Sara Gullace

Graphene-antiferromagnet (AFM) van der Waals heterostructures can be used to modify graphene conductance upon changes in the AFM magnetic state.

Metal–Organic Frameworks (MOFs) attract attention for their intrinsic porosity, large surface area, and functional versatility. To fully utilize their potential in applications requiring precise control at smaller scales, it is essential to overcome challenges associated with their bulk form. This is particularly difficult for 3D MOFs with spin crossover (SCO) behavior, which undergo a reversible transition between high‐spin and low‐spin states in response to external stimuli. Maintaining their structural integrity and SCO properties at the nanoscale remains a significant challenge, yet these properties make them ideal candidates for sensors, data storage, and molecular switch applications. This study reports the synthesis of nanocrystals of the well‐known SCO MOF [Fe ₂ (H _0.67 bdt) ₃ ]·xH ₂ O ( 1 , x = 0–10, bdt ²⁻ = 1,4‐benzeneditetrazolate), which exhibits both magnetic and charge transport properties. The nanocrystals are obtained through sonication of macrocrystals, and the preservation of their crystalline structure at the nanoscale is explored using Microcrystal Electron Diffraction (MicroED). A comparison between macro‐ and nanocrystals highlights the structural integrity and the preservation of charge‐transport properties, underlining the potential for further miniaturization of MOFs for advanced technological applications.

Li–S batteries (LSBs) comprising two Kagome imine COFs as modifiers for Celgard separators are fabricated. The work highlights the cooperative effect of polysulfide trapping, Li⁺ sieving and electrocatalytic properties for high-performance LSBs.

The increasing population and industrial development are responsible for environmental pollution. Among toxic chemicals, polycyclic aromatic hydrocarbons (PAHs) are highly carcinogenic contaminants resulting from the incomplete combustion of organic materials. Two-dimensional materials, such as transition metal dichalcogenides (TMDCs), are ideal sensory scaffolds, combining high surface-to-volume ratio with physical and chemical properties that are strongly susceptible to environmental changes. TMDCs can be integrated in field-effect transistors (FETs), which can operate as high-performance chemical detectors of (non)covalent interaction with small molecules. Here, we have developed MoS₂-based FETs as platforms for PAHs sensing, relying on the affinity of the planar polyaromatic molecules for the basal plane of MoS₂ and the structural defects in its lattice. X-ray photoelectron spectroscopy analysis, photoluminescence measurements, and transfer characteristics showed a notable reduction in the defectiveness of MoS₂ and a p-type doping upon exposure to PAHs solutions, with a magnitude determined by the correlation between the ionization energies (E_I) of the PAH and that of MoS₂. Naphthalene, endowed with the higher E_I among the studied PAHs, exhibited the highest output. We observed a log-log correlation between MoS₂ doping and naphthalene concentration in water in a wide range (10^-9-10^-6 M), as well as a reversible response to the analyte. Naphthalene concentrations as low as 0.128 ppb were detected, being below the limits imposed by health regulations for drinking water. Furthermore, our MoS₂ devices can reversibly detect vapors of naphthalene with both an electrical and optical readout, confirming that our architecture could operate as a dual sensing platform.

A gold nanoparticles transparent electrode was realized by chemical reduction. This work aims to compare the transparent gold nanoparticles electrode with a more commonly utilized gold-film-coated electrode in order to investigate its potential use as counter-electrode (CE) in dye-sensitized solar cells (DSSCs). A series of DSSC devices, utilizing I⁻/I³⁻ and Co(III)/(II) polypyridine redox mediators [Co(dtb)3]³⁺/²⁺; dtb = 4,4′ditert-butyl-2,2′-bipyridine)], were evaluated. The investigation focused firstly on the structural characterization of the deposited gold layers and then on the electrochemical study. The novelty of the work is the realization of a gold nanoparticles CE that reached 80% of average visible transmittance. We finally examined the performance of the transparent gold nanoparticles CE in DSSC devices. A maximum power conversion efficiency (PCE) of 4.56% was obtained with a commercial I⁻/I³⁻-based electrolyte, while a maximum 3.1% of PCE was obtained with the homemade Co-based electrolyte.

An investigation on the photoelectrochemical and sensitizing properties of two different hybrid organic dyes, anchored as sensitizers on mesoporous TiO_2, in Grätzel solar cells, is presented. Firstly, we studied the absorption properties of the C106 sensitizer, a Ru polypyridine complex, and of the Y123, an organic push and pull dye. In this work, we characterized these two dyes, employing two different electrolytes, with similar experimental condition and device parameters. From the J–V curves and IPCE photo action spectra, we performed an inedited bifacial study based on the comparison of their photovoltaic performances, exploiting several backgrounds (black or white). Among the obtained results from this study, we found the best bifaciality factor of 93% for C106 and the best power conversion efficiency of 12.8% for Y123. These results represent, concerning these two dyes and to the best of our knowledge, some of the highest values in literature.

The development of systems capable of responding to environmental changes, such as humidity, requires the design and assembly of highly sensitive and efficiently transducing elements. Such a challenge can be mastered only by disentangling the role played by each component of the responsive system, thus ultimately achieving high performance by optimizing the synergistic contribution of all functional elements. Here, we designed and synthesized a novel [1]benzothieno[3,2-b][1]benzothiophene derivative equipped with hydrophilic oligoethylene glycol lateral chains (OEG-BTBT) that can electrically transduce subtle changes in ambient humidity with high current ratios (>10⁴) at low voltages (2 V), reaching state-of-the-art performance. Multiscale structural, spectroscopical, and electrical characterizations were employed to elucidate the role of each device constituent, viz., the active material’s BTBT core and OEG side chains, and the device interfaces. While the BTBT molecular core promotes the self-assembly of (semi)conducting crystalline films, its OEG side chains are prone to adsorb ambient moisture. These chains act as hotspots for hydrogen bonding with atmospheric water molecules that locally dissociate when a bias voltage is applied, resulting in a mixed electronic/protonic long-range conduction throughout the film. Due to the OEG-BTBT molecules’ orientation with respect to the surface and structural defects within the film, water molecules can access the humidity-sensitive sites of the SiO₂ substrate surface, whose hydrophilicity can be tuned for an improved device response. The synergistic chemical engineering of materials and interfaces is thus key for designing highly sensitive humidity-responsive electrical devices whose mechanism relies on the interplay of electron and proton transport.

This article presents MoS ₂ -based FETs as potential Hg ²⁺ sensors, providing a genuine insight into the affinity between heavy metal ions and defectiveness in 2D materials. The sensors markedly displayed high selectivity, sensitivity and reversibility.