Giseon Baek

We present two-epoch JWST NIRSpec and MIRI observations of the young protostar EC 53 (V371 Ser), a periodically variable source with well-characterized quiescent and burst phases. The spectra in both epochs show absorption in the CO overtone (∼2.3 μ m) and fundamental (∼4.6 μ m) bands and the H ₂ O stretching (∼2.7 μ m) and bending (∼6.0 μ m) modes. We also obtained high-resolution ( R ≈ 45,000) IGRINS spectra during the burst to constrain the CO overtone line profiles. Local thermodynamic equilibrium (LTE) slab modeling yields gas temperatures of ∼1800 K (CO overtone) and ∼1200 K (CO fundamental), consistent with the overtone tracing hotter gas at smaller radii. The H ₂ O stretching-mode absorption shows no compelling evidence for variability, and the current JWST CO overtone data do not provide a robust constraint on overtone variability. In contrast, the CO fundamental and H ₂ O bending-mode features weaken by a factor of ∼2 during the burst, which is most naturally explained by continuum changes rather than large variations in absorbing gas. To quantify continuum dilution, we introduce a “relative veiling” that treats the quiescent spectrum as an internal reference and measures the change in the continuum excess between the two epochs. This formalism yields burst-to-quiescent hot-continuum ratios of 2.9 ± 0.2 for the CO overtone and 1.71 ± 0.11 for the CO fundamental. Using a viscous-disk prescription, these imply representative accretion-rate ratios of ∼3.6 and ∼2.0, respectively. The differing ratios suggest that inner-disk regions traced at different temperatures, and thus radii, respond differently across the burst cycle, consistent with episodic mass buildup in the inner disk during quiescence followed by more efficient transport through the innermost disk onto the protostar during the burst.

We present the 1.6–28 μ m spectra of the young protostar EC 53, obtained with the James Webb Space Telescope (JWST) Near Infrared Spectograph Integral Field Unit and MIRI Medium Resolution Spectroscopy during the quiescent and burst phases of its periodic brightness variations. To isolate ice absorption features, we modeled and removed the mid-infrared silicate dust absorption using a dedicated continuum-fitting procedure. In the optical depth spectrum, we first fit the broad H ₂ O ice features and then decomposed the major ice components, including NH ₃ , CO ₂ , CH ₃ OH, CO, and CH ₄ , by matching laboratory profiles for both pure and H ₂ O-mixed ices. The 4.62 μ m and 6.85 μ m bands are attributed to OCN ^– and NH ₄ ⁺ ions, respectively. Minor or tentative contributions from complex species (HCOOH, H ₂ CO, CH ₃ COOH, CH ₃ CHO, CH ₃ CH ₂ OH, and NH ₂ CHO) are also considered for our global ice analysis. The silicate-corrected spectra reveal no measurable change in any ice absorption band between the two phases, indicating that moderate and short-period accretion bursts in EC 53 do not significantly alter the physical or chemical state of the ices within its envelope. The derived abundances of these major species relative to H ₂ O significantly exceed the values typically observed toward other embedded protostars. Finally, we place the ice inventory of EC 53 in the context of other protostellar systems observed with JWST, highlighting that its chemically rich, thermally quiescent ice reservoir provides a benchmark for studying ice evolution under episodic accretion.

Crystalline silicates form at high temperatures (>900 K) (refs. ^1,2). Their presence in comets^3,4,5,6 suggests that high-temperature dust processing occurred in the early Solar System and was subsequently transported outwards to comet-forming regions. However, direct evidence for this crystallization and redistribution in Sun-like protostars has remained unknown. By comparing James Webb Space Telescope mid-infrared spectra of the periodically bursting protostar EC 53 (ref. ⁷), we detect crystalline silicate (forsterite and enstatite) emission features that appear only during the burst. The emergence of these features indicates active crystal formation by thermal annealing in the hot inner disk during the accretion burst. We also detect a nested outflow—a collimated atomic jet enclosed by slower molecular outflows, consistent with magnetohydrodynamic wind models⁸. This configuration provides a mechanism for the outward transport of freshly crystallized silicates⁹. To our knowledge, our results provide the first direct observational evidence of in situ silicate crystallization during episodic accretion bursts in a very young star still embedded in its dense envelope. Although we do not directly detect grains transported to the outer disk, the observed trends are consistent with outward redistribution, indicating that both dust processing and transport occur during the earliest and most dynamic stages of star formation.

Despite the organic molecule inventory detected in the Orion Kleinmann–Low Nebula (Orion KL), acetaldehyde (CH₃CHO)—one of the most ubiquitous interstellar aldehydes—has not been firmly identified with millimeter-wave interferometry. We analyze extensive Atacama Large Millimeter/submillimeter Array archival data sets (142–355 GHz) to search for acetaldehyde, revealing two distinct acetaldehyde emission peaks and one component with more complex kinematic structures. One peak aligns with MF10/IRc2, where emissions of other O-bearing complex organic molecules are rarely reported, while the other is coincident with the ethanol peak in the southwest region of the hot core. The MF10/IRc2 detection suggests unique chemistry, possibly influenced by repeated heating events. In contrast, codetection with ethanol indicates an ice origin and suggests a potential chemical relationship between the two species. We determine acetaldehyde column densities and kinetic temperatures toward these two peaks under local thermodynamic equilibrium assumptions and compare its distribution with ethanol and other molecules that have an aldehyde (HCO) group, such as methyl formate, glycolaldehyde, and formic acid. Toward the ethanol peak, the observed abundance ratios between HCO-containing species are analyzed using a chemical model. The model suggests two key points: (1) the destruction of ethanol to form acetaldehyde in the ice may contribute to the observed correlation between the two species; and (2) a long cold-collapse timescale and a methyl formate binding energy similar to or lower than water are needed to explain the observations. The relative abundance ratios obtained from the model are highly sensitive to the assumed kinetic temperature, which accounts for the high spatial variability of the aldehyde ratios observed toward Orion KL.

We present an investigation of complex organic molecules (COMs) in the spatially resolved Keplerian disk around V883 Ori, an eruptive young star, based on a spectral survey carried out with the Atacama Large Millimeter/submillimeter Array in Band 6 (220.7−274.9 GHz). We identified about 3700 molecular emission lines and discovered 23 COMs in the disk. We estimated the column densities of the COMs detected, using the iterative LTE line-fitting method. According to our analyses, using only optically thin lines is critical to deriving the reliable column densities of COMs. Therefore, covering a large frequency range is important for the studies of COMs. The most distinct phenomenon found from the spectra of the V883 Ori disk is that nitrogen-bearing COMs other than CH₃CN are missing, whereas various oxygen-bearing COMs, except for the CH₂OH-bearing molecules, are detected. The missing CH₂OH-bearing COMs may indicate the warm water-ice dominant environment for forming COMs. We compared our results with various objects in different evolutionary stages, from Class 0 hot corinos to a solar system comet 67P/Churyumov-Gerasimenko, to examine the effect of evolution on the COM compositions. In general, the COM abundances relative to methanol in V883 Ori are higher than in the hot corinos and hot cores, while they are comparable to the cometary values. This may indicate the planet-forming material chemically evolves in the disk midplane after being accreted from the envelope. In addition, as found in the comet 67P/Churyumov-Gerasimenko, nitrogen might also be trapped as ammonium salt within the dust grains in the V883 Ori disk.

Emission lines from complex organic molecules in B335 were observed in four epochs, spanning a luminosity burst of about 10 yr duration. The emission lines increased dramatically in intensity as the luminosity increased, but they have decreased only slightly as the luminosity has decreased. This behavior agrees with expectations of rapid sublimation as the dust temperature increases, and of slower freeze-out after the dust temperature drops. Further monitoring of this source, along with detailed chemical models, will exploit this natural laboratory for astrochemistry.

An unbiased spectral survey of V883 Ori, an eruptive young star, was carried out with the Atacama Large Millimeter/submillimeter Array in Band 6. The detected line emission from various molecules reveals morphological/kinematical features in both the Keplerian disk and the infalling envelope. A direct infall signature, redshifted absorption against the continuum, has been detected in CO, HCO⁺, HCN, HNC, and H₂CO. HCO⁺ and SO show large armlike structures that probably connect the infalling envelope to the disk. HCN and H₂CO reveal a distinct boundary between the inner and outer disks and tentative spiral structures connecting the outer disk to the inner disk. HNC shows a large central emission hole (r ∼ 0.″3) due to its chemical conversion to HCN at high temperatures. HDO emission, a direct tracer of the water sublimation region, has been detected in the disk. Molecular emission from complex organic molecules is confined within the HDO emission boundary, and HCO⁺ has an emission hole in its distribution due to its destruction by water. Together, these features suggest that the current episode of eruption in V883 Ori may be triggered by the infall from the envelope to the outer disk, generating a spiral wave that propagates inward and greatly enhances the accretion onto the central star.

We present the spectra of complex organic molecules (COMs) detected in HOPS 373SW with the Atacama Large Millimeter/submillimeter Array (ALMA). HOPS 373SW, which is a component of a protostellar binary with a separation of 1500au, has been discovered as a variable protostar by the JCMT transient monitoring survey with a modest (∼30%) brightness increase at submillimeter wavelengths. Our ALMA target-of-opportunity observation at ∼345 GHz for HOPS 373SW revealed extremely young chemical characteristics with strong deuteration of methanol. The dust continuum opacity is very high toward the source center, obscuring line emission from within 0.″03. The other binary component, HOPS 373NE, was detected only in C¹⁷O in our observation, implying a cold and quiescent environment. We compare the COM abundances relative to CH₃OH in HOPS 373SW with those of V883 Ori, which is an eruptive disk object, as well as other hot corinos, to demonstrate the chemical evolution from envelope to disk. High abundances of singly, doubly, and triply deuterated methanol (CH₂DOH, CHD₂OH, and CD₃OH) and a low CH₃CN abundance in HOPS 373SW compared to other hot corinos suggest a very early evolutionary stage of HOPS 373SW in the hot corino phase. Since the COMs detected in HOPS 373SW would have been sublimated very recently from grain surfaces, HOPS 373SW is a promising place to study the surface chemistry of COMs in the cold prestellar phase before sublimation.

We report the detection of the millimeter CH₃OH masers including a new detection of class I (11_0,11–10_1,10A) and class II (6_1,5–5_2,4E) maser transitions toward the high-mass protostar S255IR NIRS3 in postburst phase. The CH₃OH emissions were detected as a mixture of maser and thermal characteristics. We examine the detected transitions using an excitation diagram and local thermodynamic equilibrium model spectra and compare the observed properties with those of thermal lines. Class II CH₃OH maser transitions showed distinctive intensity and velocity distributions from those of thermal transitions. Bright, distinct emission components in addition to the fragmented and arc-shaped emissions are only detected in class I CH₃OH maser transitions toward southern and western directions from the protostellar position, implying the presence of the slow outflow shocks.