Guojun Li

To reduce water consumption and potential formation damage associated with conventional water-based fracturing fluids while improving the proppant-carrying and flow adaptability of CO₂-based systems without relying on specialized CO₂ thickeners, a CO₂–water polymer hybrid fracturing fluid was developed using an AM/AA copolymer (poly(acrylamide-co-acrylic acid), P(AM-co-AA)) as the thickening agent for the aqueous phase. Systematic experimental investigations were conducted under high-temperature and high-pressure conditions. Fluid-loss tests at different CO₂ volume fractions show that the CO₂–water polymer hybrid fracturing fluid system achieves a favorable balance between low fluid loss and structural continuity within the range of 30–50% CO₂, with the most stable fluid-loss behavior observed at 40% CO₂. Based on this ratio window, static proppant-carrying experiments indicate controllable settling behavior over a temperature range of 20–80 °C, leading to the selection of 60% polymer-based aqueous phase + 40% CO₂ as the optimal mixing ratio. Rheological results demonstrate pronounced shear-thinning behavior across a wide thermo-pressure range, with viscosity decreasing systematically with increasing shear rate and temperature while maintaining continuous and reproducible flow responses. Pipe-flow tests further reveal that flow resistance decreases monotonically with increasing flow velocity and temperature, indicating stable transport characteristics. Phase visualization observations show that the CO₂–water polymer hybrid fracturing fluid system exhibits a uniform milky dispersed appearance under moderate temperature or elevated pressure, whereas bubble-dominated structures and spatial phase separation gradually emerge under high-temperature and relatively low-pressure static conditions, highlighting the sensitivity of phase stability to thermo-pressure conditions. True triaxial hydraulic fracturing experiments confirm that the CO₂–water polymer hybrid fracturing fluid enables stable fracture initiation and sustained propagation under complex stress conditions. Overall, the results demonstrate that the AM/AA copolymer-based aqueous phase can provide effective viscosity support, proppant-carrying capacity, and flow adaptability for CO₂–water polymer hybrid fracturing fluid over a wide thermo-pressure range, confirming the feasibility of this approach without the use of specialized CO₂ thickeners.

A CO₂-responsive TMPDA–SDS–SiO₂ gel system was developed and evaluated through formulation optimization, structural characterization, rheological testing, and core flooding experiments. The optimal formulation was identified as 7.39 wt% SDS, 1.69 wt% TMPDA, and 0.1 wt% SiO₂, achieving post-CO₂ viscosities above 10³–10⁴ mPa·s. Spectroscopic and microscopic analyses confirmed that CO₂ protonates TMPDA amine groups to form carbamate/bicarbonate species, which drive the micellar transformation into a wormlike network, thereby enhancing gelation and viscosity. Rheological tests showed severe shear-thinning behavior, excellent shear recovery, and reversible viscosity changes under alternating CO₂/N₂ injection. The gel demonstrated rapid responsiveness, reaching stable viscosities within 8 min, and maintained good performance after 60 days of thermal aging at 90 °C and in high-salinity brines. Plugging tests in sand-packed tubes revealed that a permeability reduction of 98.9% could be achieved at 0.15 PV injection. In heterogeneous parallel core flooding experiments, the gel preferentially reduced high-permeability channel conductivity, improved sweep efficiency in low-permeability zones, and increased incremental oil recovery by 14.28–34.38% depending on the permeability contrast. These findings indicate that the CO₂-responsive TMPDA–SDS–SiO₂ gel system offers promising potential as a novel smart blocking gel system for improving the effectiveness of CO₂ flooding in heterogeneous reservoirs.

Quasi-dry CO₂ fracturing technology is a new CO₂ fracturing technology that combines liquid CO₂ fracturing (dry CO₂ fracturing) and water-based fracturing. It uses a liquid CO₂ system containing a small amount of water-based fracturing fluid to carry sand, and it is characterized by sand blending at normal pressure, convenient preparation, the integrated application of resistance reduction and sand carrying, and no dedicated closed sand blender requirement. We developed a self-crosslinking emulsion-type water-based fracturing fluid (ZJL-1), which contained ionic bonds, hydrogen bonds, van der Waals forces, and hydrophobic associations, for quasi-dry CO₂ fracturing, and the comprehensive properties of the ZJL-1 fracturing fluid were evaluated. The results showed that the ZJL-1 fracturing fluid had obvious viscoelastic characteristics, a heat loss rate of less than 10% at 200 °C, a good thermal stability, sufficient rheology under high temperature and high shear conditions, and a good thermal stability. The resistance reduction rate reached 70%, which demonstrates a good resistance reduction performance. Compared with conventional guar fracturing fluid, ZJL-1 can carry more sand and has a lower core damage rate. The on-site use of quasi-dry fracturing showed that optimizing the mixing ratio of liquid CO₂ fracturing fluid and ZJL-1 fracturing fluid effectively enhanced oil and gas recovery. This can be used to optimize quasi-dry fracturing and can be used as a reference.

Based on the characteristics of low-permeability oil and gas reservoirs and the requirements for profile control and water plugging and for water cut decrease and production increase in the high water cut stage of the middle and late exploitation periods, ultrafine temperature-resistant and salt-tolerant swellable particles DS-1 suitable for low permeability oilfields were prepared by introducing N,N-dimethylacrylamide(DMAA) monomers into the 2-acrylamido-2-methylpropanesulfonic acid (AMPS)/acrylamide(AM)/N,N-dimethylbisacrylamide ternary crosslinking system. The median of initial particle size was 22.00 μm, and is compatible with formation pore throats. A static water absorption experiment showed that the particles can still maintain a high swelling ratio after 15 days at a high temperature and high mineralization degree, so they have long-term stability. The physical and chemical properties of the particles were analyzed microscopically using the infrared spectrum method and the scanning electron microscope (SEM) method. A dynamic displacement experiment confirmed that the particles can effectively plug dominant channels of waterflooding, increase the injection pressure, and improve the interlayer and intralayer heterogeneity. In the field experiment, the swellable particles DS-1 were used as a main slug for water plugging operations, and a good water cut decrease and oil production increase effect was obtained.

T oilfield is the fractured-vuggy carbonate reservoir at a temperature of around 130 °C, with salinity of up to 22 × 10⁴ mg/L. In order to solve the problem of the high water cut in the late development stage of T oilfield, we selected XN-T from 27 kinds of swelling retarding particles by testing their swelling capacity, and coated a thin film to improve its retarding swelling capacity. The mechanisms of strong water absorption and water-holding abilities of particles were analyzed by infrared spectrometry and SEM. In the core flow experiment, the plugging rate was found to be 98.42%. Finally, the injection parameters of the coated particles were optimized to maximize the water plugging and profile control ability, resulting in an optimal particle size of 0.4–0.6 mm and a mass fraction of 10%.