Renjie Niu

Recent studies have proposed usage of biochar as a substrate amendment in green infrastructure, such as green roofs and bio-filtration units. However, understanding of the variation in physio-chemical properties of biochar due to the production process and feedstock is still lacking. The present study investigated the effects of pyrolysis temperature and feedstocks on the hygroscopic water content and physio-chemical properties of biochar. Biochars were produced from three feedstock types, invasive vegetation (i.e., water hyacinth), non-invasive vegetation (i.e., wood) and one animal waste (i.e., chicken manure). Biochar was produced at two different pyrolysis temperatures (i.e., 300 °C and 600 °C). Scanning electron microscopy + energy dispersive spectrometry (SEM + EDS), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) were performed on all samples to analyze the surface morphology, pore size, element content, functional groups, and chemical bonds. Relative humidity was adjusted to reflect the biochar’s hygroscopic property by measuring the maximum moisture content at the sample equilibrium state. The characterization reveals that the lowest carbon content (42.78%) was found at 300 °C for water hyacinth biochar (WHB). The highest carbon content (92.14%) was found at 600 °C for wood biochar (WB). As the pyrolysis temperature increased, the mean pore volume (from 0.03 to 0.18 cm³/g) and diameter (from 8.40 to 10.33 nm) of the WHB increased. However, the pore diameter of chicken manure (CB) decreased (from 9.23 nm to 7.53 nm) under an increase in pyrolysis temperature. For a given pyrolysis temperature, the hygroscopicity of WHB was highest among all biochars. With an increase in pyrolysis temperature, the hygroscopicity of biochars changed differently. The hygroscopicity of WHB decreased from 82.41% to 44.33% with an increase of pyrolysis temperature. However, the hygroscopicity of CMB and WB remained unchanged. This study suggests that production process of biochars need to be considered for appropriate selection as substrate material in green infrastructure. Further, it promotes the establishment of commercial production of biochar for usage in green infrastructure.

The influence of biochars on water retention, mitigating nutrient leaching, and pollutant removal in green infrastructure has been explored in the past. However, there is a lack of understanding on how feedstock (i.e., biomass) would affect biochar physicochemical properties and hence, overall erosion control (including infiltration, surface, and sub-surface runoff) in green infrastructure. The main purpose of this study was to investigate the effect of biochars produced from three different feedstocks (pig manure, wood, and kitchen waste) on the erosion of granite residual soil. Flume experiments were conducted to measure and analyze soil erosion, runoff, and infiltration. The result showed that the runoff and soil erosion of kitchen waste biochar (KWB) samples were reduced by 17.7% and 21.7%, respectively. On the contrary, wood biochar (WB) and pig manure biochar (PMB) were found to enhance runoff and soil erosion. In addition, biochar particles were found in runoff and infiltration in erosion experiment. Thus, it is important to note that measures should be taken to prevent biochar loss when using biochar as a soil amendment. Additionally, the effects of different types of biochar on soil hydraulic and hydrophobicity properties should be taken into account as a selection criterion for choosing amendments in green infrastructure. This study finds that kitchen waste biochar has better performance in improving soil hydraulics and erosion.