Seyed Mehdi Borghei

A two-stage anaerobic-aerobic sequencing reactor system was developed in order to enhance the removal of biological phosphorus in the sequencing of combined reactors. Combining both aerobic and anaerobic designs in one reactor improved the efficiency and reduced the construction and operating costs. The combination of an upflow anaerobic fixed bed (UAFB) and a floating activated sludge aerobic bioreactor was designed with respective Kaldnes packing ratios of 90 and 30% for the anaerobic and aerobic sections. The controlled parameters were pH levels within a neutral range, a temperature of 37°C, mixed liquor suspended solids (MLSS) of 1220 and 1030 mg/L for the aerobic and anaerobic sections, respectively, and an attached growth that was equal of 743 and 1190 mg/L for the aerobic and anaerobic sections, respectively. Tests were conducted for three different initial phosphorus concentrations (12.8, 32.0, and 44.8 mg/L), two different volumes for each section, and four chemical oxygen demands (CODs) (500, 1000, 1200, and 1400 mg/L). The results demonstrated that, generally, the phosphorus removal in the anaerobic section fell significantly by increasing the inlet COD, and the maximum removal occurred at COD = 500 mg/L. More than 90% of the phosphorus was removed in the aerobic section at COD = 500 mg/L. In other words, the best performance of the reactor was when the ratio of the COD : N : P = 100 : 5 : 2, composition of phosphorus in industrial wastewater.

Over the past few decades, anaerobic-aerobic wastewater treatment systems have been widely used in industrial and municipal wastewater treatment. This study was conducted to examine the effects of combined anaerobic-aerobic bioreactors in the removal of chemical oxygen demands (COD) while reducing phosphate concentrations in synthetic wastewater. In this project, a bioreactor with the dimensions of 10 cm × 10 cm × 80 cm with respective Kaldnes packing ratios of 90 and 30% for the anaerobic and aerobic sections was designed. A combined anaerobic-aerobic reactor’s structure made changing hydraulic retention times only possible by adjusting the volume of its aerobic and anaerobic sections. In the first case, the anaerobic and aerobic sections of the reactor occupied 30 and 50 cm of its height, respectively. The height of the anaerobic section decreases to 12.5 cm in the second case. In aerobic and anaerobic sections, pH was within a neutral range, temperature was 37°C. MLSS (mixed liquor suspended solids) was 1220 and 1030 mg/L, and attached growth was 743 and 1190 mg/L respectively. In order to evaluate COD in the wastewater, three different initial phosphorus concentrations were tested: 12.8, 32.0 and 44.8 mg/L, as well as four COD: 500, 1000, 1200 and 1400 mg/L. Considering the results, COD removal is greater than 80% when the valve 2 is in the anaerobic section outlet regardless of the concentration of phosphate. In this case, the best result is for inlet COD of 500, where the reactor can eliminate more than 90%. When the COD concentration reaches 1000 to 1400 ppm, the reactor’s COD removal efficiency declines to 60%.

Microplastics are currently known to be among the most detrimental environmental. The research on ways to counteract these pollutions and the use of microorganisms for the biological decomposition of various plastic polymers have evolved over the recent years. In this regard, the present study collected effluents from the southern Tehran treatment plant and separated and counted the microplastics present in them, it was found that the least number of microplastics was found in the samples of the summer season and the highest number of microplastics was found in the samples of the spring season. In these samples, particles could be identified in three forms: fiber, fragment, and film, which revealed that the most frequently observed microplastics were polypropylene and then polyethylene. These microplastics combine with the microbes in the culture medium. Three microbial colonies that survived were then separated and identified, which revealed that these bacteria included Achromobacter denitrificans (sample B), Bacillus amyloliquefaciens (sample C), and Pseudomonas aestusnigri (sample E). Moreover, the decomposition of polypropylene and polyethylene microplastics exposed to isolates was examined through various methods. Results of cellular gravity examination indicated that the average weight reduction in the PP sample exposed to B and E bacterial isolates was 38.2% and 58.9%, respectively. In the SEM images, the surface of the polymers of these two isolates is more uneven. Moreover, the mean cellular weight reduction for PE-based microplastic exposed to isolate C was 13.3%, the results of FT-IR tests showed that the peaks in the samples exposed to strains B and E were accompanied by changes compared to the control sample (G). The results of the TGA test also confirm the greater effectiveness of the bacterial strain E. It was based on the polymer structure. In the Raman spectrum of sample E, some peaks have been removed and new peaks with other shifts have appeared in their place. Results were confirmed by carbon dioxide emission tests and the produced protein amount.

Investigations have shown the traces of antibiotics in surface water, groundwater, wastewater treatment plants, and drinking water. However, conventional wastewater treatment is not entirely effective for vancomycin degradation. Advanced oxidation is one of the most widespread methods of antibiotic degradation in aqueous media. Vancomycin was quantified by high-performance liquid chromatography. The Response Surface Methodology (RSM) based on Central Composite Design (CCD) was used to explore and optimise the effect of the independent variables on vancomycin degradation. Independent variables were as follows: pH (3–11), vancomycin concentration (15–75 mg/L), TiO₂–clinoptilolite (25–125 mg in 250 mL reactor volume), the temperature (25–45°C), and the reaction time (15–75 min). The validity and adequacy of the model were confirmed by the corresponding statistics (F–value = 111.5, correlation coefficient R² = 0.98, adjusted R² = 0.97, and prediction R² = 0.95). The vancomycin degradation efficiency was 97% under optimal conditions (pH = 5, vancomycin concentration = 30 mg/L, TiO₂-clinoptilolite content = 50.2 mg in a 250 mL reactor volume, temperature = 32.24°C, and reaction time = 50.9 min). This process followed the zero-order reaction kinetics model (R² = 0.98), and the removal rate of Total Organic Carbon (TOC) under optimal conditions was 56%. The results indicated that supporting TiO₂ on clinoptilolite particles could increase the photocatalytic properties.

Rotating dissolved air flotation (RDAF) has been utilized for several decades in paper‐recycling wastewater treatment; however, it has rarely been addressed in the literature, which makes research into this system challenging and complicated. However, in this work, a full‐scale industrial wastewater treatment system for a paper‐recycling mill in Mazandaran province, Iran, was evaluated. Experiments indicated that under the same wastewater and chemical conditions, there are differences in the removal efficiencies. This finding was investigated by conducting simulation in ANSYS CFX R18.0 and experimentation simultaneously. Thus, the main purpose of this research was to optimize the operation to achieve the highest removal efficiencies in a cost‐effective manner. For simulation, the flow was considered as a two‐phase homogeneous flow with a continuous solid–fluid phase, which discharges into the separation zone at different scenarios. Particles with diameters of 250, 500 and 1000 μm were introduced at four frame rotating speeds of 0.125, 0.25, 0.5 and 0.75 rpm. Measured qualitative parameters of the effluent included COD, BOD, TSS, TDS, conductivity and turbidity, whose removal efficiency ranges were (32.2%–54.8%), (32.7%–54.47%), (94.5%–97.1%), (0.47%–0.55%), (0.48%–0.59%) and (more than 55%), respectively. Moreover, the optimum rotating speeds of the frame for particles with diameters of 250, 500 and 1000 μm were obtained as 0.25, 0.5 and 0.125 rpm, respectively; these values were compared and found to agree with the experimental results.