Maria Solovyeva

The problem of spreading harmful infections through contaminated surfaces has become more acute during the recent coronavirus pandemic. The design of self-cleaning materials, which can continuously decompose biological contaminants, is an urgent task for environmental protection and human health care. In this study, the surface of blended cotton/polyester fabric was functionalized with N-doped TiO₂ (TiO₂-N) nanoparticles using titanium(IV) isopropoxide as a binder to form durable photoactive coating and additionally decorated with Cu species to promote its self-cleaning properties. The photocatalytic ability of the material with photoactive coating was investigated in oxidation of acetone vapor, degradation of deoxyribonucleic acid (DNA) fragments of various lengths, and inactivation of PA136 bacteriophage virus and Candida albicans fungi under visible light and ultraviolet A (UVA) radiation. The kinetic aspects of inactivation and degradation processes were studied using the methods of infrared (IR) spectroscopy, polymerase chain reaction (PCR), double-layer plaque assay, and ten-fold dilution. The results of experiments showed that the textile fabric modified with TiO₂-N photocatalyst exhibited photoinduced self-cleaning properties and provided efficient degradation of all studied contaminants under exposure to both UVA and visible light. Additional modification of the material with Cu species substantially improved its self-cleaning properties, even in the absence of light.

Chemical modification of cotton-rich fabrics with TiO₂ nanoparticles results in photoactive self-cleaning textiles, which can provide, under UV or solar radiation, complete oxidation of low-molecular compounds, degradation of supramolecular structures, and inactivation of microorganisms due to the photocatalytic effect. In this paper, we describe, based on the example of influenza A (H1N1) virus, a photoinduced antiviral effect of cotton fabric functionalized with nanocrystalline TiO₂. Fast inactivation of influenza virus occurs on the irradiated surface of photoactive fabric due to adsorption and photocatalytic degradation. The TiO₂ component in the prepared fabric increases the adsorption effect compared to initial cotton due to a high specific area of TiO₂ nanocrystallites. Long-term irradiation leads to destruction of all virion structures to the point of RNA molecules. In contrast to pristine cotton, no virus RNA is detected using the polymerase chain reaction (PCR) technique after long-term irradiation of photoactive fabric. The results of this study underline the potential of photoactive self-cleaning fabrics for application in air purification systems and personal protective clothes to provide permanent protection of people against harmful chemical and biological pollutants.

The development of active and stable photocatalysts for the degradation of volatile organic compounds under visible light is important for efficient light utilization and environmental protection. Titanium dioxide doped with nitrogen is known to have a high activity but it exhibits a relatively low stability due to a gradual degradation of nitrogen species under highly powerful radiation. In this paper, we show that the combination of N-doped TiO₂ with bismuth tungstate prevents its degradation during the photocatalytic process and results in a very stable composite photocatalyst. The synthesis of Bi₂WO₆–TiO₂-N composites is preformed through the hydrothermal treatment of an aqueous medium containing nanocrystalline N-doped TiO₂, as well as bismuth (III) nitrate and sodium tungstate followed by drying in air. The effect of the molar ratio between the components on their characteristics and photocatalytic activity is discussed. In addition to an enhanced stability, the composite photocatalysts with a low content of Bi₂WO₆ also exhibit an enhanced activity that is substantially higher than the activity of individual TiO₂-N and Bi₂WO₆ materials. Thus, the Bi₂WO₆–TiO₂-N composite has the potential as an active and stable photocatalyst for efficient purification of air.

In this study, various solid uranium oxycompounds and TiO₂-supported materials based on nanocrystalline anatase TiO₂ are synthesized using uranyl nitrate hexahydrate as a precursor. All uranium-contained samples are characterized using N₂ adsorption, XRD, UV–vis, Raman, TEM, XPS and tested in the oxidation of a volatile organic compound under visible light of the blue region to find correlations between their physicochemical characteristics and photocatalytic activity. Both uranium oxycompounds and TiO₂-supported materials are photocatalytically active and are able to completely oxidize gaseous organic compounds under visible light. If compared to the commercial visible-light TiO₂ KRONOS^® vlp 7000 photocatalyst used as a benchmark, solid uranium oxycompounds exhibit lower or comparable photocatalytic activity under blue light. At the same time, uranium compounds contained uranyl ion with a uranium charge state of 6+, exhibiting much higher activity than other compounds with a lower charge state of uranium. Immobilization of uranyl ions on the surface of nanocrystalline anatase TiO₂ allows for substantial increase in visible-light activity. The photonic efficiency of reaction over uranyl-grafted TiO₂, 12.2%, is 17 times higher than the efficiency for commercial vlp 7000 photocatalyst. Uranyl-grafted TiO₂ has the potential as a visible-light photocatalyst for special areas of application where there is no strict control for use of uranium compounds (e.g., in spaceships or submarines).