Eslam Deef-Allah

This study developed a conditioning framework for the sustainable use of waste-engine-oil-modified binders (WEOMBs) in 100% reclaimed asphalt pavement (RAP) mixtures. Binder with a penetration grade of 60–70 was modified by 5%, 8%, and 10% waste engine oil (WEO) by binder weight. The WEOMBs were subjected to physical, chemical, and compositional analyses. For 10% WEOMB, the results showed a reduction of the binder softening point by 18% and an increase in binder penetration of almost 8%, enhancing softening and the workability of the binder. Binder chemical and compositional analyses verified that WEO altered the binder’s colloidal structure by augmenting aliphatic fractions and molecular mobility, while diminishing resin content and promoting saturates plus aromatics content. At 160 °C for 45 min, the RAPs were conditioned with 1% WEOMB (containing different WEO percentages) by the total weight of the RAP mixture. Among all the conditioned mixtures, the 100% RAP modified with 1% WEOMB, containing 8% WEO, showed the best performance. Dynamic modulus and phase angle analyses demonstrated that RAP conditioning reduced excessive stiffness and produced a balanced viscoelastic response, enhancing the rutting resistance. The proposed conditioning framework demonstrated the feasibility of producing fully recycled mixtures with balanced mechanical performance and adequate cracking resistance.

Asphalt–rubber binders (A-RBs) have a long and deep history of use; however, little is known regarding the interrelated chemical behaviors and miscibility of rubber with the asphalt fractions [saturates, aromatics, resins, and asphaltenes (SARA)]. This study comprehensively attempted to address this knowledge deficiency by employing Fourier transform infrared spectroscopy (FTIR) to investigate the chemical evolution of A-RBs. A-RB interacted at 190 °C and 3000 min⁻¹ for 8 h was deemed to have the optimal rheological performance. FTIR of the liquid fractions of A-RB 190–3000 showed a prominent chemical shift in the SARA fractions, with new peaks that showed rubber polybutadiene (PB) and polystyrene migration into asphaltenes. Meanwhile, decreases in peaks with C–H aromatic bending and S=O stretching for the A-RB 190–3000 saturates showed that the rubber absorbed low-molecular-weight maltenes during swelling. Peaks associated with C=C aromatic appeared in saturates and aromatics, respectively, emphasizing that unsaturated components migrated from the rubber into the asphalt. Thermal analysis showed that rubber dissolution for this sample reached 82%. While a PB peak existed in asphaltenes of A-RB 220–3000, its intensity was diminished by depolymerization, thus compromising the integrity of the migrated rubber structure and generating less rheological enhancement. This study concludes that FTIR characterization of SARA fractions offers valuable insights into the interactions between asphalt and rubber, and that regulated processing conditions are essential for enhancing binder performance.

Asphalt recycling technologies have advanced considerably over the last few decades with the utilization of reclaimed asphalt pavements (RAP) and recycled asphalt shingles (RAS). Characterizing aged and heterogeneous binders in these mixtures is challenging, particularly with limited extracted binders. This study suggests a data-driven framework that considers the rheological, chemical, and thermal characteristics to predict the binders’ performance. Ninety-seven mixtures with 0–35% of the asphalt binder replaced with RAP/RAS binders were included as cores from the field, plant-produced mixtures, and laboratory-fabricated mixtures. The binders were chemically quantified using aging, aromatic, and aliphatic indices. Thermal analyses of the binders involved the percentage of the thermal residue. The framework predicted the rheological resistance of the binders to rutting and cracking using linear and nonlinear machine learning models. The nonlinear models outperformed the linear models for the three rheological parameters. The nonlinear models achieved a 69% reduction in the root mean square error (RMSE) for rutting, a 37% reduction in the RMSE for fatigue cracking, and a 21% reduction in the RMSE for thermal cracking. However, the nonlinear models overfitted for block cracking and had an RMSE 41% higher than the linear models, despite a perfect correlation (R = 1.00). The feature importance demonstrated the strong effects of the chemical and thermal parameters on rheological prediction. The data-driven framework can successfully support efforts to better manage asphalt recycling by predicting the binder performance.

Understanding the development of an asphalt binder’s internal network structure is essential when interacting asphalt and crumb rubber. Thus, the focus of this study was to reveal the development of asphalt–rubber binders’ (A-RBs) network structures at different interaction times and their correlation with performance. Atomic force microscopy (AFM) was utilized to image the morphologies of the binders, and the binders’ performances were explored rheologically with a dynamic shear rheometer. Extending the interaction time to 8 h and utilizing a soft binder altered the network structures from agglomerated dispersoids—minuscule distributed phase zones embedded in the continuous matrix of the asphalt binder—to well-organized lamellar structures. At 8 h, using a softer binder increased stiffness by 25% and elasticity by 15%, accelerating early rubber dissolution. Extending the interaction time from 4 to 8 h increased rubber dissolution by 5–23%, depending on the binder type. The 150% increase in stress overshoot for A-RBs with the soft binder versus those with the stiff one reflects the development of the network structure. At 8 h, the soft binder reduced the AFM mean phase angle by 10% and the standard deviation by 64%, indicating a more homogeneous and stable network than that obtained with the stiff binder. Thus, the 8 h interaction time and soft binder facilitated rubber swelling and enhanced component diffusion, aiding in the formation of a homogeneous network.

This study proposes that a proactive quality assurance (QA) framework for asphalt mixes with recycled materials, i.e., reclaimed asphalt pavement and recycled asphalt shingles, should be developed. Quality control (QC) is generally concerned with the contractor’s obligation to produce mixes which meet the job mix formula (JMF) targets. However, QA considers the variability in fabrication processes and materials and offers monitoring by evaluating the contractor’s performance. Although both aggregate gradations and asphalt contents were within the JMF specifications, the recovered binders revealed significant differences from the contract binders in the JMF. Rheological tests indicated increased stiffness and elasticity but reduced capability to relax thermal stresses in binders recovered from plant–lab- and lab-fabricated mixtures, compared to field mixtures. Thermal-rheological analysis models corroborated these results by demonstrating reduced decomposition areas for more aged binders, enhancing performance prediction—especially for limited binder amounts. The creation of a QA decision matrix facilitated uniform, performance-oriented assessments. The matrix indicated only 23% of the mixtures satisfied JMF criteria and reported QC data—predominantly field mixtures—underscoring the impact of the fabrication mechanisms and the use of soft binders. This matrix integrates statistical analysis and binder performance assessments as a tool for verifying material compliance and tracking contractor efficiency. It reflects a transition from traditional QC toward a more proactive QA framework for sustainable pavements.

Assessing the binder performance of thermal characterization is critical for quality control. This is pertinent for recovered binders from mixtures, which may not be in adequate quantities to evaluate their performance, particularly in mixtures containing reclaimed asphalt pavement (RAP). The present study deployed a thermogravimetric analyzer to evaluate compositional changes in recovered binders from RAP-containing mixtures, focusing on thermograph and derivative of thermograph (DTG) characteristics and correlating the results to rheological features. Incorporating RAP in mixtures influenced recovered binders’ DTG shapes, reducing low-combusted components (%LCC) and increasing residues (%R). The recovered binder from the zero-RAP-containing mixture showed a 4.36% increase in %LCC and a 1.97% decrease in %R compared to the short-term aged original binder. Binders recovered from RAP-containing mixtures exhibited greater stiffness than the short-term aged original binders. The %LCC dropped from 7.22% to 25.52%, while the %R increased from 20.69% to 33.06%. Uncertainty analyses showed that the DTG area and %R had the least uncertainty and that the %LCC had greater uncertainty. Analysis through regression revealed that DTG area and %R can predict G*/sinδ well, showing a correlation between better thermal stability and binder stiffness. This research puts a number on the correlation between thermal and rheological properties, which helps to improve quality control for binders.

Open Access Article Comparing the Performance of Recycled Calcined Bauxite vs. Locally Available Aggregate as Components in High Friction Surface Treatment Applications by Eslam Deef-Allah 1 , Korrenn Broaddus 2 and Magdy Abdelrahman 3 1 Ph.D, Assistant Professor, Department of Construction Engineering and Utilities, Zagazig University, Egypt 2 Former Graduate Student, Department of Civil, Architectural, … Continue reading "Comparing the Performance of Recycled Calcined Bauxite vs. Locally Available Aggregate as Components in High Friction Surface Treatment Applications"

It has been decades since recycled asphalt shingles (RAS) or reclaimed asphalt pavement (RAP) were utilized in asphalt mixes.

Modifying asphalt mixtures with recycled components is common practice due to their environmental and economic merits. However, due to the oxidized air-blown asphalt binders in recycled asphalt shingles (RAS) and aged binders in reclaimed asphalt pavement (RAP), adopting RAP and/or RAS as recycled components in asphalt mixtures influences the performance of the overall asphalt binder in these mixtures. The percentages of recycled components and performance grade (PG) of virgin asphalt binders (VABs) in the asphalt mixtures govern the performance of the overall asphalt binder. Therefore, the main idea of this study was to investigate the effect of the percentages of RAP/RAS and PGs of the VABs on the load- and non-load-associated cracking resistance of the extracted asphalt binders (EABs) from field cores. Rheological tests were performed on the EABs to assess the load-associated cracking (fatigue cracking) and non-load-associated cracking (low-temperature and block cracking) resistance. The VAB's PGs, mixtures' ages, and the percentages of RAP/RAS affected the EABs' cracking resistance. When compared to EABs from mixtures with lower amounts of RAP, employing RAS in the asphaltic mixtures improved EABs' resistance to fatigue and block cracking. However, using RAS deteriorated EABs' resistance to low-temperature cracking. Increasing the RAP's percentage in the asphaltic mixtures decreased the cracking resistance of the EABs. Strong relationships were established between EABs' load- and non-load-associated cracking resistance.