HKHijiri Kito

Hijiri Kito

*This is an algorithmically generated author record based on publicly available information.

Current Organizations / Institutes

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Previous Organizations / Institutes

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Hijiri Kito has a total of 53 co-authors. Here are the top co-authors by number of shared publications:


Latest Publications

  • Fabrication of multi-filament(Ba,A)Fe2As2 (A: Na, K) HIP round wires and a small superconducting coil

    by Sunseng Pyon, Takamasa Ito, Ryosuke Sakagami, Tsuyoshi Tamegai, Satoshi Awaji, Hijiri Kito, Shigeyuki Ishida, Hiroshi Eisaki, Yoshiyuki Yoshida, Hideki Kajitani

    We report the fabrication and systematic characterizations of multi-filament (Ba,A)Fe2As2 (A: Na, K) round wires processed under high pressure. The evaluated transport and magnetic critical current density show clear core-number dependence. This trend originates from degradation of the superconducting core during the wire-drawing process, degradation of the concentric texturing of the core, and the enhanced sausaging effect of the core (revealed by x-ray tomography) as the number of cores increases. Details of the characterizations and suggestions for the improvement of the fabrication process are discussed. We constructed a superconducting magnet using seven-filament (Ba,K)Fe2As2 hot-isostatic pressed round wires. The generated magnetic field and critical current (I c) of the coils at 4.2 K are 1.0 kOe and 18 A, respectively. Measurements of the I c of short segments picked up from the coil show that there is enough room for improvements.


  • Direct observation of the electronic structure of the layered phosphide superconductor ZrP2−xSex

    by A. Ino, T. Kubo, S. Ishizaka, H. Takita, W. Mansuer, K. Shimada, S. Ueda, H. Kitô, I. Hase, S. Ishida, et al.

    A layered phosphide superconductor, AP2−xXx (A = Zr and Hf; X = Se and S), is expected to be a foothold for the quest of new superconductors. Here, we report direct experimental observation of the electronic structure of ZrP2−xSex (x=0.55, 0.60, 0.75, and 0.85), using high-resolution bulk-sensitive hard x-ray photoemission spectroscopy. Core-level spectra of P show two distinct components separated by an energy of 1.2 eV. These reveal that the P atoms at two crystallographic sites have different valence charges, −1 and −3, playing different chemical roles, and furthermore that the occupation ratio between them varies monotonically with x. We observed valence-band features at −6.5, −4.0, and −1.4 eV together with a clear Fermi edge. The consistency with first-principles calculation indicates that the electronic states at Fermi level are mainly ascribed to the Zr 4d band. Notably, a hump feature near the Fermi level shows an upward energy shift by 0.49 eV with decreasing x from 0.85 to 0.55. The energy shifts of spectral features substantiate that replacing Se2− with P3− serves as hole doping, shedding light on the tunability of ZrP2−xSex. These findings on the electronic structure establish an essential basis for understanding the superconductivity in the AP2−xXx system.


  • New Intermetallic Ternary Phosphide ChalcogenideAP2−xXx(A= Zr, Hf;X= S, Se) Superconductors with PbFCl-Type Crystal Structure

    by Hijiri Kitô, Yousuke Yanagi, Shigeyuki Ishida, Kunihiko Oka, Yoshito Gotoh, Hiroshi Fujihisa, Yoshiyuki Yoshida, Akira Iyo, Hiroshi Eisaki

    We have synthesized a series of intermetallic ternary phosphide chalcogenide superconductors, AP2−xXx (A = Zr, Hf; X = S, Se), using the high-pressure synthesis technique. These materials have a PbFCl-type crystal structure (space group P4/nmm) when x is greater than 0.3. The superconducting transition temperature Tc changes systematically with x, yielding dome-like phase diagrams. The maximum Tc is achieved at approximately x = 0.7, at which point the Tc is 6.3 K for ZrP2−xSex (x = 0.75), 5.5 K for HfP2−xSex (x = 0.7), 5.0 K for ZrP2−xSx (x = 0.675), and 4.6 K for Hfp2−xSx (x = 0.5). They are typical type-II superconductors and the upper and lower critical fields are estimated to be 2.92 T at 0 K and 0.021 T at 2 K for ZrP2−xSex (x = 0.75), respectively.


  • Optical response of FeAs-based compounds

    by M. Nakajima, S. Ishida, K. Kihou, Y. Tomioka, T. Ito, C.H. Lee, H. Kito, A. Iyo, H. Eisaki, K.M. Kojima, et al.


  • Simplest nontoxic double-layered cuprate Ba2CaCu2O4(O,F)2 superconductor with a transition temperature of 108K

    by P. M. Shirage, D. D. Shivagan, Y. Tanaka, Y. Kodama, H. Kito, A. Iyo

    We report synthesis and properties of the simplest double-layered cuprate superconductor Ba2CaCu2O4(O,F)2 . A superconducting transition temperature (Tc) has been achieved as high as 108K for a sample with a nominal fluorine content y=1.6 in Ba2CaCu2O6−yFy . The Tc is the highest among double-layer cuprates that are free of toxic elements such as Hg, Tl, and Pb so that the nontoxic Ba2CaCu2O4(O,F)2 will be promising for application. As y decreases from approximately 2, the a -axis length decreases and the Tc increases from 40to108K . The material is underdoped at large y and as y decreases, the doping moves toward an optimally doped state.


  • NMR Initiatives on Understanding High‐temperature Superconductivity

    by Y. Kitaoka, H. Mukuda, S. Shimizu, M. Abe, A. Iyo, Y. Tanaka, H. Kito, K. Tokiwa, T. Watanabe

    ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

  • Comparative study of the electronic structure ofMgB2andZrB2

    by C. Jariwala, A. Chainani, S. Tsuda, T. Yokoya, S. Shin, Y. Takano, K. Togano, S. Otani, H. Kito

    X-ray photoemission spectroscopy is used to compare the electronic structures of MgB2 and ZrB2. The B 1s core levels in high-quality MgB2 and ZrB2 exhibit a single asymmetric peak typical of a metallic boride. The Mg 2p core level shows a single peak with negligible intensity in charge-transfer satellites and no correlation effects. The Mg 2p and B 1s core-level spectra exhibit a broad bulk plasmon feature centered at about 22 eV from the main peak, in good accord with calculations. The measured valence bands are consistent with band-structure calculations indicating a higher density of states (DOS) at EF for MgB2 compared to ZrB2. The high Tc in MgB2 is due to p-derived DOS, while ZrB2 is dominated by d-derived states at EF.