Dejun Yang

Upon entering aquatic ecosystems, coal fly ash (CFA) particles and their leachates distribute across all environmental compartments, from surface water to benthic sediments, rendering them accessible to aquatic organisms spanning multiple trophic levels. Although CFA is widely classified as non-hazardous waste, a growing body of toxicological evidence demonstrates its capacity to induce significant adverse biological effects. This discrepancy between laboratory-demonstrated toxicity and its current non-hazardous regulatory status highlights a critical knowledge gap in risk assessment frameworks and testing philosophies. Herein, we provide a comprehensive review of CFA characterization techniques, leaching methodologies and their environmental relevance, and the aquatic ecotoxicity of both particulates and leachates to primary, secondary, and tertiary consumers. Based on the findings from the review, we propose four paradigm shifts to more accurately characterize CFA ecotoxicological risks: from standardized leaching protocols to application-specific and maximum leachability tests, from single-species assays to multi-trophic-level bioassays, from single-metal analysis to comprehensive, whole-matrix testing that integrates particulate and dissolved fractions, and from standardizing the reporting of CFA provenance, coal types, and combustion conditions to meaningful meta-analyses and cross-study comparisons. It is believed that these suggestions will substantially advance the realistic ecotoxicological assessment of CFA and bridge the gap between laboratory toxicity data and regulatory classification.

The limited availability of phosphorus (P) in soil poses a critical constraint on agricultural productivity, and sustainable P fertilization practices are of great importance for crop production. In this study, we developed a novel dual-function granular material (RMG) derived from red mud, a waste residue from the aluminum industry. This material is capable of adsorbing P in P-rich soils and releasing P in P-deficient soils, thereby enabling the sustainable use of red mud and P fertilizer. The influences of RMG on the migration and transformation of P in soil were investigated. Application of RMG significantly increased the critical threshold for P leaching, thereby effectively mitigating P loss. In the initial stage of leaching, P in the leachate was present predominantly as particulate phosphorus, whereas molybdate-reactive P became the dominant form in later stages. With increasing RMG dosage, the pH of the leachate rose while the total phosphorus concentration declined, indicating that alkaline components in RMG promoted the adsorption and precipitation of phosphates in soil. The release behavior of P from P-enriched RMG was also examined. The results showed that the total soil P content increased progressively with higher RMG dosage and longer cultivation duration. Elevated temperature and soil moisture content were found to enhance the release and migration of P from RMG into the soil. SEM-EDS analyses revealed that released components (e.g., Ca²⁺ and Fe³⁺) from RMG formed relatively stable complexes with free phosphates. Moreover, adsorption of P onto the RMG surface further facilitated its migration and transformation within the soil. The research findings provide valuable insights for the simultaneous pollution remediation and resource utilization of red mud and phosphorus.

China’s loess deposits exhibit high vulnerability to deformation under precipitation and snowmelt, posing significant risks to infrastructure. This study utilized enzyme-induced carbonate precipitation (EICP) to enhance the mechanical properties of Yili loess. Comparative analyses of untreated and EICP-treated samples were conducted using unconfined compression strength (UCS) tests, unconsolidated–undrained (UU) triaxial shear tests, and scanning electron microscopy (SEM). Results demonstrated that urease activity increased markedly between 25–65 °C, while calcium carbonate production peaked at 55 °C before declining. EICP treatment elevated UCS by 52% relative to untreated soil and altered the failure mechanisms: untreated specimens failed through penetrating shear cracks, whereas treated specimens exhibited compressive failure with vertical fissures. Triaxial tests confirmed enhanced properties in EICP-stabilized loess, showing 8.3–10.7% higher failure strength and 15.7% greater cohesion (increasing from 31.3 kPa to 36.2 kPa), while the internal friction angle remained largely unchanged. Microstructural analysis revealed that EICP generated continuous cementitious layers and crystal bridges of vaterite, transforming particle contacts from point-to-point to surface-to-surface interfaces. Simultaneously, crystal precipitation reduced pore sizes and increased tortuosity. These micro-scale modifications improved interparticle friction constraints and stress transfer efficiency, thereby enhancing the macroscopic mechanical performance. The findings validate EICP’s efficacy for stabilizing collapsible loess deposits and provide insights for geohazard mitigation in similar engineering contexts.

Soil heavy metal contamination is one of the most severe global environmental challenges today. Microbiologically induced calcite precipitation (MICP), as an environmentally friendly bioremediation technique, demonstrates significant potential in addressing such pollution. To optimize the MICP process, the research systematically investigated the influence of urea concentration on the remediation of soils co-contaminated with cadmium (Cd) and nickel (Ni). A highly efficient urease-producing strain, SX4 (Enterobacter sp.), was isolated from mining areas, showing the highest urease activity (conductivity change: 22.14 mS·cm⁻¹) among all isolates. Under optimal growth conditions (pH = 7, urea concentration 20 g·L⁻¹, OD₆₀₀ = 1.76), the remediation cycles for Cd– and Ni-contaminated soils were 120 h and 132 h, respectively. Evaluation of different urea concentrations (0, 10, 20, 40 g·L⁻¹) confirmed that the 20 g·L⁻¹ group was the most effective. It achieved effective removal rates of 45.71% and 43.34% for Cd and Ni, respectively, in single-pollutant contamination, and 32.44% for Cd and 38.75% for Ni, in co-polluted conditions. The findings elucidate the pivotal role of urea concentration in the MICP remediation process, providing crucial scientific evidence for optimizing the practical engineering parameters of this technology.

Mining leads to soil degradation and land subsidence, resulting in decreased soil quality. However, there are limited studies on the detailed effects of mining activities on soil properties, particularly in western aeolian sand. This study, therefore, quantitatively assessed the aeolian sandy soil disturbance induced by mining activities in the contiguous regions of Shanxi, Shaanxi, and Inner Mongolia. The following soil physical quality indices were measured in the pre (May 2015), mid (October 2015), and postmining period (April 2016), such as the soil water content (SWC), particle size (PS), soil penetration (SP), and soil saturated hydraulic conductivity (SSHC). The results showed that mining activities brought irreversible effects on soil structures. In the pre‐mining period, land subsidence broke up large soil particles, destroying soil structure, leading to decreased PS (218.33 vs. 194.36 μm), SP (4615.56 vs. 2631.95 kPa), and subsequently decreased SSHC (1.12 vs. 0.99 cm/min). Rainfall during the midmining period exacerbated this fragmentation. Thereafter, low temperatures and humidity caused the soil to freeze, allowing the small soil particles to merge into larger ones. Meanwhile, the natural re‐sedimentation, subsidence, and heavy mechanical crushing in the post‐mining period increased PS and SP. The SSHC hence increased to 1.21 cm/min. Furthermore, the evaluation of soil indices from different stress zones showed that the external pulling stress zone always had a higher SSHC than the neutral zone in any mining period, possibly due to the presence of large cracks and high SWC. This study contributes to the understanding of the impact of mining activities on soil physical qualities, providing a theoretical basis and quantitative guidance for the surface damage caused by coal mining in the aeolian sandy area in Western China.

The rapid development of urbanization has led to population growth, increased resource consumption, and intensified environmental pollution. Consequently, urban ecological security has increasingly become a key factor constraining the sustainable development of socio-economic systems. This study constructed an urban ecological security evaluation system based on the Pressure-State-Response (PSR) model and used Xuzhou, a typical coal resource city, as a case study to apply and validate the model. Specifically, the analytic hierarchy process and entropy weight method were used to determine the index weights, and the ecological security index was used to evaluate the ecological security status of each system in Xuzhou from 2006 to 2022. Finally, the grey prediction GM (1,1) model was used to predict the ecological security status of Xuzhou in the next five years. The results show that the “disposal capacity of waste gas treatment facilities”, “per capita disposable income”, and “agricultural fertilizer application intensity” occupy a large weight in the whole evaluation system. The pressure index generally showed a fluctuating upward trend, and the state index fluctuated around 0.12. There is a simultaneous upward trend in the response index and the composite index. The ecological security level of the composite index has increased from “unsafe” in 2006 to “relatively safe” in 2022 and will continue to improve to “ideal security” in the future. This study provides a scientific basis for the formulation of sustainable development policies in Xuzhou and also provides a reference for the ecological safety management and assessment of other similar cities.

Soil sampling and in situ measurements were conducted at 24 locations at three time points from May 2015 to April 2016. The statistical analysis showed that the variabilities of soil water content and soil penetration were moderate, while particle size and soil saturated hydraulic conductivity varied considerably. Rainfall before measurements contributed positively to the mean soil water content and negatively to particle size. This was mainly due to the soil aggregates and large soil particles being broken into smaller particles from rain splash. The detached small-sized soil particles could coalesce into larger-sized ones and even soil aggregates. Stressors in zones differ, resulting in variations between soil physical quality indices. The point-to-point comparisons indicated that the mean measured soil water content and soil saturated hydraulic conductivity were similar, if the measurements for these two indices were conducted under similar weather conditions during the same period between years. The investigation on the relationships among soil physical quality indices showed a negative relationship between the measured soil water content and soil saturated hydraulic conductivity. A positive correlation was also found between soil particle size and soil saturated hydraulic conductivity. Lower soil strength resulted in higher soil saturated hydraulic conductivity. Keyword : coal mining subsidence, particle size distribution, post-mining period, soil penetration, soil saturated hydraulic conductivity, soil water content

Underground mining activities can easily trigger surface subsidence and cause damage to surface soil. However, there is still a lack of studies on damaged soil, restricting ecological remediation in mining-induced subsidence regions to a certain degree. Focusing on the particular example of No. 4 Mine in Yili, Xinjiang, China, this study comprehensively combined field sampling, laboratory experiments, and data analysis to investigate the variation rules of basic physical properties and shear characteristics of soil samples. The latter had different subsidence degrees (0, 0–20, 20–40, and above 40 cm) and various depths (0– 10, 10–20, 20– 40, 40–60, and 60–80 cm). The experimental results show that: First, the natural density and dry unit weight of shallow soil in the serious-subsidence region were more significantly affected by mining-induced subsidence than the conditions in the deep layer, which also dropped with the increase in subsidence degree (with a mean drop rate of 7%). Second, serious subsidence could greatly counteract the positive effect of slight and moderate subsidence on the soil shear strength, with a drop rate of up to 30.7%. Third, compared with soil physical indices, mining-induced subsidence more easily affected shear strength indices. In particular, the soil samples taken from 0 to 10 cm depth in the slight subsidence area and 60–80 cm depth in the moderate subsidence area were most significantly affected by mining-induced subsidence, with PCA comprehensive scores of over 1.5. The present study can con-tribute to gaining in-depth knowledge of the damage characteristics of surface soil under mining-induced subsidence and provide a theoretical foundation for formulating reasonable coal mining strategies and ecological protection measures.