Jolanta Kwiatkowska-Malina

The presence of various pesticides in natural streams and wastewater is a significant environmental issue due to their high toxicity, which causes harmful consequences even at low quantities. One cost-effective method to remove these pollutants from water could be through adsorption using an inexpensive, easily obtained adsorbent—biochar. The presented research demonstrates the efficacy of applying biochar obtained from wheat grains to eliminate alachlor from water. The sorption properties of the biochar and the likely removal mechanisms are defined. The study found that the biochar removed 76–94% of alachlor, depending on the initial concentration of the pesticide in water. The maximum removal of alachlor (94%) using biochar occurred at an initial pesticide content of 1 mg/L. Both the pseudo-second-order kinetic (R² = 0.999) and the Langmuir isotherm models (R² = 0.996) effectively characterized the elimination of alachlor by wheat grain biochar. The biochar’s maximum adsorption capacity for alachlor was 1.94 mg/g. The analyzed biochar, with its micropores and various surface functional groups, was able to effectively adsorb alachlor and trap it within its structure.

The presence of various pesticides in natural streams and wastewater is a significant environmental issue due to their high toxicity, which causes harmful consequences even at low quantities. One cost-effective method to remove these pollutants from water could be through adsorption using inexpensive, easily obtained adsorbent - biochar. This study demonstrates the effectiveness of using biochar produced from wheat grains to eliminate alachlor from water. The sorption properties of the biochar and the likely removal mechanisms have been defined. The study found that the biochar removed 76-94% of alachlor, depending on the initial concentration of the pesticide in water. The pseudo-second-order kinetic model (R² = 0.999) and the Langmuir isotherm model (R² = 0.996) effectively characterized the elimination of alachlor by wheat grains biochar. The analyzed biochar, with its micropores and various surface functional groups, can effectively adsorb alachlor and trap it within its structure.

The spatial data sets of soil resources are essential for the interpretation of the site-specific ecosystems, not only concerning process investigations, but also for sustainable soil management The objective of the study was to attempt identification of the primary parameters influencing the rational management of soils available without the necessity of carrying out time-consuming and costly field and laboratory research. The research was carried out in the Pawłów commune (north-eastern part of the Świętokrzyskie Voivodeship, Poland). The research included the application of different methods and interpretation of source materials, including (i) digital soil-agricultural map, (ii) annex to the soil-agricultural map at a scale of 1:5000, (iii) soil quality contours, (iv) digital terrain model, and (v) orthophotomaps. Obtaining data concerning soil type and/or agricultural usefulness complexes would require conducting a generalisation process. Publicly available ortophotomaps and cartographic materials in the form of topographic maps and a numerical terrain model were analysed to determine the extent of soils to be protected. The rational management of space and soil resources can be visualised and documented using BIM technology; however, relying on GIS data is not the most straightforward task due to the lack of integration on the BIM-GIS line. This paper presents the current state of the art and attempts to address selected problems in this area.

When introducing innovative waste-derived amendments, their potential impact on soil retention capacity towards phosphorus (P) should be accounted for to limit its losses and thus water eutrophication. The study was aimed at evaluating P sorption properties of organic waste-derived amendments conifer woodchip biochar (BIO) and brown coal waste (BCW), and assessing their impact on P sorption properties in soil five years after their application in terms of limiting P losses from soils to the water sources. In batch tests samples of amendments and sandy acid soil (Haplic Luvisol) were exposed for 24 h to balancing solutions with a different P content, respectively 0–80 mg P L⁻¹ for amendments and 0–20 mg P L⁻¹ for soil. Three treatments were studied: (1) conifer woodchip biochar (BIO, (2) brown coal waste (BCW) and (0) soil without amendment (control). Organic amendments were applied to soil at a rate equivalent of 10.2 t C ha⁻¹ once at the start of the trial and they amounted to 24.2 t ha⁻¹ for BCW and 12.8 t ha⁻¹ for BIO. Based on the results of the bath tests and the Langmuir and Freundlich equations, sorption parameters of P were determined for BIO, BCW and the soil after their application. The maximum sorption capacities (S_max) of BIO and BCW were 832.3 and 250.4 mg kg⁻¹, respectively, and were controlled mainly by the organic surfaces of their structures. Within the range of concentrations used in the balancing solutions (5–20 mg P L⁻¹), sorption of P was generally higher in unfertilized soil compared to soil amended with BCW and BIO. The application of BIO significantly (p < 0.05) decreased the S_max (17%), while BCW decreased the bonding energy of P (k) by 15% compared to the untreated soil. The content of dissolved P increased significantly in the case of both BCW and BIO applications, which may indicate an increase in soil susceptibility to P losses. However, the effectiveness of these amendments in limiting P losses with the use of other doses and in different soil and climatic conditions cannot be excluded. Further research is recommended to better understand the effect of biochar feedstock and temperature of its production on P retention/losses in various types of soils.

This paper presents guidelines for the designation and development of locations for tourism and recreation in the countryside and on the city outskirts. The proposed criteria for designating these areas can be used in the development of strategic and planning documents. Using the METPRET and SWPR methodology in the area of the Mazowieckie Voivodeship, the research allows for the development of proposals to be included in the strategic documents of the voivodeship. These proposals indicated the need to find new areas with the potential for individual short-term tourism and recreation. In uncertain circumstances, an integrated approach to spatial policy is essential as it ensures the ability of urban, suburban, and rural areas to adapt to change and develop sustainably.

Groundwater is increasingly being used to help meet the Sustainable Development Goals (SDGs) 2 and 6 in many parts of the world, including Ghana. Against this background, hydrogeochemical and multivariate statistical studies were conducted to determine the physicochemical characteristics and suitability of groundwater in some agrarian communities in the Upper East Region of Ghana for drinking and irrigational farming. Additional analyses were also performed to identify potential health risks associated with the groundwater use and to better understand the hydrogeochemical processes controlling groundwater evolution for its effective management. The results showed that the groundwater is typically fresh; moderate to very hard in character; undersaturated with calcite, dolomite, halite, and gypsum; and supersaturated with quartz and amorphous silica. The physicochemical characteristics of the groundwater are controlled by both anthropogenic and natural activities/processes, such as fertilizer application, irrigation return flows, rock weathering, and forward/reverse cation exchange. The total dissolved solids (TDS) (165–524 mg/L), electrical conductivity (EC) (275–873 μS/cm), sodium percentage (Na%; 9.05–17.74%), magnesium ratios (MR) (29.25–53.3%), permeability index (PI) (36.6–74.6%), and sodium adsorption ratio (SAR) (0.20–0.51) point to the possibility of using the groundwater for irrigation, however, with some salinity control. The water quality and health risk analysis also revealed that the groundwater can be used for drinking; however, the high concentrations of fluoride, which can cause noncarcinogenic health issues such as dental and skeletal fluorosis in both adults and children, must be reduced to the WHO required level of 1.5 mg/L.

Humic acids (HAs) regulate soil chemical reactivity and improve many soil functions. The amendment of soil with organic materials increases soil organic matter (SOM) content and promotes the formation of HAs. However, the effect of the type, frequency and duration of amendment, and pedoclimatic conditions on SOM transformation and HA structural changes remains unclear. Herein, four experimental field sites (S1–4) with short-to-long-term organic fertilisation schemes were used to assess the effects of such factors, i.e., S1: loamy sand amended once with farmyard manure (FYM), brown coal waste (BCW), and biochar (BIO) for 0.5 and 1.5 years; S2: silt loam amended once with BIO for 8 years; S3: loamy sand amended every 5 years with FYM for 94 years; and S4: clayey silt amended every 2 years with FYM for 116 years. All HAs were extracted and analysed for structural differences by elemental analysis (EA), attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR), solid-state cross polarisation magic angle spinning nuclear magnetic resonance spectroscopy (CP/MAS ¹³C-NMR), and differential scanning calorimetry (DSC). Results from EA, FTIR, and NMR showed that the long-term samples from S3 (treatments, T9–T10) and S4 (T11–T12) had the greatest aromatic characteristics, which increased with FYM amendment (T10 and T12). These agreed with DSC data, which indicated lower aliphatic contents compared with other samples. Samples from S2 (T7–T8), with receded amendment effects, had less aromatic and greater aliphatic characteristics compared with the short-term samples, S1 (T1–T6). In S1, structural changes were limited, but aromaticity increased with BIO (T3 and T6) compared with corresponding FYM (T1 and T4) and BCW (T2 and T5) amendments due to inherently high aromatic groups in the former. Overall, the results showed that the site (due to differences in pedoclimatic conditions), field age of OM, and amendment frequency were the main factors that influenced HA structure, and hence SOM transformation. Regular, long-term organic amendment increases the aromatic characteristics of HAs, which can improve soil functionality, but short-term structural improvements are achievable only when amending material is rich in aromatic compounds.

Plants are a key link in the trophic chain and therefore may determine the global circulation of pollutants, including heavy metals (HMs). In the context of sustaining soil functions associated with food safety, the bioavailability of HMs should be reduced to a minimum needed for adequate plant nutrition. The objective of the study was to analyse the bioavailability of zinc, lead and cadmium in phacelia (Phacelia tanacetifolia Benth.) under conditions of varied soil pH and doses of brown coal-based organo-mineral amendment so-called the Rekulter. The experiment was carried out on Haplic Luvisols in field stone pots that sank into the ground, with the following HM content (in mg kg⁻¹ of soil): 90.0 (Zn), 60.4 (Pb) and 0.80 (Cd). The Rekulter was applied to the soil in the amounts of 180, 360 and 720 g per pot. The bio-accumulation index (BI) was calculated as a ratio of a HM content in a plant to its total content in a soil sample, and it was used to evaluate bioavailability. The application of the Rekulter reduced the bioavailability of the studied heavy metals: the lowest BI values were found in the case of Pb. The uptake of HMs by phacelia was the smallest for the highest applied Rekulter dose at a soil pH of approximately 6.0. The bioavailability of Zn, Pb and Cd was influenced by soil pH and organic matter content, reducing their mobility and possible environmental risks. The Rekulter reduced HM bioavailability: the lowest bio-accumulation index (BI) values were found in the case of Pb. The application of the Rekulter into soil improved the physical, chemical and biological properties of soil, including the reduction of contaminant bioavailability.

At the end of October 2018, a storm of unprecedented strength severely damaged the forests of the eastern sector of the Italian Alps. The affected forest area covers 42,500 ha. The president of one of the damaged regions asked for help from the University of Padua. After eight months of discussion, the authors of this article wrote a consensus text. The sometimes asper debate brought to light some crucial aspects: 1) even experienced specialists may have various opinions based on scientific knowledge that lead to conflicting proposals for action. For some of them there is evidence that to restore a destroyed natural environment it is more judicious to do nothing; 2) the soil corresponds to a living structure and every ecosystem’s management should be based on it; 3) faced with a catastrophe, people and politicians find themselves unarmed, also because they rarely have the scientific background to understand natural processes. Yet politicians are the only persons who make the key decisions that drive the economy in play and therefore determine the near future of our planet. This article is an attempt to respond directly to a governor with a degree in animal production science, who formally and prudently asked a university department called “Land, Environment, Agriculture and Forestry” for help before taking decisions; 4) the authors also propose an artistic interpretation of facts (uncontrolled storm) and conclusions (listen to the soil). Briefly, the authors identify the soil as an indispensable source for the renewal of the destroyed forest, give indications on how to prepare a map of the soils of the damaged region, and suggest to anchor on this soil map a series of silvicultural and soil management actions that will promote the soil conservation and the faster recovery of the natural dynamic stability and resilience.