Muhammad Syafiq Alauddin

Poly(aryl-ether-ketone) materials (PAEKs), a class of high-performance polymers comprised of polyetheretherketone (PEEK) and polyetherketoneketone (PEKK), have attracted interest in standard dental procedures due to their inherent characteristics in terms of mechanical and biological properties. Polyetheretherketone (PEEK) is a restorative dental material widely used for prosthetic frameworks due to its superior physical, mechanical, aesthetic, and handling features. Meanwhile, polyetherketoneketone (PEKK) is a semi-crystalline thermoplastic embraced in the additive manufacturing market. In the present review study, a new way to fabricate high-performance polymers, particularly PEEK and PEKK, is demonstrated using additive manufacturing digital dental technology, or 3-dimensional (3D) printing. The focus in this literature review will encompass an investigation of the chemical, mechanical, and biological properties of HPPs, particularly PEEK and PEKK, along with their application particularly in dentistry. High-performance polymers have gained popularity in denture prosthesis in advance dentistry due to their flexibility in terms of manufacturing and the growing interest in utilizing additive manufacturing in denture fabrication. Further, this review also explores the literature regarding the properties of high-performance polymers (HPP) compared to previous reported polymers in terms of the dental material along with the current advancement of the digital designing and manufacturing.

Today, additive manufacturing (AM) is considered one of the vital tenets of the industry 4.0 revolution due to its high productivity, decentralized production and rapid prototyping. This work aims to study the mechanical and structural properties of polyhydroxybutyrate as an additive in blend materials and its potential in medical applications. PHB/PUA blend resins were formulated with 0 wt.%, 6 wt.%, 12 wt.% and 18 wt.% of PHB concentration. Stereolithography or an SLA 3D printing technique were used to evaluate the printability of the PHB/PUA blend resins. Additionally, from FESEM analysis, a change was observed in PUA’s microstructure, with an additional number of voids spotted. Furthermore, from XRD analysis, as PHB concentration increased, the crystallinity index (CI) also increased. This indicates the brittleness properties of the materials, which correlated to the weak performance of the tensile and impact properties. Next, the effect of PHB loading concentration within PHB/PUA blends and aging duration towards the mechanical performance of tensile and impact properties was also studied by using analysis of variance (ANOVA) with a two-way method. Finally, 12 wt.% of PHB/PUA was selected to 3D print the finger splint due to its characteristics, which are compatible to be used in finger bone fracture recovery.

Industry Revolution 4.0 have revolutionized every industry worldwide where manufacturing technology became more automated and efficient, and the food industry is no different from other industries such as textile, machinery, electronics, and chemical. In the food industry, technology is very important in order to compete with the high demands for food production. In recent years technology such as genetically modified organisms (GMO), precision agriculture, unmanned vehicle systems (drones) for agriculture, and the internet of things have been developed to improve efficiency in manufacturing food. However, one technology that has the capability to disrupt the food industry is additive manufacturing or better known as 3D printing technology. The technology has become a new manufacturing technology for the food industry that provides freedom of customizing food in terms of structural, ingredients as well as automated cooking for a plethora of applications that suits the customer needs. Technology creates a new platform in gastronomy by changing the perspective on making food. This paper focused on the technological aspect of additive manufacturing technology in terms of the suitable printer’s use, the variety of materials that are used as well as potential materials, the key challenges faced by additive manufacturing with regard to production, and the future opportunities that can be discovered. Although additive manufacturing for food is relatively new compared to other additive manufacturing applications, the potential of such technology is huge and can be explored

The integration of additive manufacturing (3D printing) in the biomedical sector required material to portray a holistic characteristic in terms of printability, biocompatibility, degradability, and mechanical properties. This research aims to evaluate the 3D printability and mechanical properties of polyhydroxybutyrate (PHB) as additives in the urethane dimethacrylate (UDMA) based resin and its potential for medical applications. The printability of the PHB/UDMA resin blends was limited to 11 wt.% as it reached the maximum viscosity value at 2188 cP. Two-way analysis of variance (ANOVA) was also conducted to assess the significant effect of the varied PHB (wt.%) incorporation within UDMA resin, and the aging duration of 3D printed PHB/UDMA on mechanical properties in terms of tensile and impact properties. Meanwhile, the increasing crystallinity index (CI) of X-ray diffraction (XRD) in the 3D printed PHB/UDMA as the PHB loading increased, indicating that there is a strong correlation with the lower tensile and impact strength. FESEM images also proved that the agglomerations that occurred within the UDMA matrix had affected the mechanical performance of 3D printed PHB/UDMA. Nonetheless, the thermal stability of the 3D printed PHB/UDMA had only a slight deviation from the 3D printed UDMA since it had better thermal processability.

Polymers remain an integral part of denture fabrication materials, specifically polymethylmetacrylate (PMMA). PMMA has been extensively used, particularly in construction as a denture base material. Nonetheless, various challenges, including microbial threats in the form of candidiasis occurrence, still remain a biological challenge to denture wearers. The present article comprehensively reviews the biomodifications introduced to denture components, in particular denture base material, to improve the overall biological properties, together with physical, mechanical, structural integrity, and optical properties. In addition, fundamental information specifically to PMMA as a conventional denture base material and the causative aetiological microbial agents for biological threat to dentures are explored.

Guided bone and tissue regeneration remains an integral treatment modality to regenerate bone surrounding teeth and dental implants. Barrier membranes have been developed and produced commercially to allow space for bone regeneration and prevent the migration of unwanted cells. Ideal membrane properties, including biocompatibility, sufficient structural integrity and suitable shelf life with easy clinical application, are important to ensure good clinical regenerative outcomes. Membranes have various types, and their clinical application depends on the origin, material, structure and properties. This narrative review aims to describe the currently available barrier membranes in terms of history, main features, types, indication and clinical application and classify them into various groups. Various membranes, including those which are resorbable and non-resorbable, synthetic, added with growth factors and composed of modern materials, such as high-grade polymer (Polyetheretherketone), are explored in this review.

Polyetheretherketone (PEEK) is a unique polymer material which has recently been introduced to dentistry. This study aimed to assess the structural integrity of PEEK as a posterior tooth crown and compared it with ceramic-based material. A total of 31 monolithic CAD-CAM PEEK (Juvora^TM, Strumann, Andover, MA, USA) crowns and 31 lithium disilicate (IPS e.max^®CAD, Voclar Vivadent AG, Liechtenstein) crowns were created and cemented on dentin-like teeth (AlphaDie^®MF, Schütz Dental GmbH, Rosbach, Germany) in a precise procedure mimicking the physical and mechanical properties of natural teeth and periodontal ligaments. A static compressive strength test using a universal testing machine and a dynamic fatigue test using a chewing simulator machine were used until crown failure to assess the fracture behaviour by mode of fracture (fractographic analysis) and 3D digital subtraction analysis. The results showed that PEEK has a greater fracture resistance than IPS e.max^®CAD by 2060 N to 703 N. Additionally, in fatigue limit, IPS e.max^®CAD showed a constant failure under 2.0 Kg (=320 N) before 5000 chewing cycles while PEEK survived at a significantly higher load > 11 Kg (930 N). Furthermore, PEEK showed a continued survival at >1,250,000 cycles while the mean fatigue life of IPS e.max^®CAD was around 133,470 cycles. PEEK illustrated a significantly less catastrophic failure mode with some plastic deformation at the fractographic stereomicroscope and in the 3D digital subtraction analysis. Using PEEK for crowns looks very promising, however, further clinical studies are required to assure this study’s results.