Ziyong Ma

Using renewable D-gluconic acid δ-lactone as the starting material, two novel glucosamide-based organosilicon quaternary ammonium surfactants (2/3SiDDGPBH) were synthesized through an environmentally friendly three-step process involving amidation, hydrophobic modification, and quaternization. Comprehensive characterization demonstrated their exceptional performance: surface tension reduction to 33.4 mN/m (2SiDDGPBH) and 33.64 mN/m (3SiDDGPBH), uniform spherical micelles (1–10 nm and 30–100 nm) were formed, and outstanding foam properties with 3SiDDGPBH developed, showing superior foamability and stability. Material modification tests on polymethyl methacrylate (PMMA) plates, mature acacia leaves, oilpaper, vegetable-tanned top-grain leather, and melamine-formaldehyde resin (MFR) faced with plywood revealed excellent spreading performance and durability, particularly for 3SiDDGPBH-treated MFR plywood, which maintained excellent spreading performance even after 80 washing cycles. Scanning electron microscopy (SEM) analysis confirmed that the Si wt% of MFR plywood treated with 2/3SiDDGPBH and scrubbed MFR plywood both exhibited a significant increase, and the 3SiDDGPBH-treated MFR plywood demonstrated superior bonding properties. These surfactants combine low surface tension, excellent foaming properties, and outstanding spreading performance, demonstrating broad application prospects in fields such as pesticide adjuvants, industrial and household cleaning agents, cosmetics, oilfield extraction, textile printing and dyeing, and functional coatings.

Cylindrical gears are used extensively due to their significant advantages including high efficiency, high load-bearing capacity, and long lifespan. However, the machining accuracy of cylindrical gears is significantly affected by motion errors and force-induced errors of machine tools. In this study, a motion error model of the machine tools was established based on multi-body system theory and homogeneous coordinate transformation method, quantifying the contributions and variation patterns of 12 key errors in the A and B-axes to workpiece geometric errors. Then, by using the stiffness analytical model and the spatial meshing theory, the influence of the force-induced elastic deformation of the shaft of rolling wheel and the springback of the workpiece tooth flank on the geometric error was revealed. Finally, taking the through rolling of a spur cylindrical gear with a module of 1.75 mm, a pressure angle of 20°, and 46 teeth as an example, the force-induced elastic deformation model of the shaft was verified by the rolling tests. Results show that for 40CrNiMo steel, the total profile deviation, total helix deviation, and single pitch deviation in the X-direction caused by rolling forces are 32.48 μm, 32.13 μm, and 32.13 μm, respectively, with a maximum contact rebound is δ_c = 28.27 μm. The relative error between theoretical and measured X-direction spindle deformation is 8.26%. This study provides theoretical foundation and experimental support for improving the precision of rolling process.