Maria Zoumaki

The objective of this research is the improvement of the physical properties of artificial sandstone in order to obtain a printable construction material whose composition and structure is suitable for the design, study and construction of environmentally friendly architectural structures. To investigate the suitability of the researched material for 3D printing and determine the physical and mechanical properties of the starch-based sandstone 3D-printed material, both cylindrical and cellular samples were designed. The 3D-printed artificial starch–sandstone material was found to have satisfactory mechanical properties.

A new biodegradable, sustainable and environmentally friendly building material is introduced and studied in this work, which can be applied to lightweight architectural structures, aiming for the reduction of the greenhouse gas emissions and mitigation of the climate change effects. The focus was to investigate the effect of water concentration and different types of sand on the mechanical properties of corn starch-based artificial sandstone. A series of cubic, cylindrical and disk specimens were prepared by varying the concentration of water and using different sources of commercial quartz sand. The quasi-static and cyclic compressive properties of starch-based artificial sandstone samples were measured as a function of water concentration and sand type, while the structure of the artificial sandstone specimens was examined by scanning electron microscopy (SEM) and optical microscopy. Moreover, the Brazilian Test was employed as the indirect method to determine the tensile strength of the samples based on the type of the commercial sand they contained. The experimental results showed that the homogeneous grading of sand grains and the latter’s chemical composition have a significant effect on the mechanical properties of the sandstone samples. The highest compression values were obtained using the microwave heating method at a water concentration of about 12 wt%, while the cyclic compression and Brazilian Tests have shown that the granulometric grading of the sand particles and the chemical composition of the sand influence the compressive and tensile strength of the material.

The objective of this research is the fabrication of biodegradable starch-based sandwich materials. The investigated sandwich structures consist of maize starch-based films as skins and biodegradable 3D-printed polylactic filaments (PLA) as the core. To investigate the tensile properties of the skins, conventional and nanocomposite films were prepared by a solution mixing procedure with maize starch and glycerol as the plasticizer, and they were reinforced with sodium montmorillonite clay, cellulose fibers and fiberglass fabric, with different combinations. Test results indicated a significant improvement in the mechanical and morphological properties of composite films prepared with sodium montmorillonite clay in addition with cellulose fibers and fiberglass fabric, with 20 wt% of glycerol. The morphology of the skins was also examined by scanning electron microscopy (SEM). Three orders of hierarchical honeycombs were designed for the 3D-printed core. To investigate how the skin material and the design of the core affect the mechanical properties of the starch-based sandwich, specimens were tested under a three-point bending regime. The test results have shown that the flexural strength of the biodegradable sandwich structure increased with the use of a second order hierarchy core and starch-based skins improved the strength and stiffness of the neat PLA-based honeycomb core. The bending behavior of the hierarchical honeycombs was also assessed with finite element analysis (FEA) in combination with experimental findings. Flexural properties demonstrated that the use of starch-based films and a PLA honeycomb core is a suitable solution for biodegradable sandwich structures.