Heng Cao

Using a single-atom photocatalyst as a model system, we uncover the role of chemisorption states in regulating ultrafast charge transfer at the CO ₂ photoreduction interface.

Enhanced low-temperature ODHP performance is achieved over a NiO/SiO ₂ catalyst by regulating the oxide–support interaction strength to balance geometric and electronic effects.

Heterogeneous single-atom systems demonstrate potential to break performance limitations of single-atom catalysts through synergy interactions. The synergy in heterogeneous single atoms strongly dependes on their anchoring sites. Herein, we reveal the site-specific synergy in heterogeneous single atoms for oxygen evolution. The Ru_TIr_V/CoOOH is fabricated by anchoring Ru single atoms onto three-fold facial center cubic hollow sites and Ir single atoms onto oxygen vacancy sites on CoOOH. Moreover, Ir_TRu_V/CoOOH is also prepared by switching the anchoring sites of single atoms. Electrochemical measurements demonstrate the Ru_TIr_V/CoOOH exhibits enhanced OER performance compared to Ir_TRu_V/CoOOH. In-situ spectroscopic and mechanistic studies indicate that Ru single atoms at three-fold facial center cubic hollow sites serve as adsorption sites for key reaction intermediates, while Ir single atoms at oxygen vacancy sites stabilize the *OOH intermediates via hydrogen bonding interactions. This work discloses the correlation between the synergy in heterogeneous single atoms and their anchoring sites.