Mozammel Mazumder

Numerous micropollutants, especially endocrine-disrupting compounds (EDCs), can pollute natural aquatic environments causing great concern for human and ecosystem health. While most of the conversation revolves around estrogen and androgen, glucocorticoids (GCs) are also prevalent in natural waters. Despite the fact that GCs play a crucial role in both inflammatory and immunologic development activities, they are also detected in natural waters and considered as one of the EDCs. Although many researchers have mentioned the adverse effect of GCs on aquatic organisms, a complete management technology to remove these pollutants from surface and coastal waters is yet to be established. In the current study, six glucocorticoids (prednisone, prednisolone, cortisone, cortisol, dexamethasone, and 6R-methylprednisolone) have been selected according to their higher detection frequency in environmental waters. The concentration of selected GCs ranged from 0.05 ng/L to 433 ng/L and their removal efficiency ranged from 10% to 99% depending on the water source and associated removal technologies. Although advanced technologies are available for achieving successful removal of GCs, associated operational and economic considerations make implementation of these processes unsustainable. Further studies are necessary to resolve the entry routes of GCs compounds into the surface water or drinking water permanently as well as employ sustainable detection and removal technologies.

This paper scrutinized hydraulic fracturing applications mainly in the United States with regard to both groundwater and surface water contamination with the purpose of bringing forth objective analysis of research findings. Results from previous studies are often unconvincing due to the incomplete database of chemical additives; after and before well-founded water samples to define the change in parameters; and specific sources of water pollution in a particular region. Nonetheless, there is a superior chance of both surface and groundwater contamination induced by improper and less monitored wastewater disposal and management practices. This report has documented systematic evidence for total dissolved solids, salinity, and methane contamination regarding drinking water correlated with hydraulic fracturing. Methane concentrations were found on an average rate of 19.2 mg/L, which is 17 times higher than the acceptance rate and the maximum value was recorded as 64.2 mg/L near the active hydraulic fracturing drilling and extraction zones than that of the nonactive sites (1.1 mg/L). The concentration of total dissolved solids (350 g/L) was characterized as a voluminous amount of saline wastewater, which was quite unexpectedly high. The paper concludes with plausible solutions that should be implemented to avoid further contamination.