Mianli Huang

With worsening global energy and ecological crises, clean hydrogen (H2) production has become a research hotspot in energy science, and sonocatalytic H2 production shows unique potential by converting waste mechanical...

CdS@ZnS core shell nanocomposites were prepared by a one-pot hydrothermal route. The morphology of the composite was tuned by simply changing the Zn²⁺ precursor concentration. To characterize the samples prepared, various techniques were employed, including XRD, FESEM, TEM, XPS and UV-vis DRS. The band gaps of CdS and ZnS were measured to be 2.26 and 3.32 eV, respectively. Compared with pure CdS, the CdS@ZnS samples exhibited a slight blue shift, which indicated an increased band gap of 2.29 eV. The CdS@ZnS core shell composites exhibited efficient photocatalytic performance for H₂ generation under simulated sunlight illumination in contrast to pure CdS and ZnS. Additionally, an optimized H₂ generation rate (14.44 mmol·h⁻¹·g⁻¹_cat) was acquired at CdS@ZnS-2, which was approximately 4.6 times greater than that of pure CdS (3.12 mmol·h⁻¹·g⁻¹_cat). Moreover, CdS@ZnS heterojunction also showed good photocatalytic stability. The process of charge separation over the photocatalysts was investigated using photoelectrochemical analysis. The findings indicate that the CdS@ZnS nanocomposite has efficient charge separation efficiency. The higher H₂ generation activity and stability for CdS@ZnS photocatalysts can be attributed to the intimate interface in the CdS@ZnS core–shell structure, which promoted the light absorption intensity and photoinduced charge separation efficiency. It is expected that this study will offer valuable insights into the development of efficient core shell composite photocatalysts.

Solar energy is an inexhaustible clean energy. However, how to improve the absorption efficiency in the visible band is a long-term problem for researchers. Therefore, an electromagnetic wave absorber with an ultra-long absorption spectrum has been widely considered by researchers of optoelectronic materials. A kind of absorbing material based on ZnS material is presented in this paper. Our purpose is for the absorber to achieve a good and wide spectrum of visible light absorption performance. In the wide spectrum band (553.0 THz–793.0 THz) of the absorption spectrum, the average absorption rate of the absorber is above 94%. Using surface plasmon resonance (SPR) and gap surface plasmon mode, the metamaterial absorber was studied in visible light. In particular, the absorber is insensitive to both electric and magnetic absorption. The absorber can operate in complex electromagnetic environments and at high temperatures. This is because the absorber is made of refractory metals. Finally, we discuss and analyze the influence of the parameters regulating the absorber on the absorber absorption efficiency. We have tried to explain why the absorber can produce wideband absorption.