Liang Jiang

Heavy metal ion pollution poses a serious threat to the natural environment and human health. Photoreduction through Bi-based photocatalysts is regarded as an advanced green technology for solving environmental problems. However, their photocatalytic activity is limited by the rapid recombination of photogenerated e⁻ and h⁺ pairs and a low photo-quantum efficiency. In this work, an optimal precursor of Bi-based MOFs was identified by using different solvents, and rod-like Bi₂O₃ materials were derived by in situ oxidation of Bi atoms in the precursor. The adsorption and photocatalytic reduction efficiency of the prepared Bi₂O₃ materials for Cr(VI) were evaluated under visible light irradiation. The results showed that the prepared materials had a large specific surface area and enhanced visible light absorption. Bi₂O₃(DMF/MeOH-3)-400 had a large specific surface area and many active adsorption sites, and it had the highest adsorption of Cr(VI) (49.13%) among the materials. Bi₂O₃(DMF/MeOH-3)-400 also had the highest photocatalytic reduction efficiency, and it achieved 100% removal of 10 mg·L⁻¹ Cr(VI) within 90 min under light. In addition, the material showed remarkable stability after three consecutive photocatalytic cycles. The enhanced photocatalytic performance was mainly attributed to the fast separation of electron–hole pairs and efficient electron transfer in the MOF-derived materials, which was confirmed by electrochemical tests and PL spectroscopy. Reactive species trapping experiments confirmed that electrons were the main active substances; accordingly, a possible photocatalytic mechanism was proposed. In conclusion, this work provides a new perspective for designing novel photocatalysts that can facilitate the removal of Cr(VI) from water.

Chloride ions readily react with organic matter and other ions, resulting in the formation of disinfection by-products (DBPs) that exhibit heightened levels of toxicity, carcinogenicity, and mutagenicity. This study creatively employed waste walnut shells as self-templates and low-cost magnesium bicarbonate as a rigid template to successfully synthesize multifunctional porous carbon derived from walnut shells. Employing a series of characterization techniques, it was ascertained that the porous carbon material (WSC/Mg) synthesized via the dual-template method exhibited a distinct layered microscopic surface structure, with a predominance of C and O elements on the surface. The material displayed a high degree of graphitization, significant specific surface area, and abundant oxygen-containing surface functional groups. The incorporation of magnesium bicarbonate as a hard template improved the structure of the walnut shell porous carbon, resulting in a significant enhancement in mass transfer efficiency for the target product on the adsorbent and a substantial improvement in removal efficiency. In comparison with walnut shell-derived carbon using only self-templating, WSC/Mg exhibited a 17.26-fold increase in adsorption capacity for 2,4-dichlorophenol. Furthermore, even after four adsorption–desorption cycles, WSC/Mg-12 maintained an adsorption efficiency above 90%. It is remarkable that WSC/Mg-12 demonstrated exceptional resistance to interference from natural organic matter and pH variations. Moreover, the adsorbed saturated WSC/Mg-12 effectively treated real coke wastewater, resulting in an 80% color removal rate, 20% COD removal rate, and 15% ammonia nitrogen removal rate. In conclusion, this study presents an innovative approach for cost-effective and versatile porous carbon materials with extensive applications in water environment purification and biomass utilization.

The design and synthesis of efficient photocatalysts that promote the degradation of organic pollutants in water have attracted extensive attention in recent years. In this work, CdS nanoparticles are grown in situ on Co@C derived from metal–organic frameworks. The resulting hierarchical CdS/Co@C nanostructures are evaluated in terms of their adsorption and photocatalytic ciprofloxacin degradation efficiency under visible-light irradiation. The results show that, apart from offering a large surface area (55.69 m²·g⁻¹), the prepared material can effectively suppress the self-agglomeration of CdS and enhance the absorption of visible light. The CdS/Co@C-7 composite containing 7% wt Co@C has the highest photodegradation rate, and its activity is approximately 4.4 times greater than that of CdS alone. Moreover, this composite exhibits remarkable stability after three successive cycles of photocatalysis. The enhanced photocatalytic performance is largely ascribed to the rapid separation of electron–hole pairs and the effective electron transfer between CdS and Co@C, which is confirmed via electrochemical experiments and photoluminescence spectra. The active substance capture experiment and the electron spin resonance technique show that h⁺ is the main active entity implicated in the degradation of CIP, and accordingly, a possible mechanism of CIP photocatalytic degradation over CdS/Co@C is proposed. In general, this work presents a new perspective on designing novel photocatalysts that promote the degradation of organic pollutants in water.

ZnIn₂S₄, a novel two-dimensional visible light-responsive photocatalyst, has attracted much attention in the photocatalytic evolution of H₂ under visible light irradiation due to its attractive intrinsic photoelectric properties and geometric configuration. However, ZnIn₂S₄ still has severe charge recombination, which results in moderate photocatalytic performance. Herein, we report the successful synthesis of 2D/2D ZnIn₂S₄/Ti₃C₂ nanocomposites by a facile one-step hydrothermal method. The efficiency of the nanocomposites in photocatalytic hydrogen evolution under visible light irradiation was also evaluated for different ratios of Ti₃C₂, and the optimal photocatalytic activity was achieved at 5% Ti₃C₂. Importantly, the activity was significantly higher than that of pure ZnIn₂S₄, ZnIn₂S₄/Pt, and ZnIn₂S₄/graphene. The enhanced photocatalytic activity is mainly due to the close interfacial contact between Ti₃C₂ and ZnIn₂S₄ nanosheets, which amplifies the transport of photogenerated electrons and enhances the separation of photogenerated carriers. This research describes a novel approach for the synthesis of 2D MXenes for photocatalytic hydrogen production and expands the utility of MXene composite materials in the fields of energy storage and conversion.

In this study, Co-doped TiO₂ was synthesized using waste tobacco stem silk (TSS) as a template via a one-pot impregnation method. These samples were characterized using various physicochemical techniques such as N₂ adsorption/desorption analysis, diffuse reflectance UV–visible spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and electron paramagnetic resonance spectroscopy. The synthesized material was used for the photodegradation of tetracycline hydrochloride (TCH) under visible light (420–800 nm). No strong photodegradation activity was observed for mesoporous TiO₂ synthesized using waste TSS as a template, mesoporous Co-doped TiO₂, or TiO₂. In contrast, Co-doped mesoporous TiO₂ synthesized using waste TSS as a template exhibited significant photocatalytic degradation, with 86% removal of TCH. Moreover, owing to the unique chemical structure of Ti-O-Co, the energy gap of TiO₂ decreased. The edge of the absorption band was redshifted, such that the photoexcitation energy for generating electron–hole pairs decreased. The electron–hole separation efficiency improved, rendering the microstructured biotemplated TiO₂ a much more efficient catalyst for the visible-light degradation of TCH.

Solar-driven photocatalytic H₂O₂production with water and O₂is an environmentally friendly process for producing H₂O₂, an important chemical.