Dan Wang

Diffusion solidification is an effective method to produce non-dendritic microstructures and reduce casting defects in magnesium alloys. However, the influence of precursor alloy superheat on the solidification behavior and the resulting microstructure remains insufficiently understood. In this study, pure magnesium was used as the high thermal mass (HTM) alloy and three Mg-Al-Zn alloys with different aluminum and zinc contents were used as the low thermal mass (LTM) alloys. The effects of superheat on grain morphology, solute diffusion, and constitutional supercooling were investigated through a combination of experimental casting and numerical simulation using Ansys Fluent and Matlab. The results show that the solidified interface consists of five distinct regions, including two base metals, two transition zones, and a central controlled diffusion solidification zone. A higher superheat of the HTM alloy relative to the LTM alloy promotes a wider transition zone and finer globular grains, whereas equal or lower superheat leads to columnar or rosette structures. The Mg-30 wt.%Al-3.5 wt.%Zn alloy with moderate aluminum content produces fine globular grains due to a thinner constitutional supercooling layer and a higher degree of supercooling, which suppresses grain growth and increases nucleation rate. In contrast, the Mg-55 wt.%Al-6.5 wt.%Zn alloy with high aluminum content forms coarse rosette and columnar grains. Among the conditions investigated, the combination of 10 °C HTM and 5 °C LTM superheats tends to promote the formation of fine equiaxed grains. Increasing superheat above this range reduces supercooling and coarsens grains, while decreasing superheat inhibits interface diffusion and promotes solute segregation. The findings provide a theoretical basis for designing precursor alloy compositions and superheat parameters in controlled diffusion solidification of magnesium alloys.

In this study, 310S austenitic stainless-steel was welded using a laser with varying amounts of Nb to systematically investigate the effect of Nb on solidification cracking susceptibility, mechanical properties, and corrosion resistance of the weld. Under the present experimental conditions, the critical restraint width was higher for the 0.58 wt.% Nb and 1.45 wt.% Nb welds than for the Nb-free and 2.3 wt.% Nb welds, indicating that Nb addition affected the solidification cracking response of the weld. At low-to-moderate Nb contents, Nb can aggravate compositional segregation and increase the presence of low-melting-point liquid films, thereby increasing cracking susceptibility. At higher Nb contents, the reduced cracking susceptibility was accompanied by microstructural refinement and changes in the distribution of Nb-rich constituents during solidification. With increasing Nb content, the number of precipitated phases in the weld increases, mainly distributed at the austenite grain boundaries in granular, elongated, and chain-like forms. The introduction of Nb generally increases the microhardness and tensile strength of the welded joint, attributed to grain refinement strengthening and solid-solution strengthening. The reduction in area first increased and then decreased, suggesting that excessive Nb addition may reduce ductility because of the increased amount of grain-boundary precipitates and local strengthening heterogeneity. With increasing Nb content, the Ir/Ia ratio decreased from 67.6% to 52.2%, suggesting improved intergranular corrosion resistance. This improvement is likely related to the preferential reaction of Nb with carbon, which may suppress the formation of Cr-depleted zones at grain boundaries. Overall, Nb addition improved the corrosion resistance and increased the hardness and tensile strength of the weld; however, its effect on solidification cracking susceptibility was non-monotonic, indicating that careful control of Nb content is required to balance cracking susceptibility, mechanical properties, and corrosion resistance.

In this work, a laser lap-welded joint of galvanized steel/Mg and a laser lap-welded joint of galvanized steel/Mg assisted by ultrasonic vibration were compared. By adjusting the laser beam power and ultrasonic amplitude, the appropriate welding process parameters were obtained. The weld formation, microstructure and mechanical properties were studied and analyzed. The results indicated that the addition of ultrasonic vibration generated an excitation force with a certain frequency and amplitude on the weldment, making the molten metal in the molten pool produce ultrasonic forced vibration, and producing the effects of cavitation, acoustic streaming, mechanical stirring and heat, thus reducing welding residual stress and welding-deformation, porosity and incomplete-fusion defects. In addition, it can make the fusion zone transition evenly, improve the wettability, refine the weld grain, and reduce the average grain area from 583 μm² to 324 μm². Moreover, the distribution of Mg-Zn reinforcing phase at the interface was more uniform and denser, and the maximum tensile shear strength increased from 179.9 N/mm to 290 N/mm, indicating that the addition of ultrasonic vibration was conducive to improving the comprehensive mechanical properties of the joint.

Refractory high-entropy alloys (RHEAs) typically exhibit excellent high-temperature strength but limited ductility. In this study, a comprehensive machine learning strategy with integrated material knowledge is proposed to predict the elongation of TiZrNbVAl RHEAs. By referring to the ductility theories, a set of cost-effective material features is developed with various mathematical forms of thermodynamic parameters. These features are proven to effectively incorporate material knowledge into ML modeling. They also offer potential alternatives to those obtained from costly first-principles calculations. Based on Pearson correlation coefficients, the linear relationships between pairwise features were compared, and the seven key features with the greatest impact on the model were selected for ML modeling. Regression tasks were performed to predict the ductility of TiZrNbVAl, and the CatBoost gradient boosting algorithm exhibiting the best performance was eventually selected. The established optimized model achieves high predictive accuracies exceeding 0.8. These key features were further analyzed using interpretable ML methods to elucidate their influences on various ductility mechanisms. According to the ML results, different compositions of TiZrNbVAl with excellent tensile properties were prepared. The experimental results indicate that Ti₄₄Zr₂₄Nb₁₇V₅Al₁₀ and Ti₄₄Zr₂₆Nb₈V₁₃Al₉ both exhibited ultimate tensile strengths of approximately 1180 MPa and elongations higher than 21%. They verified that the ML strategy proposed in this study is an effective approach for predicting the properties of RHEAs. It is a potential method that can replace costly first-principles calculations. Thermodynamic parameters have been shown to effectively predict alloy ductility to a certain extent.

The removal of the surface paint of Q345 (Gr·B) steel, as well as microstructure and hardness of the cleaned surface were investigated. The laser source used in this study is a nanosecond pulsed Gaussian light source. The surface morphology and microstructure were characterized by a scanning electron microscope and electron back-scattered diffraction. A hardness test was used for capturing variations of the parameter of the cleaned region in comparison to the base metal. The results show that when the X-scanning speed was 1500 mm/s and Y-moving speeds was 7 mm/s during ns-laser cleaning, respectively, the cleaned surface was relatively flat and there was only a few small residual paint. In addition, the contents of Fe and C elements on the cleaned surface reached to 89% and 9%, respectively. Moreover, the roughness was the lowest of 0.5 μm through the observation of the three-dimensional topography. In addition, a fine grain layer appeared on the cleaned surface after laser cleaning at the X-scanning speeds of 500 mm/s and 1000 mm/s. The maximum hardness of the fine grain layer was more than 400 HV, higher than the base metal.