Federico Bosi

Ethylene-tetra-fluoroethylene (ETFE) is a polymer employed in tension membrane structures with mechanical properties that strongly depend on time and temperature effects. A comprehensive understanding of the mutual influence of these variables and a unified viscoelastic constitutive model design can enable wider exploitation of ETFE in sustainable lightweight construction. This study presents a thermomechanical characterisation of ETFE foils through quasi-static tensile experiments spanning two orders of magnitude of strain rates, creep, relaxation, shear and dynamic cyclic tests in a wide range of temperatures suitable for building applications, from $-20^{\circ }\text{ C}$ − 20 ∘  C to $60^{\circ }\text{ C}$ 60 ∘  C . The experimental results in different material orientations are used to identify the limits of the linear viscoelastic domain, define the direction-dependent creep compliance master curves and calibrate the parameters of a plane stress orthotropic linear viscoelastic model, employing the Boltzmann superposition and the time-temperature superposition principles. The model has been numerically implemented using a recursive integration algorithm and its code is provided open source. A validation on independently acquired data shows the accuracy of the constitutive model in predicting ETFE behaviour within the linear viscoelastic regime usually adopted during structural design, with excellent extrapolation capabilities outside the range of the calibration data.

The function of all musculoskeletal joints depends on hierarchical structures spanning the molecular to whole joint scales. Investigating biomechanics across length scales requires correlative multiscale experimental methods. This study applies multimodal in situ synchrotron imaging techniques to spinal joints – focussing on the vertebral endplates – to explore relationships between structure and mechanical strain across spatial scales. Strain mapping using digital volume correlation combined with microarchitectural analysis reveals that high tensile and shear strains play a role in the cartilage to bone transition. Correlative imaging and diffraction show that bone contains narrower mineral nano-crystallites under greater compressive prestrain compared to calcified cartilage. We hypothesise that this multiscale structural adaptation supports the mechanical function of the intervertebral disc. Future applications of the techniques presented here have potential to help unravel biomechanical underpinnings of pathologies affecting mineralised tissue structure. The multiscale structure-function relationships uncovered here may inspire the design of biomaterials and orthopaedic implants.

The building construction industry is the largest anthropogenic source of pollution, with massive energy consumption and substantial CO₂ emissions. Lightweight tension structures allow the simultaneous implementation of several sustainable strategies by using recyclable low-carbon structural membranes offering a greener alternative to glass and other cladding materials. Their efficient structural load-bearing mechanisms result in significant weight savings in buildings and a drastic reduction of the environmental impact associated with material production, transportation, use, and disposal. A subgroup of lightweight materials, structural fabrics, and foils has been gaining popularity among designers and architects in recent years because of their desirable features such as high stiffness, strength, ductility, durability, and functional properties. While these structural membranes open new crucial perspectives for the clean energy transition and have been recently employed worldwide, their full potential is still limited by the lack of construction codes, advanced optimization tools, and comprehensive viscous-thermo-mechanical constitutive models. This chapter aims to foster the design of membrane structures by presenting their basic principles and recent advancements in the field. It covers the design approaches, employed materials and efforts in their characterization and modeling, implications on the sustainability of the built environment, current challenges, and future pathways from both academic research and engineering design viewpoints.