Zongjia Qiu

The accuracy of lithium-ion battery thermal-runaway early warning is strongly affected by the State of Charge (SOC). To improve the adaptability of fixed-threshold strategies, this study investigated SOC-dependent temperature and gas responses of 18650 LiNi₁/₃Co₁/₃Mn₁/₃O₂/graphite cells under thermal abuse at 50%, 75%, and 100% SOC, representing limited and complete thermal-runaway scenarios respectively, using a sealed pressure-resistant chamber. Temperature and chamber concentrations of characteristic gases, including CO₂, CO, C₂H₄, and CH₄, were monitored. The results show that higher SOC lowers the critical temperature for rapid self-heating, advances characteristic gas appearance, and increases the measured chamber gas concentrations by approximately 2.1–2.8 orders of magnitude. Reaction-kinetics analysis indicates that stronger electrolyte reduction by highly lithiated graphite at high SOC is the main reason for the different gas-evolution patterns. Based on these findings, an SOC-adaptive dual-parameter threshold model combining temperature and CO₂ concentration was established and retrospectively evaluated. The model provides earlier and more balanced warnings than fixed-threshold strategies, while the limitations associated with discrete GC-MS sampling and practical BMS implementation are discussed.

Lithium-ion batteries (LIBs) may experience thermal runaway (TR) under thermal abuse conditions, posing significant safety risks to energy storage systems, electric vehicles, and portable electronics. To ensure the safety of LIB-powered applications, developing an effective TR early warning method is crucial. This study employs polyimide-coated femtosecond fiber Bragg grating (FBG) sensors to investigate TR characteristics in 18,650 LIBs (LiNi_1/3Mn_1/3Co_1/3O₂/graphite), including TR onset temperature determination and the evolution of temperature and radial strain at different states of charge (SOCs). Compared with existing studies, the polyimide-coated femtosecond FBGs employed here offer superior breakage resistance and high-temperature tolerance, enabling more precise temperature and strain measurements. For radial strain monitoring obtained during high-temperature-induced LIBs thermal runaway experiments, temperature compensation was achieved using polyimide-coated femtosecond FBG temperature sensors, yielding higher-accuracy strain evolution profiles. Experimental results demonstrate that the higher-SOC LIBs exhibit more severe TR eruptions, with 1.76× higher peak temperatures and 1.3× greater mass loss than low-SOC LIBs. The proposed scheme pioneers an new approach to effective active safety warning of LIBs thermal runaway.

To address the issues of quadrature component attenuation and signal-to-noise ratio (SNR) degradation caused by carrier phase delay in Phase-Generated Carrier (PGC) demodulation, this paper proposes a phase delay compensation method based on sampling-point shift pre-calibration. By establishing a discrete phase offset model, we derive the mathematical relationship between sampling point shift and carrier cycle duration, and introduce a compensation mechanism that adjusts the starting point of the sampling sequence to achieve carrier phase pre-alignment. Theoretical analysis demonstrates that this method restricts the residual phase error to within Δθ_max = πf₀/f_s, thereby fundamentally avoiding the denominator-zero problem inherent in traditional compensation algorithms when θ approaches 45°. Experimental validation using an Extrinsic Fabry–Perot Interferometric (EFPI) ultrasonic sensor shows that, at a sampling rate of 10 MS/s, the proposed pre-alignment algorithm improves the minimum demodulation SNR by 35 dB and reduces phase fluctuation error to 2% of that of conventional methods. Notably, in 1100 consecutive measurements, the proposed method eliminates demodulation failures at critical phase points (e.g., π/4, π/2), which are commonly problematic in traditional techniques. By performing phase pre-compensation at the signal acquisition level, this method significantly enhances the long-term measurement stability of interferometric fiber-optic sensors in complex environments while maintaining the existing PGC demodulation architecture.

Traditional Fabry–Perot (F–P) sensors are limited by fixed reflectivity and a finite number of interference orders, which restrict their detection sensitivity and resolution to some extent. To improve the fringe finesse (F) of the F–P sensing system, this study proposes a dynamic loop optical design based on 2 × 1 and 1 × 2 fiber-optic couplers combined with an erbium-doped fiber amplifier (EDFA). This design utilizes the phase-accumulation effect within the loop and EDFA gains compensation to extend dual-beam interference into multi-beam interference. Numerical simulations and experimental results show that, under optimized parameters (P1 = P2 = 10%, G = 20 dB), the system's fringe finesse increases from 2.03 to 66.25, a more than 30-fold increase. The full width at half maximum (FWHM) sharpens from 2.63 to 0.08 nm, and the peak normalized intensity variation rate increases from 0.75 to 29.49, nearly a 40-fold increase, significantly enhancing the system's sensitivity and resolution. This approach, through non-invasive optical loop dynamic feedback and parameter optimization, overcomes the performance limitations of traditional F–P sensors, providing a new, to the best of our knowledge, solution for high-precision optical sensing in complex environments such as high temperatures and high pressures. It also demonstrates potential applications in fields like distributed acoustic pressure sensing, high-resolution spectral analysis, and narrow-linewidth laser design.

Fiber optic sensing technology's performance is crucially influenced by the choice of demodulation algorithms. Traditional intensity demodulation methods rely on precisely controlling the working point to the quadrature point (Q point) by adjusting the laser wavelength. However, issues like laser wavelength adjustment accuracy and laser power variations with wavelength affect demodulation accuracy, limiting its application in complex scenarios. Additionally, this method requires sensitivity calibration and has a limited dynamic range. To address these limitations, this paper proposes an amplitude ratio of harmonic components (ARHC) demodulation algorithm. It analyzes the harmonic components of the interference light intensity output by the sensor to calculate Fabry-Perot cavity length changes, achieving real-time demodulation of dynamic signals. Compared to traditional methods, the ARHC algorithm simplifies system adjustment, has a larger demodulation range and higher accuracy, and is more adaptable to environmental changes. Simulations and experiments demonstrate its effectiveness and high-precision, large-dynamic-range signal demodulation capabilities under different interference conditions. The EFPI ultrasonic sensitivity based on the ARHC algorithm is 2.5 nm/Pa@23kHz, and it can linearly demodulate up to a vibration amplitude of 372.8 nm for the sensitive diaphragm, with a demodulation error of less than or equal to 0.8 nm.

The predecessor of China Optics was China Optics and Applied Optics Digest, which was founded in 1985. At that time, it was the only retrieval journal in the field of optics in China. At the end of 2008, China Optics and Applied Optics Digest was renamed 《中国光学》的前身是1985年创办的《中国光学与应用光学文摘》，当时是国内光学领域唯一的检索刊物。2008年底《中国光学与应用光学文摘》转型更名为《中国光学与应用光学》期刊，刊载内容突破了文摘的限制，正式成为学术刊物。

Sulfur dioxide (SO₂) is a key indicator for fault diagnosis in sulfur hexafluoride (SF₆) gas-insulated equipment. In this work, an in situ photoacoustic detection system using an ultraviolet (UV) LED light as the excitation source was established to detect SO₂ in high-pressure SF₆ buffer gas. The selection of the SO₂ absorption band is discussed in detail in the UV spectral regions. Based on the result of the spectrum selection, a UV LED with a nominal wavelength of 285 nm and a bandwidth of 13 nm was selected. A photoacoustic cell, as well as a high-pressure sealed gas vessel containing it, were designed to match the output optical beam and to generate a PA signal in the high-pressure SF6 buffer gas. The performance of the proposed system was assessed in terms of linearity and detection limit. An SO₂ detection limit (1σ) of 0.17 ppm was achieved. Additionally, a correction method was supplied to solve PA signal derivation induced by pressure fluctuation. The method can reduce the derivation from about 5% to 1% in the confirmation experiment.

Accurate quantitative detection for trace gas has long been the center of failure diagnosis for gas-insulated equipment. An absorption spectroscopy-based detection system was developed for trace SF₆ decomposition SO₂ detection in this paper. In order to reduce interference from other decomposition, ultraviolet spectrum of SO₂ was selected for detection. Firstly, an excimer lamp was developed in this paper as the excitation of the absorption spectroscopy compared with regular light sources with electrodes, such as electrodeless lamps that are more suitable for long-term monitoring. Then, based on the developed excimer lamp, a detection system for trace SO₂ was established. Next, a proper absorption peak was selected by calculating spectral derivative for further analysis. Experimental results indicated that good linearity existed between the absorbance and concentration of SO₂ at the chosen absorption peak. Moreover, the detection limit of the proposed detection system could reach the level of 10⁻⁷. The results of this paper could serve as a guide for the application of excimer lamp in online monitoring for SF₆-insulated equipment.