Eui Hyun Cho

The upgrading of waste plastic pyrolysis oil (WPPO) through hydrotreating (HDT) is crucial for transforming plastic waste into chemical feedstock. The catalytic role of HDT is of paramount importance for this conversion procedure. In this study, bimetallic catalysts based on Ni and Mo were prepared using the surfactant-assisted melt-infiltration (SAMI) method, completely omitting the use of liquid solutions. Thorough analysis via X-ray diffraction, transmission electron microscopy, and hydrogen temperature-programmed reduction confirmed that the addition of Span60 surfactant effectively prevented the aggregation of Ni and Mo components, reduced the size of metal particles, and improved the dispersion of active sites on the zeolite supports. Consequently, NiMo-based catalysts incorporating Span60, synthesized using the SAMI method, exhibited a superior catalytic performance in the removal of nitrogen, sulfur, and chloride impurities from WPPO during HDT compared to those without surfactant. Specifically, the catalyst prepared with Span60 exhibited 15% higher nitrogen conversion compared to the catalyst prepared without Span60.

The Paris Agreement requires the world to put the best efforts to reduce CO₂ emissions, due to the global warming problems. As a promising technology corresponding to this greenhouse gas treatment, the CO₂ methanation process a.k.a power to gas (PtoG), which catalytically converts CO₂ into methane, has been in the limelight. To develop an efficient catalytic process, it is necessary to design a low-cost and high-efficiency catalyst for high CO₂ conversion and CH₄ selectivity. In this study, we have developed Ni/γ-Al₂O₃ catalysts by the one-step melt-infiltration method, where both aging and calcination are done in one pot. For enhancement of the catalytic activity and selectivity, sufficient Ni content (>25 wt %) and a high dispersion (−1. And the various characteristic analyses (Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), H₂-chemisorption, temperature programmed reduction (TPR), etc.) were performed to confirm the effects on the catalytic performance. As a result, based on the experiments and the characterization data, the 30 wt %-Ni catalyst (Ni particles size = 11 nm) showed the best CO₂ conversion at 300 °C and the 20 wt % one having the highest Ni dispersion (Ni particles size = 8.8 nm), which showed the best intrinsic reaction rate and CH₄ selectivity in the entire temperature range.