Tomasz Kondratowicz

CeO ₂ is a promising Ru support for cSCWG, combining high activity, stability and practical coke removal. These features make it a solid candidate for industrial-scale biomass processing.

A green, scalable and cost-effective synthesis of microspherical Mg/Al–CO₃ LDHs with an average particle size of 34 ± 6 μm and a multi-hierarchical morphology.

We report a new synthetic strategy for preparing well-organised, spherical and mesoporous, mixed-metal, hollow-core@layered double hydroxides. Hollow-SiO₂@Cu_xZn_yMg_zAl-LDHs (x + y + z = 2.32 ± 0.06) were prepared by exploiting a unique “memory effect” feature of LDH materials. The reconstruction with simultaneous incorporation of Cu²⁺ and Zn²⁺ into the LDH shell was achieved by exposing hollow-SiO₂@Mg₂Al-LDO to an aqueous solution containing Cu²⁺ and Zn²⁺ cations. The effect of a single reconstruction step with various concentrations of Cu²⁺ and Zn²⁺ solutions (20–80 mM), as well as the implementation of five successive cycles of calcination–reconstruction on the chemical composition, morphology, texture and structure of the resulting materials are described. Hollow-SiO₂@Cu_xZn_yMg_zAl-LDHs are precursors to active catalysts for CO₂ hydrogenation to methanol. The most active catalyst exhibits a space-time yield for methanol of 1.68 g_MeOH g_Cu ⁻¹ h⁻¹ at 270 °C (3 : 1 CO₂ : H₂, 30 bar) which represents a 1.7-fold increase in space-time yield compared to commercial Cu/ZnO/Al₂O₃ catalyst under the same conditions.

Well-organized, spherical, mesoporous hollow @CuMgAl-LDHs (layered double hydroxides) are prepared by the controlled removal of the SiO₂ from SiO₂@CuMgAl-LDH core–shell hybrids that in turn are synthesized via a bottom-up strategy.