Clarisse Mourinha

The evaluation of the spatial and temporal variability of soil properties can be valuable to improve crop productivity and soil health. A study of soil properties was carried out in southern Portugal, in three farm fields with irrigated annual crops (layers 0–20 cm and 20–40 cm), over three years. Factor Analysis (FA) and Discriminant Analysis (DA) were used to analyze the data. With FA, the observed variables were grouped into a smaller number of latent variables related to soil attributes. Discriminant Analysis was used to classify and identify the most dominant attributes and indicators for the time and space variability of soil parameters. The FA performed for the surface layer included factors related to texture, water and nutrient retention capacity, chemical composition, and soil fertility. In the sub-surface layer, the factor structure was similar, with four factors related to texture, chemical composition, nutrient availability, and soil fertility. The most influential factors and variables in temporal discrimination (sampling dates) in both layers were those related to chemical composition, with electric conductivity as the preponderant indicator. As for the spatial differentiation (fields), the dominant factor in the surface layer was texture, and in the sub-surface layer, nutrient availability. The most important discriminant indicators of spatial variability were fine sand proportion and available potassium, respectively, for the surface and sub-surface layers. The results obtained showed potential for the multidimensional and integrated assessment of patterns of temporal and spatial variation of soil functions from agricultural practices or soil degradation processes.

Irrigation-induced or secondary salinization can occur when salts are introduced by irrigation water and accumulate within the root zone due to insufficient leaching. Mediterranean regions are especially susceptible, given the predominant climate and the expanding of irrigation areas. In this study, two indices to assess the risk of salinization (RSA) and sodification (RSO), previously applied at a regional scale, were used in a hydro-agricultural area (AHA) in Southern Portugal, in ten crop fields. Information on climate, irrigation water quality, soil characteristics, and land use was obtained from large databases and from local data. The results revealed the feasibility of using the RSA and RSO indices both on large and smaller scales, seeing as most of the area in the monitored crop fields presented the same risk classes (62% in RSA and 78% in RSO). Deviations were due to the reduction in scores for drainage and, in the case of RSO, the assigned irrigation method based on the land occupation class. Considering that different spatial scales of risk assessment are associated with different objectives and management options, a risk management framework was outlined following a multi-scale perspective for mitigation actions in salt-sensitive areas, ranging from territorial planning to the adoption of on-farm practices that can contribute to the sustainability of irrigated agriculture.

To assess environmental risks related to the mobility and toxicity of AgNPs, the chemical availability of AgNPs and polyvinylpyrrolidone-coated AgNPs (PVP-AgNPs) in three agricultural soils was quantified in a pot experiment. Porewater collection and soil extractions with 0.01 M CaCl₂, 0.4 M Glycine (pH 1.5) and 0.05 M NH₄-EDTA were performed. The effect on soil exoenzyme activities was also assessed. Porewater concentration was low (+ ions into porewater). The effect of variation in organic matter on soil enzymatic activity was larger than that of AgNPs, as no significant additional inhibitory effect from Ag could be observed. Only at low pH and in the presence of complexing ligands that form very stable Ag complexes (0.4 M Glycine extraction at pH 1.5) up to 58% of the Ag added to soil was released (independently of PVP coating). An extraction with glycine is proposed as a useful indicator of potentially available Ag in soils.

Nowadays, the Mediterranean freshwater systems face the threat of water scarcity, along with multiple other stressors (e.g., organic and inorganic contamination, geomorphological alterations, invasive species), leading to the impairment of their ecosystem services. All these stressors have been speeding up, due to climate variability and land cover/land use changes, turning them into a big challenge for the water management plans. The present study analyses the physicochemical and phytoplankton biomass (chlorophyll-a) dynamics of a large reservoir, in the Mediterranean region (Alqueva reservoir, Southern Portugal), under diverse meteorological conditions and land cover/land use real scenarios (2017 and 2018). The most important stressors were identified and the necessary tools and information for a more effective management plan were provided. Changes in these parameters were further related to the observed variations in the meteorological conditions and in the land cover/land use. The increase in nutrients and ions in the water column, and of potentially toxic metals in the sediment, were more obvious in periods of severe drought. Further, the enhancement of nutrients concentrations, potentially caused by the intensification of agricultural activities, may indicate an increased risk of water eutrophication. The results highlight that a holistic approach is essential for a better water resources management strategy.

Four streams in the Guadiana watershed were followed up to assess hydrogeomorphological and physicochemical characteristics, and to analyze its correlation with land use/land cover (LULC), analyzing their possible influence in reservoir water quality and possible influence in the reservoir water quality. The highest amounts of organic descriptors and nutrients were quantified in streams with the major percentage of olive groves and vineyards and urban land cover classes. Streams more influenced by agro-silvo-pastoral class presented better water quality, as this type of LULC acts as a buffer of the contamination runoff. The results highlighted that the hydrogeomorphology of the streams may influence the transfer of pollutants loads to reservoirs. Hence, in intermittent streams characterized by coarse particles in the sediment, high amounts of pollutants are accumulated when the flow ceases, and are further transported to the reservoirs when the flow retakes. On the contrary, streams with sediments characterized by a great percentage of fine particles and organic matter do not induce so much stress in reservoirs, since these allow the adsorption of nutrients and trace elements, without their transfer to reservoirs.