Xi Li

In this work, a hydrophobically associative polymer (HAP) was mixed with β-cyclodextrin and epichlorohydrin polycondensate (β-CDP) in an aqueous solution to enhance the intermolecular interaction through host–guest inclusion between hydrophobes and cyclodextrins. Results showed that the host–guest interaction improved the thickening ability and viscoelasticity of the HAP solution and maintained its shear thinning behavior. The host–guest inclusion system demonstrated special viscosity–temperature curves and variable activation energy. Enhanced oil recovery (EOR) performance tests showed that the oil increment produced by the host–guest inclusion system was 5.5% and 9.3% higher than that produced by the HAP and the partially hydrolyzed polyacrylamide solution, respectively. Compared with pure HAP, β-CDP/HAP has a better comprehensive performance and is more attractive for EOR in high-temperature reservoirs.

A manganese dioxide-modified red mud (Mn-RM) was developed as an adsorbent for the effective removal of lead ions (Pb²⁺) from wastewater. Various methods were used to characterize the prepared Mn-RM, analyze its adsorption performance, and evaluate the associated environmental risks post-adsorption. The results revealed that Mn-RM has a large surface area (38.91 m²/g) and a developed porous structure (0.02 cm³/g). The adsorption process exhibited good agreement with the Langmuir isotherm and pseudo-second-order kinetic models, showcasing a theoretical maximum saturation adsorption capacity of 721.35 mg/g. The adsorption mechanism primarily involves electrostatic attraction, ion exchange, and chemical precipitation. The optimal treatment conditions were determined by utilizing a response surface model, resulting in a maximum Pb²⁺ removal efficiency of 87.45% at pH 5.21, a dosage of 0.83 g/L, and an initial concentration of 301.04 mg/L. The risk assessment code (RAC) for each heavy metal in Mn-RM was less than 1%, indicating low environmental risk. Furthermore, the synthetic toxicity index (STI) values showed a significant decrease post-treatment. This study introduces the concept of “controlling waste with waste”, offering a cost-effective approach to both utilizing red mud and removing aqueous Pb²⁺ while ensuring environmental safety and minimal ecological impact.

This work evaluates an approach to improve the enhanced heavy oil recovery performance of hydrophobic associating polymer. A polymeric system based on water-soluble hydrophobic associating polymer (WSHAP) and cyclodextrin (CD) polymer was proposed in this work. Addition of CD polymer to WSHAP forms interpolymer bridges by inclusion of CD groups with hydrophobic tails, and thereby the network structure is strengthened. The proposed system offers good viscoelasticity, pronounced shear thinning, and interesting viscosity-temperature relations. Sand pack tests indicated that the proposed system can build high resistance factor during the propagation in porous media, and its moderate adsorption phenomenon was represented by the thickness of the adsorbed layer. The relationship between effective viscosity and oil recovery increment indicated that the proposed system can significantly reduce the residual oil saturation due to the “piston-like” propagation. The overall oil recovery was raised by 5.7 and 24.5% of the original oil in place compared with WSHAP and partially hydrolyzed polyacrylamide (HPAM), respectively.