Baoyu Liu

Perovskite light-emitting diodes (PeLEDs) have attracted tremendous attention due to their ideal optoelectronic properties, such as high color purity, high fluorescence quantum yield, and tunable light color. The perovskite layer plays a decisive role in the performance of PeLEDs and the solvent engineering of the perovskite layer is the key technological breakthrough in preparing high quality films. In this study, we have proposed the strategy of adding different amounts of solvents to the perovskite precursor solution to optimize the morphology of perovskite films and device performance. As a result, with the decreasing concentration of perovskite precursor solution, the perovskite film morphology is smoother and more favorable for carrier injection and combing, which induces an enhanced external quantum efficiency. The maximum luminance of PeLEDs was increased from 1667 cd/m² to 9857 cd/m² and the maximum current efficiency was increased from 6.7 cd/A to 19 cd/A. This work provides a trend to achieve improved film morphology and device performance for perovskite optoelectronic devices.

The electron transport layer (ETL) is critical to carrier extraction for perovskite solar cells (PSCs). Moreover, the morphology and surface condition of the ETL could influence the topography of the perovskite layer. ZnO, TiO₂, and SnO₂ were widely investigated as ETL materials. However, TiO₂ requires a sintering process under high temperature and ZnO has the trouble of chemical instability. SnO₂ possesses the advantages of low-temperature fabrication and high conductivity, which is critical to the performance of PSCs prepared under low temperature. Here, we optimized the morphology and property of SnO₂ by modulating the concentration of a SnO₂ colloidal dispersion solution. When adjusting the concentration of SnO₂ colloidal dispersion solution to 5 wt.% (in water), SnO₂ film indicated better performance and the perovskite film has a large grain size and smooth surface. Based on high efficiency (16.82%), the device keeps a low hysteresis index (0.23).

The investigation of crystal growth is crucial for us to improve the film quality and photophysical properties of CH₃NH₃PbI₃ (MAPbI₃). In the two-step spin-coating process, the crystal structure could be modulated by controlling the growth conditions of PbI₂ and CH₃NH₃I (MAI) layers. In this paper, the PbI₂ layer was treated with annealing under different times. A liquid–liquid diffusion (LLD) mechanism is proposed to modify the deposition of MAI precursor solution and enhance the flatness of organic–inorganic hybrid perovskite film. Furthermore, the perovskite films are prepared using different concentrations of MAI. The evolution process of perovskite structure is observed by modulating the concentration of MAI. The spin-coating of moderate MAI tends to form high quality MAPbI₃ films with enhanced absorption and carrier extraction capabilities. The high concentration of MAI would cause the perovskite phase transition, which provides a novel perspective to modulate the structure of organic–inorganic hybrid perovskite in the two-step spin-coating process, although it deteriorates the device performance.

In recent years, perovskite materials have been the subject of great progress in optoelectronic devices. The perovskite layer is the light absorption layer of perovskite solar cells (PSCs), and the majority charge carriers type play a crucial role in the formation of a P–N junction. In this paper, the light absorption layer of PSCs was Rb-mixed at a low concentrations by using a two-step spin-coating method, which could adjust the majority charge carriers type in perovskite films from N-type to P-type, and it has little influence on the crystal structure and light absorption capacity of perovskite. In addition, low concentration Rb-mixing is different from high concentration Rb-mixing. With increasing Rb-mixing concentration, the perovskite grains does not change shape. Although the quality of perovskite films deteriorated and the PL peaks exhibit a slight blue shift after mixing, the efficiency only slightly decreased, indicating that the new P-N hetero-junction was still formed after mixing, which provided a new idea for the future research of homo-junction PSCs.

The film quality of the electron transport layer (ETL) plays an important role in improving the performance of perovskite solar cells (PSCs). In order to reduce the effect of rough fluorine-doped SnO₂ (FTO)substrate on the film quality of the TiO₂ ETL, multiple cycles of spin-coating were employed to realize optimized TiO₂ film and improve the performance of PSCs with rough FTO. The results show that TiO₂ ETL was optimized most effectively using two spin-coating cycles, obtaining the best performance of PSCs with rough FTO. The carbon electrode-based PSCs were then demonstrated. Our work discusses the feasibility of low-quality rough FTO for the fabrication of PSCs and photodetectors to reduce costs.

Flexible perovskite solar cells (PSCs) have received increasing attention in wearable and portable devices over the past ten years. The low-temperature process of electron transport layer plays a key role in fabricating flexible PSCs. In this paper, we improve the performance of flexible PSCs by controlling the thermodynamic procedure in the low-temperature annealing process of solution-processed TiO₂ layers and modulating the precursor concentration of (6,6)-phenyl c₆₁ butyric acid methyl ester (PC₆₁BM) deposited on fluorine-doped tin oxide (FTO)/TiO₂ substrate. The results show that slowing down evaporation rate of residual solvent and adopting PC₆₁BM of appropriate precursor concentration are confirmed to be effective methods to improve the performance of flexible PSCs. We also demonstrate carbon electrode-based flexible PSCs. Our work expands the feasibility of low temperature process for the development of flexible perovskite photodetectors and light-emitting diodes, as well as flexible PSCs.

In recent years, flexible perovskite solar cells have drawn tremendous attention in the field of wearable devices, and optimization of perovskite composition plays an important role in improving film quality and photophysical properties. At present, some researchers have only studied A-site organic cations mixing or X-site halide anions mixing in the ABX₃ structure of perovskite, but there are few reports on co-mixing of A-site and X-site ions in flexible perovskite solar cells. In this paper, we mainly try to study the effects of different concentrations of mixed formamidine methylamine halide (FA_xMA_1-xBr_xCl_yI_1-x-y) precursor solutions on the quality and photophysical properties of perovskite films under low temperature process. We conclude that the film quality and photophysical properties reached the best results when the optimized precursor solution concentration was 60:6:6. The investigation on composition optimization in this experiment laid the foundation for the improvement of the performance of flexible perovskite solar cells. We also use the results of this experiment to prepare flexible perovskite solar cells based on carbon electrodes, which are expected to be applied in other flexible optoelectronic or electro-optical devices.