Gopal Panthi

Poly(vinyl acetate) nanofibers doped with PdS-ZnS nanoparticles (PdS-ZnS/PVAc nanofibers) were fabricated via an electrospinning technique. PdS-ZnS nanoparticles were in situ synthesized by adding (NH₄)₂S solution to poly(vinyl acetate)/zinc acetate/palladium acetate solution. Electrospinning of the formed colloidal solution led to the formation of poly(vinyl acetate) nanofibers containing uniformly distributed PdS-ZnS nanoparticles. The prepared samples were characterized by field emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy and Fourier transform infrared spectroscopy. In photocatalytic activity investigation, the PdS-ZnS/PVAc nanofibers showed remarkably enhanced performance towards water photosplitting under solar irradiation compared to the ZnS/PVAc nanofibers. This enhanced performance is attributed to the synergistic effects of heterostructured PdS-ZnS nanoparticles, which can improve photogenerated charge migration and solar light absorption.

Graphitic carbon nitride (g-C₃N₄), a metal-free polymer semiconductor, has been recognized as an attractive photocatalytic material for environmental remediation because of its low band gap, high thermal and photostability, chemical inertness, non-toxicity, low cost, biocompatibility, and optical and electrical efficiency. However, g-C₃N₄ has been reported to suffer from many difficulties in photocatalytic applications, such as a low specific surface area, inadequate visible-light utilization, and a high charge recombination rate. To overcome these difficulties, the formation of g-C₃N₄ heterojunctions by coupling with metal oxides has triggered tremendous interest in recent years. In this regard, zinc oxide (ZnO) is being largely explored as a self-driven semiconductor photocatalyst to form heterojunctions with g-C₃N₄, as ZnO possesses unique and fascinating properties, including high quantum efficiency, high electron mobility, cost-effectiveness, environmental friendliness, and a simple synthetic procedure. The synergistic effect of its properties, such as adsorption and photogenerated charge separation, was found to enhance the photocatalytic activity of heterojunctions. Hence, this review aims to compile the strategies for fabricating g-C₃N₄/ZnO-based Z-scheme and S-scheme heterojunction photocatalytic systems with enhanced performance and overall stability for the photodegradation of organic pollutants. Furthermore, with reference to the reported system, the photocatalytic mechanism of g-C₃N₄/ZnO-based heterojunction photocatalysts and their charge-transfer pathways on the interface surface are highlighted.

For the first time, heterostructures of electrospun carbon nanofibers decorated with Ag₃PO₄ nanoparticles (Ag₃PO₄/CNFs) were successfully fabricated by the combination of simple and versatile electrospinning technique followed by carbonization and incorporation of Ag₃PO₄ nanoparticles via colloidal and precipitation synthesis approaches. The as-fabricated heterostructures were characterized by FESEM with EDS, XRD, TEM with HRTEM, FTIR and UV-vis diffuse reflectance spectroscopy. Experimental results revealed that the heterostructure obtained by colloidal synthesis approach (Ag₃PO₄/CNFs-1) was decorated with small-sized (~20 nm) and uniformly distributed Ag₃PO₄ nanoparticles on the surface of CNFs without any evident agglomeration, while in the heterostructure obtained by the precipitation synthesis approach (Ag₃PO₄/CNFs-2), CNFs were decorated with agglomerated and bigger-sized Ag₃PO₄ nanoparticles. The visible-light-driven photocatalytic investigation signified that the Ag₃PO₄/CNFs-1 heterostructure can exhibit higher performance towards the photodegradation of MB dye solution compared to the Ag₃PO₄/CNFs-2 heterostructure, which could be attributed to the synergistic effect between the uniformity and small size of Ag₃PO₄ nanoparticles and CNFs that can serve as a conductivity network to prevent the recombination of charge carriers. Moreover, the mechanism of the photocatalytic activity as-prepared heterostructure is proposed.

Present work reports the enhancement in photocatalytic performance of Ag₃PO₄ nanoparticles through sulfate doping and anchoring on Polyacrylonitrile (PAN)-electrospun nanofibers (SO₄²⁻-Ag₃PO_4/PAN-electrospun nanofibers) via electrospinning followed by ion-exchange reaction. Morphology, structure, chemical composition, and optical properties of the prepared sample were characterized using XRD, FESEM, FTIR, XPS, and DRS. The anchoring of SO₄²⁻-Ag₃PO₄ nanoparticles on the surface of PAN-electrospun nanofibers was evidenced by the change in color of the PAN nanofibers mat from white to yellow after ion-exchange reaction. FESEM analysis revealed the existence of numerous SO₄²⁻-Ag₃PO₄ nanoparticles on the surface of PAN nanofibers. Photocatalytic activity and stability of the prepared sample was tested for the degradation of Methylene blue (MB) and Rhodamine B (RhB) dyes under visible light irradiation for three continuous cycles. Experimental results showed enhanced photodegradation activity of SO₄²⁻-Ag₃PO₄/PAN-electrospun nanofibers compared to that of sulfate undoped sample (Ag₃PO₄/PAN-electrospun nanofibers). Doping of SO₄²⁻ into Ag₃PO₄ crystal lattice could increase the photogenerated electron–hole separation capability, and PAN nanofibers served as support for nanoparticles to prevent from agglomeration.

In this work, flexible ternary composites of cobalt-doped cadmium selenide/electrospun carbon nanofibers (Co-CdSe@ECNFs) for photocatalytic applications were fabricated successfully via electrospinning, followed by carbonization. For the fabrication of the proposed photocatalysts, Co-CdSe nanoparticles were grown in situ on the surface of ECNFs during the carbonization of precursor electrospun nanofibers obtained by dispersing Se powder in the electrospinning solution of polyacrylonitrile/N,N-Dimethylformamide (PAN/DMF) containing Cd²⁺ and Co²⁺. The photocatalytic performance of synthesized samples is investigated in the photodegradation of methylene blue (MB) and rhodamine B (RhB) dyes. Experimental results revealed the superior photocatalytic efficiency of Co-CdSe@ECNFs over undoped samples (CdSe@ECNFs) due to the doping effect of cobalt, which is able to capture the photogenerated electrons to prevent electron–hole recombination, thereby improving photocatalytic performance. Moreover, ECNFs could play an important role in enhancing electron transfer and optical absorption of the photocatalyst. This type of fabrication strategy may be a new avenue for the synthesis of other ECNF-based ternary composites.

Heterojunction nanofibers of PAN decorated with sulfate doped Ag₃PO₄ nanoparticles (SO₄²⁻-Ag₃PO₄/PAN electrospun nanofibers) were successfully fabricated by combining simple and versatile electrospinning technique with ion exchange reaction. The novel material possessing good flexibility could exhibit superior antibacterial property over sulfate undoped species (Ag₃PO₄/PAN electrospun nanofibers). FESEM, XRD, FTIR, XPS and DRS were applied to characterize the morphology, phase structure, bonding configuration, elemental composition, and optical properties of the as fabricated samples. FESEM characterization confirmed the successful incorporation of SO₄²⁻-Ag₃PO₄ nanoparticles on PAN electrospun nanofibers. The doping of SO₄²⁻ ions into Ag₃PO₄ crystal lattice by replacing PO₄³⁻ ions can provide sufficient electron-hole separation capability to the SO₄²⁻-Ag₃PO₄/PAN heterojunction to generate reactive oxygen species (ROS) under visible light irradiation and enhances its antibacterial performance. Finally, we hope this work may offer a new paradigm to design and fabricate other types of flexible self-supporting negative-ions-doped heterojunction nanofibers using electrospinning technique for bactericidal applications.