Xiaohong Zhang

Low density polyethylene (LDPE) is a good insulating material which is widely used in cable materials due to its excellent insulation and processability. However, in the DC high voltage environment, pure polyethylene materials still face many problems, the most serious of which is space charge accumulation. The cable will inevitably be subjected to tensile stress during production, installation and operation. Therefore, it is of great significance to study the effect of stretching on the microstructure and space charge characteristics for polymers and their composites. In this paper, MMT/LDPE micro-composites, SiO₂/LDPE nano-composites and MMT-SiO₂/LDPE micro-nano-composites were prepared by melt blending. Mechanical stretching was carried out on pure LDPE materials and the above three kinds of composite materials. Each material was stretched according to four stretching ratios, which are 0%, 5%, 10% and 20%. The crystal morphology was observed by polarizing microscope (PLM), the crystallization perfection was tested by differential scanning calorimetry (DSC), and the space charge distribution inside each sample was measured by pulsed electro-acoustic (PEA) method. At the same time, the average charge density and apparent charge mobility for samples during depolarization were calculated and analyzed. The experimental results show that when the pure low density polyethylene sample is not stretched, its crystal structure is loose. Tensile stress can make the loose molecular chains align in LDPE and improve its crystalline structure, which is helpful to restrain the accumulation of space charge inside the sample. For MMT/LDPE, SiO₂/LDPE and MMT-SiO₂/LDPE composites, their internal crystal structure is compact. Stretching will destroy their original crystal structure at first, and then disorder molecular chains inside the three composite materials. With the increase of stretching ratio, the molecular chains begin to orient along the direction of force, the crystallization tends to be perfect gradually, and the space charge accumulation in samples also decreases. From the calculation results of apparent charge mobility for each sample, with the increase of stretching ratio, the trap depth and trap density inside samples firstly increased and then decreased.

Low-density polyethylene (LDPE) is an important thermoplastic material which can be made into films, containers, wires, cables, etc. It is highly valued in the fields of packaging, medicine, and health, as well as cables. The method of improving the dielectric property of materials by blending LDPE with inorganic particles as filler has been paid much attention by researchers. In this paper, low-density polyethylene is used as the matrix, and montmorillonite (MMT) particles and silica (SiO₂) particles are selected as micro and nano fillers, respectively. In changing the order of adding two kinds of particles, a total of five composite materials were prepared. The crystallization behavior and crystallinity of five kinds of composites were observed, the ε_r and tanδ changes of each material were investigated with frequency and temperature, and the power frequency (50 Hz) AC breakdown performance of materials were measured. The differential scanning calorimetry (DSC) and X-ray diffraction (XRD) results show that the crystallinity of the composites is higher than that of LDPE. Experimental data of dielectric frequency spectra show that the dielectric constants of micro–nano composites and composites with added MMT particles are lower than LDPE, the dielectric loss of composites can be improved by adding MMT particles. The experimental data of dielectric temperature spectra show that the permittivity of SiO₂-MMT/LDPE is still at a low level under the condition of 20~100 °C. In terms of breakdown field strength, the SiO₂/LDPE composite material increased by about 17% compared with the matrix LDPE, and the breakdown field strength of the materials SiO₂-MMT/LDPE and MMT-SiO₂/LDPE increased by about 6.8% and 4.6%, respectively.

Low-density polyethylene (LDPE) is one of the most comprehensive products used as insulation materials in power equipment. How to improve its dielectric properties by doping inorganic particles in LDPE has always been the focus of many researchers. In this paper, silica (SiO₂) particles and montmorillonite (MMT) particles were added to LDPE, the order of adding particles was changed, and different micro-nano composites was made. The crystallization characteristics of composites were analyzed, the curves of the conductance current with the change of field intensity were analyzed, and the space charge distribution of each material were investigated. The results of crystallization show that the crystalline properties and crystallinity of the composites are higher than the matrix LDPE, the addition of SiO₂ particles increases the composites’ crystallinity significantly, and the intercellular spacing of micro-nano composites is the smallest among all materials. The curve of conductance current versus electric field intensity shows that the tightness of the crystal structure can effectively hinder the movement of the molecular chain, inhibit carrier migration, while shortening the free travel of electrons, thereby reducing the electric conduction current of the material. The experimental results of the space charge accumulation curve further show that the compact crystal structure of the material is beneficial to the dissipation of space charge in the dielectric.

Leakage coaxial cable is a kind of coaxial cable with various slot structures on the outer conductor of the cable. It can transmit signal and transmit or receive signal and has dual functions of signal transmission line and antenna. Leakage cable has the advantages of strong environmental adaptability, uniform signal coverage, and less attenuation. It is not only widely used in closed or semiclosed space with high signal reception quality, such as tunnels, subway, underground parking lot, and elevators but also can realize security and theft-proof monitoring and protection in some areas, such as oil wells, mining fields and natural resource protection areas, military fortresses, museums, airports, banks, and schools. This paper introduces the classification and electrical parameters of leaky coaxial cables. On the basis of U-groove leaky coaxial cables, the relationship between the parameters of groove holes in U-groove and the loss of leaky coaxial cables is simulated and analyzed by HFSS software. The improved method of U-groove structure is obtained, and the curved hook-groove leaky coaxial cables are designed according to this method. The simulation results show that the coupling loss of the cable is lower than that of the U-groove leakage cable, and the transmission loss is still within the national standard. It lays a theoretical foundation for the design and development of leaky coaxial cable with low coupling loss.

In this article, low-density polyethylene (LDPE) was used as a matrix polymer, the Micro-ZnO and Nano-ZnO particles were used as the inorganic filler. With the melt blending method, the Nano-ZnO/LDPE(Nano-ZnO particles doping into LDPE), Micro-ZnO/LDPE(Micro-ZnO particles doping into LDPE) and Micro-Nano-ZnO/LDPE (Nano-ZnO and Micro-ZnO particles doping into LDPE in the same time) composites were prepared. Then, the inorganic filler and the composites were dealt with structural characterizations and analysis by Fourier transform infrared (FTIR), Polarization microscope (PLM), and Differential scanning calorimeter (DSC). Besides, these samples were dealt with (alternating current) AC breakdown performance test. The micro-experimental results showed that the Micro-ZnO and Nano-ZnO particles doping reduced the crystal size and increased the crystallization rate. With the change of cell structure, the crystallinity of composites increased. The crystallinity order of different samples was as follows: LDPE < Micro-ZnO/LDPE < Nano-ZnO/LDPE < Micro-Nano-ZnO/LDPE. From the breakdown of the experimental result, with the same mass fraction of the different inorganic doping of particles, the breakdown strength of these composites was different. The Nano-ZnO particle doping could improve the breakdown strength of composites effectively. Among them, the breakdown strength of Nano-ZnO/LDPE and Micro-Nano-ZnO/LDPE were 11% higher and 1.3% lower than that of pure LDPE, respectively. Meanwhile, the breakdown strength of Micro-composite was the lowest but its Weibull shape coefficient was the highest. Therefore, the Micro-ZnO doping was helpful for the Nano-ZnO dispersing in the matrix, which produced the Micro-Nano-synergy effects better.

In order to analyze the partial discharge (PD) characteristics of a liquid/solid composite medium in an oil-filled submarine cable terminal; we have designed five discharge models including needle-plate, plate-to-plate air gap, surface, slide-flash and suspension potential. At the same time, the ultrasonic signals of PD have been extracted through the typical fault model research platform of oil-filled submarine cable equipment. First, we use SureShrink threshold wavelet denoising to suppress the ultrasonic signal noise. Secondly, through the multi-scale analysis of the signal, the energy distribution maps of five different types of PD are obtained; the analysis found that needle-plate discharge, suspension discharge, and slide-flash discharge have better resolution; and plate-to-plate air gap discharge and creeping discharge have similar characteristics and are not easy to distinguish. Finally, we designed six characteristic parameters of the ultrasound signal, and screened three feature quantities by a back propagation (BP) neural network to distinguish between plate-to-plate air gap discharge and surface discharge. In summary, the method of combining multi-scale analysis and neural networks is used to distinguish the five discharge types by extracting the characteristic values of the characteristic signals.

Based on the principle of operating an oil-filled-cable operation and the explanation of the oil-filling process provided in the cable operation and maintenance manual of submarine cables, this study investigated oil-pressure variation caused by gas generated as a result of cable faults. First, a set of oil-filled cables and their terminal oil-filled simulation system were designed in the laboratory, and a typical oil-filled-cable fault model was established according to the common faults of oil-filled cables observed in practice. Thereafter, ultrasonic signals of partial discharge (PD) under different fault models were obtained via validation experiments, which were performed by using oil-filled-cable simulation equipment. Subsequently, the ultrasonic signal mechanism was analyzed; these signals were generated via electric, thermal, and acoustic expansion and contraction, along with electric, mechanical, and acoustic electrostriction. Finally, upon processing the 400 experimental data groups, four practical parameters—maximum amplitude of the ultrasonic signal spectrum, D_max, maximum frequency of the ultrasonic signals, f_max, average ultrasonic signal energy, D_av, and the ultrasonic signal amplitude coefficient, M—were designed to characterize the ultrasonic signals. These parameters can be used for subsequent pattern recognition. Thus, in this study, the terminal PD of an oil-filled marine cable was monitored.

The synergistic effects of zinc oxide (ZnO) Micro/Nano particles simultaneously filled in low-density polyethylene (LDPE) on the space charge characteristics and electrical properties has been investigated by melt blending micro-scale and nanoscale ZnO additive particles into LDPE matrix to prepare Micro-ZnO, Nano-ZnO, and Micro-Nano ZnO/LDPE composites. The morphological structures of composite samples are characterized by Polarizing Light Microscopy (PLM), and the space charge accumulations and insulation performances are correlated in the analyses with Pulse Electronic Acoustic (PEA), DC breakdown field strength, and conductance tests. It is indicated that both the micro and nano ZnO fillers can introduce plenty of heterogeneous nuclei into the LDPE matrix so as to impede the LDPE spherocrystal growth and regularize the crystalline grains in neatly-arranged morphology. By filling microparticles together with nanoparticles of ZnO additives, the space charge accumulations are significantly inhibited under an applied DC voltage and the minimum initial residual charges with the slowest charge decaying rate have been achieved after an electrode short connection. While the micro-nano ZnO/LDPE composites acquire the lowest conductivity, the breakdown strengths of the ZnO/LDPE nanocomposite and micro-nano composite are, respectively, 13.7% and 3.4% higher than that of the neat LDPE material.

Nano-dielectrics are sensitive to humidity and easily degraded in damp environment because of the high surface energy of nanoparticles. In order to study the effect of humidity on the dielectric properties of nano-dielectric, polypropylene (PP) was modified by polyolefin elastomer (POE) and nano-SiO₂, and the samples with obvious filling concentration were pre-selected by breakdown strength for damp aging. The aging experiments were carried out in different relative humidity. The dielectric properties of new, hygroscopic saturation and samples after drying were measured and analyzed. It is found that the breakdown strength of hygroscopic saturation nano-dielectrics decreased obviously compared with new samples, and it was difficult to recover after drying. The damp degradation resulted in different changing trends of permittivity of PP and nano-dielectric, but there were relaxation loss peaks of water in both of them. The influence of damp degradation on the trap distribution was studied by thermally stimulated depolarization currents (TSDC), and it was found that the traps level introduced by water molecules was different in PP and nano-dielectrics. All experiment results showed that the performance of nano-dielectrics degraded obviously in humid environment, and it was difficult to recover even after complete drying because of the existence of bounded water molecules in nano-dielectrics.