Nicholas E. Frattini

Dissipative tunneling remains a cornerstone effect in quantum mechanics. In chemistry, it plays a crucial role in governing the rates of chemical reactions, often modeled as the motion along the reaction coordinate from one potential well to another. The relative positions of energy levels in these wells strongly influence the reaction dynamics. Chemical research will benefit from a fully adjustable, asymmetric double-well equipped with precise measurement capabilities of the tunneling rates. In this paper, we show a quantum simulator system that consists of a continuously driven Kerr parametric oscillator with a third-order nonlinearity that can be operated in the quantum regime to create a fully tunable asymmetric double-well. Our experiment leverages a low-noise, all-microwave control system with a high-efficiency readout, based on a tunnel Josephson junction circuit, of the which-well information. We explore the reaction rates across the landscape of tunneling resonances in parameter space. We uncover two counter-intuitive effects: (i) a weak asymmetry can significantly decrease the activation rates, even though the well in which the system is initialized is made shallower, and (ii) the width of the tunneling resonances alternates between narrow and broad lines as a function of the well depth and asymmetry. We predict by numerical simulations that both effects will also manifest themselves in ordinary chemical double-well systems in the quantum regime. Our work is a first step for the development of analog molecule simulators of proton transfer reactions based on quantum parametric processes.

By applying a microwave drive to a specially designed Josephson circuit, we have realized a double-well model system: a Kerr oscillator submitted to a squeezing force. We have observed, for the first time, the spectroscopic fingerprint of a quantum double-well Hamiltonian when its barrier height is increased: a pairwise level kissing (coalescence) corresponding to the exponential reduction of tunnel splitting in the excited states as they sink under the barrier. The discrete levels in the wells also manifest themselves in the activation time across the barrier which, instead of increasing smoothly as a function of the barrier height, presents steps each time a pair of excited states is captured by the wells. This experiment illustrates the quantum regime of Arrhenius’s law, whose observation is made possible here by the unprecedented combination of low dissipation, time-resolved state control, 98.5% quantum nondemolition single shot measurement fidelity, and complete microwave control over all Hamiltonian parameters in the quantum regime. Direct applications to quantum computation and simulation are discussed. Published by the American Physical Society 2024

Quantum fluctuations constitute the primary noise barrier limiting cavity-based axion-dark-matter searches. In an experiment designed to mimic a real axion search, we employ a quantum enhanced sensing technique to detect a synthetic axionlike microwave tone at an unknown frequency weakly coupled to a resonator, demonstrating a factor-of-5.6 acceleration relative to a quantum limited search for the same tone. This speed-up is achieved by dynamically coupling the resonator mode to a second (readout) mode with balanced swapping and two-mode squeezing interactions, which results in both visibility-bandwidth and peak-visibility increase. A small fractional imbalance between the two interaction rates yields further scan-rate enhancement and we demonstrate that an eightfold acceleration can be achieved.

Analog quantum simulators, which efficiently represent model systems, have the potential to provide new insight toward naturally occurring phenomena beyond the capabilities of classical computers. Incorporating dissipation as a resource unlocks a wider range of out-of-equilibrium processes such as chemical reactions. Here, we operate a hybrid qubit-oscillator circuit quantum electrodynamics simulator and model nonadiabatic molecular dynamics through a conical intersection. We identify dephasing of the electronic qubit as the mechanism that drives wave-packet branching when the corresponding oscillator undergoes large amplitude motion. Furthermore, we directly observe enhanced branching when the wave-packet passes through the conical intersection. Thus, the forces that influence a chemical reaction can be viewed from the perspective of measurement backaction in quantum mechanics—there is an effective measurement-induced dephasing rate that depends on the position of the wave packet relative to the conical intersection. Our results set the groundwork for more complex simulations of chemical dynamics using quantum simulators, offering deeper insight into the role of dissipation in determining macroscopic quantities of interest such as the quantum yield of a chemical reaction.

Three-wave mixing is a key process in superconducting quantum information processing, being involved in quantum-limited amplification and parametric coupling between superconducting cavities. These operations can be implemented by superconducting nonlinear asymmetric inductive element (SNAIL)-based devices that present a Kerr-free flux-bias point where unwanted parasitic effects, such as Stark shift, are suppressed. However, with a single flux-bias parameter, these circuits can only host one Kerr-free point, limiting the range of their applications. In this Letter, we demonstrate how to overcome this constraint by introducing the gradiometric SNAIL, a doubly flux biased superconducting circuit in which both effective inductance and Kerr coefficient can be independently tuned. Experimental data show the capability of the gradiometric SNAIL to suppress the Kerr effect in a three-wave mixing parametric amplifier over a continuum of flux bias points corresponding to a 1.7 GHz range of operating frequencies.

Noise asymmetry in the quantum operations with cat-qubits is exploited for efficient fault-tolerant quantum error correction.

The accuracy of logical operations on quantum bits (qubits) must be improved for quantum computers to outperform classical ones in useful tasks. One method to achieve this is quantum error correction (QEC), which prevents noise in the underlying system from causing logical errors. This approach derives from the reasonable assumption that noise is local, that is, it does not act in a coordinated way on different parts of the physical system. Therefore, if a logical qubit is encoded non-locally, we can—for a limited time—detect and correct noise-induced evolution before it corrupts the encoded information¹. In 2001, Gottesman, Kitaev and Preskill (GKP) proposed a hardware-efficient instance of such a non-local qubit: a superposition of position eigenstates that forms grid states of a single oscillator². However, the implementation of measurements that reveal this noise-induced evolution of the oscillator while preserving the encoded information^3,4,5,6,7 has proved to be experimentally challenging, and the only realization reported so far relied on post-selection^8,9, which is incompatible with QEC. Here we experimentally prepare square and hexagonal GKP code states through a feedback protocol that incorporates non-destructive measurements that are implemented with a superconducting microwave cavity having the role of the oscillator. We demonstrate QEC of an encoded qubit with suppression of all logical errors, in quantitative agreement with a theoretical estimate based on the measured imperfections of the experiment. Our protocol is applicable to other continuous-variable systems and, in contrast to previous implementations of QEC^{10,11,12,13,14}, can mitigate all logical errors generated by a wide variety of noise processes and facilitate fault-tolerant quantum computation.

Quantum superpositions of macroscopically distinct classical states—so-called Schrödinger cat states—are a resource for quantum metrology, quantum communication and quantum computation. In particular, the superpositions of two opposite-phase coherent states in an oscillator encode a qubit protected against phase-flip errors^1,2. However, several challenges have to be overcome for this concept to become a practical way to encode and manipulate error-protected quantum information. The protection must be maintained by stabilizing these highly excited states and, at the same time, the system has to be compatible with fast gates on the encoded qubit and a quantum non-demolition readout of the encoded information. Here we experimentally demonstrate a method for the generation and stabilization of Schrödinger cat states based on the interplay between Kerr nonlinearity and single-mode squeezing^1,3 in a superconducting microwave resonator⁴. We show an increase in the transverse relaxation time of the stabilized, error-protected qubit of more than one order of magnitude compared with the single-photon Fock-state encoding. We perform all single-qubit gate operations on timescales more than sixty times faster than the shortest coherence time and demonstrate single-shot readout of the protected qubit under stabilization. Our results showcase the combination of fast quantum control and robustness against errors, which is intrinsic to stabilized macroscopic states, as well as the potential of of these states as resources in quantum information processing^5,6,7,8.