportation and conversion during tribological processes. An antistatic additive (ASA) (not used in lubricating oils) for jet fuels was added to disturb the process of energy conduction (electric charges) through the lubricant film and thus determine how this disturbance affects the kinetics of the ZDDP triboreaction and, consequently, the linear wear. To achieve this research goal, two types of tribological testing devices were used: an Anton Paar tribometer (TRB) and a triboelectric tribometer (TET). The novelty of the present research is in the use of the method for disturbing the flow of charge/energy through the lubricant film with an antistatic additive for jet fuels, ASA, to influence the impact of this energy on the antiwear properties of ZDDP. The following conclusions were drawn: (1) carbon-based nanostructures, i.e., CNTs, AuCNTs, graphene, and fullerenes, are able to change the rate of chemical reactions of ZDDP during tribological processes; (2) CNTs have the ability to catalyze tribochemical reactions of ZDDP, while graphene and fullerenes are not able to perform this effectively; (3) AuCNT takes the role of an inhibitor during ZDDP’s triboreaction; and (4) by discharging electric charge/energy, ASA, in cooperation with CNT and AuCNT significantly reduces the rate of the ZDDP reaction.

This article reviews a study of the impact of synthetic biocomponents on the operational properties of aviation turbine engine fuels. The objective of the research was to simulate the functioning of aircraft fuel supply systems during the popularization of synthetic components and to provide a preliminary study of the impact of particles of various synthetic components on processes within aviation turbine engine fuel systems—particularly the aviation turbine engine combustion system. The authors produced Jet A-1 fuel blends with two selected synthetic components A and B, accepted as per the ASTM D4054 procedure. The concentrations of each of the components were selected to simulate fuel compositions in an aircraft tank that could result from supplying fuel with different synthetic components. Such blends were studied using selected laboratory tests, lubricity using the BOCLE rig and an engine test using the MiniJetRig stand. The parameters of the following power functions were adopted as criteria for a comparison of the combustion process involving fuels of various chemical structure: CO = am_fⁿ and (T_3max − T₂)/(T_3min − T₂) = a₁₁m_fⁿ¹, where CO—carbon monoxide content in exhaust gas; T_3max—maximum combustion chamber temperature; T_3min—minimum combustion chamber temperature; T₂—temperature upstream the combustion chamber; m_f—fuel mass flow rate. The test results for blends containing both synthetic components A and B were compared with change trends of similar parameters in fuels containing single synthetic components. Hard-to-predict and hard-to-define trend line deviations for the blends of both components A and B were observed. The obtained research results indicated a need to study the miscibility of fuels containing various synthetic components and to improve miscibility research methodologies.

The paper aims to verify the thesis that the reactivity model, developed in earlier research, can be used to compare the fuels combustion processes in turbine engines, which is important for predicting the behavior of different alternative fuels in combustion process. Synthetic blending components from alcohol to jet and hydroprocessed esters and fatty acids technologies and their blends with conventional jet fuel were used in tests. The undertaken laboratory tests reveal the differences between the properties of the tested fuels. Bench tests were carried out on a test rig with a miniature turbojet engine, according to authorial methodology. For each blend, on selected points of rotational speed the carbon oxide concentration in the exhaust gases was recorded. The obtained results allowed the formulation of empirical power functions describing relations between carbon oxide concentration and fuel mass flow rate. Based on general assumptions, the reactivity model was adopted to compare the combustion processes of the different fuels in turbine engines. The directions of further research on the development of the proposed model were indicated.

If a lubricant contains structures capable of conducting energy, reactions involving zinc dialkyldithiophosphate (ZDDP) may take place both very close to and away from the solid surfaces, with this indicating that ZDDP can be a highly effective anti-wear (AW) additive. The central thesis of this article is that the tribocatalytic effect is observed only when the energy emitted by the solids is transmitted by ordered molecular structures present in the lubricant, e.g., graphene. The friction tests were carried out for 100Cr6 steel balls in a sliding contact with uncoated or W-DLC-coated HS6-5-2C steel discs in the presence of polyalphaolefin 8 (PAO 8) as the lubricant, which was enhanced with graphene and/or ZDDP. There is sufficient evidence of the interactions occurring between ZDDP and graphene and their effects on the tribological performance of the system. It was also found that the higher the concentration of zinc in the wear area, the lower the wear. This was probably due to the energy transfer resulting from the catalytic decomposition of ZDDP molecules. Graphene, playing the role of the catalyst, contributed to that energy transfer.

Experimental studies reveal that the simultaneous addition of zinc dialkyl dithiophosphates (ZDDPs) and multi-wall carbon nanotubes (MWCNTs) to a poly-alpha-olefin base oil strongly reduces wear. In this paper, it is shown that MWCNTs promote the formation of an anti-wear (AW) layer on the metal surface that is much thicker than what ZDDPs can create as a sole additive. More importantly, the nanotubes’ action is indirect, i.e., MWCNTs neither mechanically nor structurally strengthen the AW film. A new mechanism for this effect is also proposed, which is supported by detailed tribometer results, friction track 3D-topography measurements, electron diffraction spectroscopy (EDS), and Raman spectroscopy. In this mechanism, MWCNTs mediate the transfer of both thermal and electric energy released on the metal surface in the friction process. As a result, this energy penetrates more deeply into the oil volume, thus extending the spatial range of tribochemical reactions involving ZDDPs.