Azar Asadi

Recent research proclivity is about supplying water for drinking, urban and industrial applications which is recognized as one of the most significant challenges that threaten humanity. Giving its simplicity and high efficient yield, membrane technology has been preferred compared to other separation technologies for water and wastewater treatment. In the present research, KIT-6 (KIT: Korea Advanced Institute of Science and Technology) was functionalized by H-acid to improve hydrophilic functional groups on KIT-6 surface. Different characterization tests were performed to prove the insertion of H-acid on KIT-6 (H-KIT-6), e.g., FT-IR, XRD, zeta potential and FESEM analysis. Also, the effects of different loading of KIT-6 and H-KIT-6 on the morphology, characteristics and performance of Polysulfone (PSf) nanofiltration (NF) membranes were investigated. The maximum pure water flux (30.2 kg/m² h), the lowest irreversible fouling ratio (3.96%) and the highest flux recovery ratio (96.04%) were obtained for the membrane embedded with 0.1 wt.% H-KIT-6 (optimum membrane). Also, the performance of the synthesized membranes was evaluated by rejection of four different salts (K₂SO₄, MgSO₄, KCl and NaCl) and heavy metal ions (As³⁺ and Hg²⁺). The NF membrane embedded with 0.1 wt.% H-KIT-6 also presented the highest rejection of different salts and heavy metal ions (As³⁺ = 99.85% and Hg²⁺ = 99.27%) compared to the others. Finally, the performance of the optimum membrane to treat a real case of Gachsaran brackish water was assessed. As a result, by applying the optimum membrane, 565 mg/l, 28 mg/l and 27 mg/l of Ca²⁺, SO₄²⁻ and Mg²⁺ were rejected, respectively.

The health of drinking water is an important criterion for developed countries and around half of the world’s population is deprived of sanitary and safe drinking water. By identifying the time of pollution occurrence and the places that are most sensitive to pollution the management of the quality of drinking water can be planned. Since the landfill for Yasouj, a city in Iran, was located in a higher place than the drinking water wells, which were drilled in a karst aquifer, the safety of the drinking water resources (including eight wells) of Yasouj were investigated in the present study. For this purpose, different parameters, comprising the concentration of eight heavy metals and eight ions, alkalinity, total harness, pH, biological oxygen demand (BOD5) and total coliform, were measured over 12 months and the obtained data were compared with the WHO’s and Iran’s drinking water standards. To assess the measured data statistically, SPSS software was applied. From the reported results, the water characterizations of the wells complied with the mentioned standards; however, four of the wells were more prone to supply higher quality water. It is noted that Hg, Cd, and the total coliform of wells were close to the permissible values reported by both the aforementioned standards. Therefore, the water obtained from wells should be disinfected before using and Hg and Cd concentrations need to be monitored regularly to prevent poisoning. Due to the rapid movement of pollutants in karst areas, it is very important to detect their presence in the water resources over time. Consequently, continuous monitoring and sampling is one of the most important protection dealings for karst aquifers.

As discharging oily wastewater from industries to the environment is a potential threat for the aquatic ecosystem, in this research, oil removal from a real case of Kermanshah polymer production plant wastewater was investigated. The focus of this study was on improving the oil rejection performance of polyethersulfone (PES) ultrafiltration membrane due to adding cellulose nanocrystals (CNC) and modified CNC with serine amino acid (CNC-Ser) in PES mix matrix. From the results, the membranes embedded with CNC-Ser showed better performance in terms of water flux, flux recovery ratio, and oil rejection (higher than 97%) compared to the modified membranes with CNC. The lowest water contact angle (41.37°), smoother surface, and higher negative surface potential (− 24 mV) were achieved for the optimum loading of CNC-Ser. Besides, long-term performance of the membranes with optimum loading of CNC and CNC-Ser were compared in both dead-end and cross-flow setups.