Shuo Wang

The polylactic acid (PLA) resin Ingeo 4032D was selected as the research object, with a focus on PLA modification by using polymers such as linear low-density polyethylene (LLDPE), high-density polyethylene (HDPE) and ethylene–propylene-diene monomer grafted with glycidyl methacrylate (EPDM-g-GMA), by using fillers such as nano calcium carbonate and zeolite. In order to characterize the deposition effect of Al₂O₃ on the film surface by plasma-assisted atomic layer deposition, Bio-oriented PLA (BOPLA) with more uniform thickness than blown film was purchased for study. The mechanical properties, friction coefficient, surface contact angle and water vapour transmission rate of the modified PLA film were compared and discussed. The aim was to find out the most influencing factors of film’s water vapour resistance.

The polylactic acid (PLA) resin Ingeo 4032D was selected as the research object. Epoxy soybean oil (ESO) and zeolite (3A molecular sieve) were used as plasticizer and reinforcing filler, respectively, for PLA blend modification. The mixture was granulated in an extruder and then blown to obtain films under different conditions to determine the optimum processing temperatures and screw rotation. Then, the thermal behaviour, crystallinity, optical transparency, micro phase structure and physical properties of the film were investigated. The results showed that with increasing zeolite content, the crystallization behaviour of PLA changed, and the haze of the film increased from 5% to 40% compared to the pure PLA film. Zeolite and ESO dispersed in the PLA matrix played a role in toughening and strengthening. The PLA/8 wt% zeolite/3 wt% ESO film had the highest longitudinal tensile strength at 77 MPa. The PLA/2 wt% zeolite/3 wt% ESO film had the highest longitudinal elongation at 13%. The physical properties depended heavily on the dispersion of zeolite and ESO in the matrix.