Wojciech Bochnowski

The aim of this study was to produce a coating for protective glass glued to touch displays with high antibacterial effectiveness. This paper presents the structural, mechanical, optical, and antibacterial properties of a TiO₂:Ag–Pt coating prepared by dual reactive DC and RF magnetron sputtering. Characterization techniques used include XRD, TEM with EDS, SEM, AFM, nanoindentation for hardness and Young’s modulus, wettability tests, and optical property analysis. The coating exhibited columnar crystals with a width of 30–50 nm. Crystals of anatase, rutile, silver, and platinum with a size of up to 3 nm were identified. The coating deposited on glass had a concentration of 5.0 ± 0.2% at. Ag and 4.4 ± 0.1% at. Pt. The value of the optical band gap energy, corresponding to the direct transition, was 3.36 eV, while Urbach’s energy was in the order of 500 meV. The hydrophilic coating had a roughness RMS = 1.8 ± 0.2 nm, hardness HV = 6.8 ± 0.5 GPa, and Young’s modulus E = 116 ± 8 GPa. A unique combination of the phase composition of the TiO₂:Ag–Pt coating, metallic Ag and Pt nanoparticles in a ceramic matrix of anatase and rutile crystallites resulted a >90% reduction of Staphylococcus aureus bacteria. This antibacterial effect was attributed to the activation of the doped semiconductor under visible light via plasmon resonance of the Ag and Pt nanoparticles, as well as a light-independent antibacterial action due to Ag⁺ ion release. In contrast, commercial antibacterial coatings typically achieve only around 60% bacterial reduction.

The aim of this study is to determine the influence of the amount of magnesium in Al-Mg alloys and strain rate on the grain refinement and mechanical properties of the material as determined in a dynamic tensile test. Hydrostatic extrusion was used to process the material. This method is not commonly used to impose severe plastic deformation of Al-Mg alloys. The article presents the results of static and dynamic strength tests on aluminium alloys subjected to plastic deformation in the hydrostatic extrusion process. Technically pure aluminium Al99.5 and three aluminium alloys with different magnesium content, Al-1Mg, Al-3Mg and Al-7.5Mg, were used in the tests. The samples were subjected to static tests using the uniaxial tensile test machine and dynamic tests using a rotary hammer. Compared to pure aluminium, increasing the magnesium content in Al-based alloys strengthened them in hydrostatic extrusion (logarithmic strain ε = 0.86) and caused an increase in the static ultimate tensile stress R_m, relative strain ε_r and the value of the yield stress. For strengthened aluminium alloys, an increase in the strain rate from 750 to 1750 s⁻¹ caused an increase in the dynamic ultimate tensile stress from 1.2 to 1.9 times in relation to the static ultimate tensile stress. The increase in magnesium content results in the formation of a larger strengthening phase, influences a different state of stress during dynamic loading and leads to a change in the orientation of the fracture surface. It was also found that an increase in magnesium content is associated with an increased number of voids, which is also directly proportional to the strain rate in the dynamic rotary hammer test.

Mo-Mo₂N nanocomposite coating was produced by reactive magnetron sputtering of a molybdenum target, in the atmosphere, of Ar and N₂ gases. Coating was deposited on Ti6Al4V titanium alloy. Presented are the results of analysis of the XRD crystal structure, microscopic SEM, TEM and AFM analysis, measurements of hardness, Young’s modulus, and adhesion. Coating consisted of α-Mo phase, constituting the matrix, and γ-Mo₂N reinforcing phase, which had columnar structure. The size of crystallite phases averaged 20.4 nm for the Mo phase and 14.1 nm for the Mo₂N phase. Increasing nitrogen flow rate leads to the fragmentation of the columnar grains and increased hardness from 22.3 GPa to 27.5 GPa. The resulting coating has a low Young’s modulus of 230 GPa to 240 GPa. Measurements of hardness and Young’s modulus were carried out using the nanoindentation method. Friction coefficient and tribological wear of the coatings were determined with a tribometer, using the multi-cycle oscillation method. Among tested coatings, the lowest friction coefficient was 0.3 and wear coefficient was 10 × 10⁻¹⁶ m³/N∙m. In addition, this coating has an average surface roughness of RMS < 2.4 nm, determined using AFM tests, as well as a good adhesion to the substrate. The dominant wear mechanism of the Mo-Mo₂N coatings was abrasive wear and wear by oxidation. The Mo-Mo₂N coating produced in this work is a prospective material for the elements of machines and devices operating in dry friction conditions.

Refill Friction Stir Spot Welding (RFSSW) shows great potential to be a replacement for single-lap joining techniques such as riveting or resistance spot welding used in the aircraft industry. In this paper, the fatigue behaviour of RFSSW single-lap joints is analysed experimentally in lap-shear specimens of Alclad 7075-T6 aluminium alloy with different thicknesses, i.e., 0.8 mm and 1.6 mm. The joints were tested under low-cycle and high-cycle fatigue tests. Detailed observations of the fatigue fracture characteristics were conducted using a scanning electron microscope (SEM) with energy dispersive X-ray spectroscopy (EDS). The locations of fatigue failure across the weld, fatigue crack initiation, and propagation behaviour are discussed on the basis of the SEM analysis. The possibility of predicting the propagation of fatigue cracks in RFSSW joints is verified based on Paris’s law. Two fatigue failure modes are observed at different load levels, including shear fracture mode transverse crack growth at high stress-loading conditions and at low load levels, and destruction of the lower sheet due to stretching as a result of low stress-loading conditions. The analysis of SEM micrographs revealed that the presence of aluminium oxides aggravates the inhomogeneity of the material in the weld nugget around its periphery and is a source of crack nucleation. The results of the fatigue crack growth rate predicted by Paris’s law were in good agreement with the experimental results.

The paper presents the results of experimental investigations, the aim of which was to determine the degree of weakening of skin sheet of the thin-walled structure through a single-row welded joints made by Refill Friction Stir Spot Welding (RFSSW) technology. At the beginning, a short...