Julien Koudio Dangbegnon

Schematic of the alkaline (1 M KOH) flow cell used for CO ₂ electroreduction and faradaic efficiency of the products obtained at a total current density of 150 mA cm ⁻² .

In this work, porous carbon-vanadium oxynitride (C-V₂NO) nanostructures were obtained at different nitridation temperature of 700, 800 and 900 °C using a thermal decomposition process. The X-ray diffraction (XRD) pattern of all the nanomaterials showed a C-V₂NO single-phase cubic structure. The C-V₂NO obtained at 700 °C had a low surface area (91.6 m² g⁻¹), a moderate degree of graphitization, and a broader pore size distribution. The C-V₂NO obtained at 800 °C displayed an interconnected network with higher surface area (121.6 m² g⁻¹) and a narrower pore size distribution. In contrast, at 900 °C, the C-V₂NO displayed a disintegrated network and a decrease in the surface area (113 m² g⁻¹). All the synthesized C-V₂NO yielded mesoporous oxynitride nanostructures which were evaluated in three-electrode configuration using 6 M KOH aqueous electrolyte as a function of temperature. The C-V₂NO@800 °C electrode gave the highest electrochemical performance as compared to its counterparts due to its superior properties. These results indicate that the nitridation temperature not only influences the morphology, structure and surface area of the C-V₂NO but also their electrochemical performance. Additionally, a symmetric device fabricated from the C-V₂NO@800 °C displayed specific energy and power of 38 W h kg⁻¹ and 764 W kg⁻¹, respectively, at 1 A g⁻¹ in a wide operating voltage of 1.8 V. In terms of stability, it achieved 84.7% as capacity retention up to 10,000 cycles which was confirmed through the floating/aging measurement for up to 100 h at 10 A g⁻¹. This symmetric capacitor is promising for practical applications due to the rapid and easy preparation of the carbon-vanadium oxynitride materials.

Porous carbon nanostructures have long been studied because of their importance in many natural phenomena and their use in numerous applications. A more recent development is the ability to produce porous carbon materials with tuneable properties for electrochemical applications, which has enabled new research directions towards the production of suitable carbon materials for energy storage applications. Thus, this work explores the activation of carbon from polyaniline (PANI) using a less-corrosive potassium carbonate (K₂CO₃) salt, with different mass ratios of PANI and the activating agent (K₂CO₃ as compared to commonly used KOH). The obtained activated carbon exhibits a specific surface area (SSA) of up to ∼1700 m² g⁻¹ for a carbon derived PANI : K₂CO₃ ratio of 1 : 6. Moreover, the prepared samples were tested as electrode materials for supercapacitors with the results showing excellent electrical double layer capacitor behavior. Charge storage was still excellent for scan rates of up to 2000 mV s⁻¹, and a capacitance retention of 70% at a very high specific current of 50 A g⁻¹ was observed. Furthermore, the fabricated device can deliver an energy density of 25 W h kg⁻¹ at a specific current of 0.625 A g⁻¹ and a power density of 260 W kg⁻¹ in 1-ethyl-3-methylimidazolium bistrifluorosulfonylimide (EMIM-TFSI) ionic liquid, with excellent rate capability after cycling for 16 000 cycles at 3.0 V with ∼98% efficiency. These results are promising and demonstrate the electrode's potential for energy storage, leading to the conclusion that K₂CO₃ is a very good alternative to corrosive activation agents such as KOH in order to achieve high electrochemical performance.