Zhengxin Yin

The Yong’an-Meixian Late Paleozoic Hercynian depression, located in western Fujian-eastern Guangdong, is an important metallogenic belt in China. The Yushui copper-polymetallic massive sulfide deposit from the middle part of the depression, with extremely high copper grades, has attracted considerable attention and research interest from geologists for years. In most previous research, the ore-forming material source and metallogenic process were inferred from indirect evidence (i.e., using H-O-C-S isotopic systematics as geochemical tracers). In this paper, the ore-forming process of the Yushui deposit has been studied directly by using nontraditional stable (Fe–Cu) isotopes for the first time, providing new evidence for the genesis of this deposit. The results show that there is a relatively negative Fe-Cu isotopic composition in the Yushui deposit, with δ⁵⁶Fe values ranging from −0.519 to −1.063‰ and δ⁶⁵Cu values ranging from −1.539 to −1.609‰, respectively. The fractionation of Fe isotopes is primarily attributed to hydrothermal leaching of the basement strata by ore-forming fluids, along with rapid precipitation of sulfides during the ore-forming process. On the other hand, the fractionation of Cu isotopes is probably controlled by the relatively low temperature of ore formation, sulfide precipitation and the involvement of organic matter in mineralization. Combining our findings with previous studies, the ore-forming materials of the Yushui deposit are likely derived from the basement ore-bearing strata (pre-Devonian strata) through leaching by hydrothermal fluids. Moreover, some of the ore bodies might have been locally overprinted by late-stage hydrothermal reworking and alteration.

Submarine hydrothermal sulfides from the ultraslow-spreading Southwest Indian Ridge (SWIR) were sampled from three hydrothermal fields, and the Fe-Cu-Zn isotopic compositions were analyzed in this study. The Fe isotopes ranged from −0.011‰ to −1.333‰. We believe the processes controlling the Fe isotope variability in the hydrothermal systems include the sulfide precipitation process, the initial isotopic composition of the hydrothermal fluid, and the temperature during precipitation. Among these factors, the sulfide precipitation process is the dominant one. The Cu isotope compositions of the sulfides varied from −0.364‰ to 0.892‰, indicating that the hydrothermal fluid preferentially leached ⁶⁵Cu in the early stages and that hydrothermal reworking led to decreases in the Cu isotopes in the later stages. In addition, because mass fractionation occurred during sulfide precipitation, the Zn isotope variations ranged from −0.060‰ to 0.422‰. Combined with the S isotopic compositions, these results also implied that different Fe-Cu-Zn isotopic fractionation mechanisms prevailed for the different sample types. Based on these results, we are sure that the metallic elements, including Fe, Cu, and Zn, were derived from the mantle in the SWIR hydrothermal field, and the Fe-Cu isotope results indicated that these metallic elements were provided by fluid leaching processes. Using the isotopic fractionation and sulfide results, we calculated that the Fe-Cu-Zn isotopic compositions of the hydrothermal fluid in this field were δ⁵⁶Fe_(fluid): −0.8~0.0‰; δ⁶⁵Cu_(fluid): 0.3~1.3‰; and δ⁶⁶Zn_(fluid): 0~0.48‰.

The sediments distributed in the marginal seas of the continental shelf are important burial materials for global organic carbon (OC). There have been many estimates of the global continental shelf OC reserves, but due to the limited acquisition of measured data, the estimated results have great uncertainty. The vast continental shelf in the northern part of the South China Sea (SCS) provides a good place for the storage of OC. Based on a large amount of sediment OC data obtained from the northern coast of the SCS, the OC storage in the surface sediment (0~10 cm) in the study area (approximately 8.63 × 10⁴ km²) was accurately calculated as 51 Tg. The study area covers different regions, such as estuaries, open seas, strait areas and upwelling development areas, and the OC content of each area is quite different. According to provenance analysis, the source of OC in sediments is mainly from the input of Pearl River runoff. The OC content is significantly higher and less affected by sediment particle size in the Pearl River Estuary and the surrounding areas; meanwhile, the OC content gradually decreases with the distance from the Pearl River Estuary. Far from the western Pearl River Estuary, the sediment OC content is mainly controlled by the particle size of the sediments and is significantly correlated with silt and clay content. The deposition rate is also an important factor affecting the burial of OC, for the high deposition rates correspond to the high levels of OC in the nearshore estuarine areas, as well as the low deposition rate region having low OC content in the sediments even though it has a high productivity of OC, such in as the upwelling sea area on the eastern side of Hainan.

We present geological, bulk-rock geochemical and Sr–Nd–Hf isotopic data for mafic rocks from the West Philippine Basin (WPB). These mafic rocks comprise pillow basalts characterized by a vesicular structure. The mid-ocean ridge basalt (MORB)-normalized trace element patterns of basalts from the study area display depletions in Nb. In addition, the chondrite-normalized lanthanide patterns of basalts from the WPB are characterized by significant depletions in the light lanthanides and nearly flat Eu to Lu segments. The investigated rocks have initial ⁸⁷Sr/⁸⁶Sr ratios (⁸⁷Sr/⁸⁶Sr(i)) of 0.703339–0.703455 and high ε_Nd(t) values (8.0 to 8.7). Furthermore, basalts from the WPB have ¹⁷⁶Hf/¹⁷⁷Hf ratios that range from 0.28318 to 0.28321 and high ε_Hf(t) from 15.2 to 16.3. Semi-quantitative modeling demonstrates that the parental melts of basalts from the study area were derived by ~20% adiabatic decompression melting of a rising spinel-bearing peridotite source. The Sr–Nd–Hf isotopic compositions of basalts from the WPB indicate that their parental magmas were derived from an upper mantle reservoir possessing the so-called Indian-type isotopic anomaly. Interpretation of the isotopic data suggests that the inferred mantle source was most likely influenced by minor inputs of a sediment melt derived from a downgoing lithospheric slab. Collectively, the petrographic and geochemical characteristics of basalts from the study area are analogous to those of mafic rocks with a back-arc basin (BAB)-like affinity. As such, the petrogenesis of basalts from the WPB can be linked to upwelling of an Indian-type mantle source due to lithospheric slab subduction that was followed by back-arc spreading.