Ion Sorin Zgură

We present a novel approach for the synthesis of crystalline zinc oxide (ZnO) nanopowders based on the direct interaction of high-power microwave radiation with a zinc wire in atmospheric air. The process utilizes a localized microwave-induced plasma to rapidly vaporize the metal, followed by oxidation and condensation, resulting in the deposition of ZnO nanostructures on glass substrates. Plasma diagnostics confirmed the generation of a plasma in local thermodynamic equilibrium (LTE), characterized by high electron temperatures. Optical emission spectroscopy highlighted atomic species such as ZnI, ZnII, OI, OII, and NI, as well as molecular species including OH, N₂ and O₂. The spectral fingerprint of N₂ molecules reveals the presence of high energy electrons, while the persistent occurrence of OI and OII emission lines throughout the plasma spectrum reveals that ZnO formation is mainly driven by the continuous dissociation of molecular oxygen. High crystallinity and chemical purity of the synthesized ZnO nanoparticles were confirmed through SEM, TEM, XRD, FTIR, and EDX characterization. The resulting nanorods exhibit a rod-like morphology, with diameters ranging from 12 nm to 63 nm and lengths between 58 nm and 354 nm. This low-cost, high-yield method offers a scalable and efficient route for metal oxide nanomaterial fabrication via direct metal–microwave coupling, providing a promising alternative to conventional physical and chemical synthesis techniques.

This research highlights the different behaviors of titanium (Ti) wires under the action of 500 W and 800 W microwave power levels. Following the interaction between microwaves and a titanium wire placed in the node of the (TM₀₁₁—transverse magnetic mode) waveguide in air at atmospheric pressure, plasma was generated. Using optical emission spectroscopy technique it was observed that during plasma generation at 500 W and 800 W microwaves powers, metallic ions, and gas ions were created, and the plasmas fulfilled the local thermodynamic equilibrium (LTE) conditions. The XRD analysis showed that on the surface of the Ti wire exposed to 500 W microwave power a mixture of titanium dioxide (TiO₂) and titanium oxide (TiO) grew, while the Ti wire exposed to 800 W microwave power was completely vaporized and a mixture of TiO₂ and TiO nanoparticles was synthesized. The SEM analysis showed that the dimensions of the titanium oxide (TiO_x) nanoparticles generated by both microwave discharges ranged from 5 nm to 200 nm. The results of EDS analysis showed that the power of microwaves plays an important role in quantitative conversion from Ti wire into a TiO_x mixture. The TEM analysis indicates that most of the nanoparticles are either amorphous or nanocrystalline. Using this simple and inexpensive technique one can grow a TiO_x layer on the surface of titanium electrodes or can synthetize nanocrystalline TiO_x particles.

A new method for the synthesis and deposition of tungsten oxide nanopowders directly on the surface of a carbon-fiber-reinforced polymer composite (CFRP) is presented. The CFRP was chosen because this material has very good thermal and mechanical properties and chemical resistance. Also, CFRPs have low melting points and are transparent under ionized radiation. The synthesis is based on the direct interaction between high-power-density microwaves and metallic wires to generate a high-temperature plasma in an oxygen-containing atmosphere, which afterward condenses as metallic oxide nanoparticles on the CFRP. During microwave discharge, the value of the electronic temperature of the plasma, estimated from Boltzmann plots, reached up to 4 eV, and tungsten oxide crystals with a size between 5 nm and 100 nm were obtained. Transmission electron microscopy (TEM) analysis of the tungsten oxide nanoparticles showed they were single crystals without any extended defects. Scanning electron microscopy (SEM) analysis showed that the surface of the CFRP sample does not degrade during microwave plasma deposition. The X-ray attenuation of CFRP samples covered with tungsten oxide nanopowder layers of 2 µm and 21 µm thickness was measured. The X-ray attenuation analysis indicated that the thin film with 2 µm thickness attenuated 10% of the photon flux with 20 to 29 KeV of energy, while the sample with 21 µm thickness attenuated 60% of the photon flux.

The effects induced by microwave field upon tungsten wires of different diameters were investigated. Tungsten wires with 0.5 and 1.0 mm diameters were placed in the focal point of a single-mode cylindrical cavity linked to a microwave generator and exposed to microwave field in ambient air. The experimental results showed that the 0.5 mm diameter wire was completely vaporized due to microwaves strong absorption, while the wire with 1 mm diameter was not ignited. During the interaction between microwaves and tungsten wire with 0.5 mm diameter, a plasma with a high electronic excitation temperature was obtained. The theoretical analysis of the experiment showed that the voltage generated by metallic wires in interaction with microwaves depended on their electric resistance in AC and the power of the microwave field. The physical parameters and dimension of the metallic wire play a crucial role in the ignition process of the plasma by the microwave field. This new and simple method to generate a high-temperature plasma from a metallic wire could have many applications, especially in metal oxides synthesis, metal coatings, or thin film deposition.

The large time of life of ¹⁴⁶Sm suggests the possibility to use this p - nuclide as astrophysical chronometer to study the geochemical galactic evolution. Due to the high temperature and large densities of gamma quanta, neutrons and protons in stellar environment ¹⁴⁶Sm nucleus can be obtained in (γ,n), (n,2n), (p,2n) processes on ¹⁴⁷Sm.The knowledge of corresponding cross sections of gamma rays, neutrons and alpha induced processes is of a great importance for the explanation of (¹⁴⁶Sm/¹⁴⁴Sm) ratio uncertainties observed on the Earth, meteorites, Moon and other celestial bodies.Cross sections of (γ,n), (n,2n), (α,γ) processes induced by fast gamma rays, neutrons and alphas on ¹⁴⁷Sm and ¹⁴²Nd, from threshold up to 25 MeV were evaluated and predicted in the frame of Hauser-Feshbach statistical model by using Talys software and the own computer programs. For each nuclear reaction contribution of direct, compound and pre-equilibrium mechanisms were determined. Theoretical evaluations are compared with existing experimental data. Parameters of optical potential in the incident and emergent channels and of nuclear densities were extracted. Calculated cross sections together with corresponding nuclear data were used in the evaluation of astrophysical rates necessary in the determination of elemental abundances as needed by nuclear astrophysical networks.