Dan Zhang

Increasing the proportion of clean energy within the energy structure is a crucial strategy for achieving energy transformation. Hydrogen and ammonia, as leaders in clean energy technologies, have garnered significant global attention. The combination of hydrogen and ammonia has emerged as a novel form of energy storage, transportation, and conversion; however, the safety aspects of their application process warrant closer attention. Research on hydrogen safety has been conducted extensively, with particular focus on the leakage, diffusion, combustion, and explosion processes. Both theoretical research and engineering applications have advanced significantly. In particular, hydrogen detection technology, primarily based on electrical measurement, has matured considerably, while schlieren imaging-based flow field visualization technology is progressing steadily. In contrast, safety research concerning ammonia remains in its early stages. Research on the leakage and diffusion characteristics of ammonia predominantly focuses on liquid ammonia, with a strong emphasis on engineering applications. Studies on the combustion and explosion characteristics of ammonia primarily address flame parameters and the combustion development laws. Ammonia serves as an efficient hydrogen storage medium. The conversion process involving hydrogen and ammonia will occur simultaneously in both time and space. Current research has not adequately addressed the safety concerns associated with the application process of hydrogen–ammonia mixtures. Future research on the safety of hydrogen–ammonia application processes should focus on the diffusion characteristics and combustion and explosion behaviors, as well as the development of electrical measurement detection technologies and optical flow field visualization techniques for hydrogen–ammonia mixtures.

Research has recently transitioned from the study of fossil-based materials to bio-sourced ones, following the quest to achieve sustainability. However, fire presents a unique hazard to bio-composite materials, which limits their applicability in various sectors. This necessitates an in-depth assessment of the fire behaviour of biobased composites used for specific applications. Improving the fire properties of bio-composites with flame retardants tends to reduce mechanical strength. Therefore, this review focused on biobased composite materials for packaging, structural, automotive, and aeronautical applications that are both mechanically strong and fire safe. It was noticed that the interfacial bonding between the matrix and the reinforcement should be optimized. In addition, optimum amounts of flame retardants are required for better fire performance. This article covers flame retardants for biobased composites, the optimum amount required, and the extent of improvement to the thermal stability and flammability of the materials. This research will help material scientists and the like in their selection of biomass feedstock, flame retardants, and general materials for different types of applications.

Degradation behavior of combustible fuel is the core factor in determining combustion characteristics. To investigate the effect of ambient atmosphere on the pyrolysis process of polyoxymethylene (POM), the pyrolysis mechanism of POM was studied with thermogravimetric analyzer tests and Fourier transform infrared spectroscopy tests. The activation energy, reaction model, and estimated lifetime of POM pyrolysis under different kinds of ambient gases have been estimated in this paper based on different results of the kinetics. The activation energy values, obtained with different methods, were 151.0–156.6 kJ mol⁻¹ in nitrogen and 80.9–127.3 kJ mol⁻¹ in air. Then, based on the Criado analysis, the pyrolysis reaction models of POM in nitrogen were found to be mastered by the “n + m = 2; n = 1.5” model, and by the “A3” model in air. The optimum processing temperature for POM was estimated, with a range from 250 to 300 °C in nitrogen and from 200 to 250 °C in air. IR analysis revealed that the significant difference in POM decomposition between N₂ and O₂ atmospheres is the formation of isocyanate group or carbon dioxide. Combustion parameters of two POMs (with and without flame retardants) obtained using cone calorimetry revealed that flame retardants can effectively improve the ignition time, smoke release rate, and other parameters of POM. The outcomes of this study will contribute to the design, storage, and transportation of polyoxymethylene.

5-aminotetrazole (5AT) has been widely used as a fuel in SPGGs for its high nitrogen content, heat resistance, and environmentally friendly product. However, 5AT-based propellants still have disadvantages, such as a high exhaust temperature and unstable combustion rate, which somewhat limit their application. Given that transition metal oxides are typically employed in small quantities to enhance the performance of solid propellants, this study selected nickel oxide (NiO) nanoparticles as a catalyst and employed them in conjunction with 5AT via mechanical ball milling to investigate their impact on the pyrolysis behavior of 5AT. It was found that the nanoscale NiO particles can significantly reduce the thermal degradation temperature of 5AT according to TG-DSC tests. The calculation of the energy required to initiate the pyrolysis of 5AT using three kinetic methods, namely Friedman (FR), Flynn–Wall–Ozawa (FWO), and Kissinger–Akahira–Sunose (KAS), indicated that the use of NiO nanoparticles can reduce the energy required by more than 46 kJ mol⁻¹, thereby increasing the likelihood of 5AT pyrolysis. Meanwhile, the reduced thermal safety parameters indicated that NiO makes 5AT more susceptible to thermal decomposition due to thermal explosion transition, so more care is needed for the storage of 5AT. Moreover, the TG-FTIR test was conducted to study the pyrolysis mechanism with or without NiO; the results showed that NiO exerts different catalytic effects on the gas products. The results from this study can offer direction and recommendations for future research on solid propellants.

Polyurethane (PU) is a typical product of the reaction between isocyanate and polyol, whose ratio would greatly influence material properties. In this paper, to investigate the influence of isocyanate on PU thermal stability and flammability, three kinds of rigid polyurethanes (RPUs) with different isocyanate ratio (1.05, 1.1, and 2.0) were manufactured in a laboratory and employed to have a series of TG (thermogravimetry), DSC (differential scanning calorimetry), and cone calorimetry tests. Kissinger’s method was used to calculate the activation energy and judge their stabilities. However, for such a complex degradation which consists of five reactions, it does not make sense by Kissinger method to obtain only two peak active energies. Considering complexity of PU degradation in air, genetic algorithm (GA) was employed to calculate kinetic triplets of five sub-reactions. The effects of isocyanate contents on each sub-reaction stability were obtained and then analyzed. By cone calorimeter testing, we found that great differences in heat release rate data. However, DSC analysis showed a complete opposite changed trend. Such difference is caused by DSC and calorimeter’s sample morphology, the former using grinded polyurethane powders but the latter polyurethane foam block.