Dihua Ouyang

In the field of energy-containing materials, the modification of nanoaluminum powders has been widely studied. However, in modified experimental design, the lack of theoretical prediction usually leads to long experimental cycles and high resource consumption. To this end, this study evaluated the process and effect of dopamine (PDA)-and polytetrafluoroethylene (PTFE)-modified nanoaluminum powders based on molecular dynamics (MD). Through the calculation of the coating stability, compatibility, and oxygen barrier performance of the modified material, the modification process and effect were explored from a microscopic point of view. The results showed that the adsorption of PDA on the nanoaluminum was the most stable, and the binding energy was 463.03 kcal center dot mol-1. PDA and PTFE with different ratios are compatible systems at 350 K, and the best compatibility ratio is 10 wt % PTFE/90 wt % PDA. The 90 wt % PTFE/10 wt % PDA bilayer model has the best barrier performance for oxygen molecules in a wide temperature range. The calculated results of the coating stability agree with the experiments, and it is pointed out that it is feasible to evaluate the modification effect in advance by MD simulation. In addition, the simulation results concluded that the double-layered PDA and PTFE have better oxygen barrier properties. Compatibility can be used only to determine whether phase separation occurs between mixtures and is not directly related to the dense mixing of polymers and the barrier properties of small gas molecules. The simulation provided in this article can predict the experimental results and provide theoretical guidance for coating modification experiments in order to reduce unnecessary experiments, shorten the experimental cycle, and reduce costs.

Studying how to improve the performance of illuminating agents to meet the requirements of ammunition miniaturization of great importance. In this study, a simple method for increasing light radiation intensity through the adding of metal oxides was developed and tested. Results revealed that the metal oxides had a very strong effect on the light radiation intensity of the reaction system. Optical radiation intensity increased by 17.8%, − 5.4% and 25.9% after the addition 5% of MgO, Al₂O₃and BaO to the Ba(NO₃)₂/Mg reaction system, respectively. This phenomenon may be related to the light radiation characteristics and reactivity of the metal oxide itself, as well as the temperature at which the added metal oxide can be excited to radiate light intensity.

As a hot research topic, nano-scale energetic materials have recently attracted much attention in the fields of propellants and explosives. The preparation of different types of nano-sized energetic materials were carried out, and the effects of nano-sized energetic materials (nEMs) on the properties of solid propellants and explosives were investigated and compared with those of micro-sized ones, placing emphasis on the investigation of the hazardous properties, which could be useable for solid rocket nozzle motor applications. It was found that the nano-sized energetic materials can decrease the impact sensitivity and friction sensitivity of solid propellants and explosives compared with the corresponding micro-sized ones, and the mechanical sensitivities are lower than that of micro-sized particles formulation. Seventy-nine references were enclosed.

Bubble volume and bubble geometry are key parameters that affect the movement and acoustic radiation performance of bubble columns. This paper proposes an image processing method to study the movement and acoustic radiation characteristics of the rising bubbles originating from the combustion of a pyrotechnic composition based on high-speed photography. Results showed that during the rise of bubbles, their shape gradually changed from spherical to irregular, and their rising trajectory presented a curvilinear form. After the rising velocities of the bubbles in the z and x directions were compared, the results revealed that the rising velocity of the bubbles was unstable. The velocity of the rising bubbles in the direction of the z axis was much higher than that of the x axis. Meanwhile, the acceleration of bubble volume decreased first and then increased. This process was repeated; however, the amplitude of increase or decrease was inconsistent, which led to the generation of a certain amount of acoustic radiation effect, and it had a similar trend of change with the acceleration of bubble volume.