MKMarija Krstulović

Marija Krstulović

*This is an algorithmically generated author record based on publicly available information.

Marija Krstulović has a total of 46 co-authors. Here are the top co-authors by number of shared publications:


Latest Publications

  • Open Access

    Thermoelastic dynamics of a nanoscale metallic film: Role of bilayer coupling revealed by extreme ultraviolet transient gratings

    by M. Krstulović, J. S. Pelli-Cresi, D. Fainozzi, L. Foglia, A. Griesi, N. Khatu, S. Laterza, R. Mincigrucci, E. Paltanin, M. Prato, et al.

    We investigate the thermoelastic dynamics of an 80 nm titanium thin film supported by a Si3N4 membrane by extreme-ultraviolet transient-grating (EUV-TG) spectroscopy across varying excitation fluences. A dominant oscillatory response at 143.8–150.6 GHz from time-domain fits is identified as a guided Lamb wave of the Ti/Si3N4 bilayer membrane with an in-plane phase velocity of approximately 6.3 km s−1. The near-coincidence of the Ti longitudinal and Si3N4 transverse acoustic velocities (∼6.1 km s−1) means that the dominant guided mode phase velocity simultaneously approximates both—a direct fingerprint of strong mechanical coupling between the layers. With increasing fluence, a systematic phase velocity increase of 4.7% is observed. A lower-frequency feature near 20–25 GHz is also detected, consistent with a breathing-type thickness response driven by transient uniform stress. Thermal relaxation analysis yields effective in-plane thermal diffusivities of (1.3–2.7) × 10−6 m2 s−1 and thermal conductivities of approximately 3–7 W m−1 K−1, significantly reduced relative to bulk Ti and consistent with boundary-limited heat transport in the confined membrane geometry. By combining nanometer-scale spatial selectivity with picosecond temporal resolution, EUV-TG enables simultaneous access to guided elastic wave propagation and nanoscale in-plane thermal transport in metallic membranes under non-equilibrium excitation. These results demonstrate how nanoscale confinement and multilayer coupling modify thermoelastic dynamics relative to bulk materials and highlight EUV-TG as a powerful tool for probing ultrafast thermoelastic dynamics in thin metallic films.

  • Open Access

    Amplification of Spontaneous Emission from Doubly Excited He Atoms

    by J. Turnšek, Š. Krušič, A. Mihelič, K. Bučar, L. Foglia, R. Mincigrucci, M. Krstulović, M. Coreno, G. Bonano, K. C. Prince, et al.

    We have observed amplification of weak fluorescence from He atoms in the 3a P o 1 autoionizing state, which decay by spontaneous emission of 40.74 eV photons in one out of 1600 cases. On average, a 4.1 ± 1.6 % conversion of 63.67 eV photons was detected in the forward direction at 20 μ J pump pulse energy and 40 mbar He gas pressure. A comparison with state-of-the-art theoretical simulations shows an unexpected spectral line shift at high gas pressure that is ascribed to transient molecular and electron scattering effects.

  • Martensitic fcc-hcp transformation pathway in solid krypton and xenon and its effect on their equations of state

    by A. D. Rosa, A. Dewaele, G. Garbarino, V. Svitlyk, G. Morard, F. De Angelis, M. Krstulović, R. Briggs, T. Irifune, O. Mathon, et al.

    The martensitic transformation is a fundamental physical phenomenon at the origin of important industrial applications. However, the underlying microscopic mechanism, which is of critical importance to explain the outstanding mechanical properties of martensitic materials, is still not fully understood. This is because for most martensitic materials the transformation is a fast process that makes in situ studies extremely challenging. Noble solids krypton and xenon undergo a progressive pressure-induced face-centered cubic (fcc) to hexagonal close-packed (hcp) martensitic transition with a very wide coexistence domain. Here, we took advantage of this unique feature to study the detailed transformation progress at the atomic level by employing in situ x-ray diffraction and absorption spectroscopy. We evidenced a four-stage pathway and suggest that the lattice mismatch between the fcc and hcp forms plays a key role in the generation of strain. We also determined precisely the effect of the transformation on the compression behavior of these materials.


  • Ge coordination inNaAlGe3O8glass upon compression to 131 GPa

    by Marija Krstulović, Angelika D. Rosa, Nicole Biedermann, Georg Spiekermann, Tetsuo Irifune, Manuel Muñoz, Max Wilke

    Structural transformations at high pressure in NaAlGe3O8 glass were investigated by means of x-ray absorption spectroscopy at the Ge K edge in combination with a diamond anvil cell. The obtained results provide a detailed picture of the local structural behavior of Ge in a chemically complex glass under compression. First and second shell bond distances (RGe-O and RGe...Ge) were extracted assuming contributions of two scattering paths (Ge-O and Ge…Ge). We observed a significant extension of the Ge-O distance from 1.73 to 1.82 Å between 3 and ∼26GPa, accompanied by an increase of the fitted number of nearest neighbors from ∼4 to ∼6. These observations can be attributed to the change from tetrahedral to octahedral Ge coordination. Second shell bond distances Ge…Ge are also consistent with this structural transformation. Between 34 and 131 GPa, the evolution of the fitted Ge-O distance implies a gradual volume reduction of the Ge octahedra. At the highest probed pressure of 131 GPa a Ge-O distance of 1.73 Å was found, which is similar to the one obtained at ambient conditions for Ge in fourfold coordination. The compressibility of the Ge-O octahedron in NaAlGe3O8 beyond 34 GPa is considerably higher than the one reported for amorphous GeO2 from x-ray diffraction analysis but it is similar to the one reported for the Ge octahedron in crystalline rutile-type GeO2. We attribute the high compressibility of the Ge-O bond in NaAlGe3O8 glass to the presence of Al and Na that increase the system's complexity and therefore its degrees of freedom. Beyond 110 GPa the data on NaAlGe3O8 glass indicate the onset of polyhedral distortion. The performed study provides insights into the structural changes of complex and polymerized germanate glasses or melts at extreme pressure conditions.