Germán Pérez-Hernández

This paper describes the thermal and energy performance of three roof configurations: a conventional concrete slab, a BIPV system, and a BIPV system equipped with passive aluminum fins. Three-dimensional transient finite element simulations were carried out under field-measured 24 h meteorological boundary conditions characteristic of hot climates. The objective of this study is to quantify the impact of PV integration and passive cooling strategies on heat transfer behavior and building energy performance. The BIPV roof achieved a 38.4% lower residual temperature than the concrete slab at 19:00, indicating superior heat dissipation. The addition of passive fins reduced module temperature by up to 10–12 °C and decreased peak roof temperature by up to 12%. This temperature reduction decreased electrical losses from 13.2% to 10.4%, resulting in a 21% relative reduction in temperature-induced losses. The predicted temperature ranges (≈60–75 °C under peak conditions) are consistent with values reported in experimental and numerical studies of BIPV systems in hot climates, supporting the physical realism of the model. Convective heat transfer was represented using effective coefficients, providing a computationally efficient engineering approximation of air-side heat exchange. Despite construction cost increases of up to 38%, PV integration achieved competitive payback periods of approximately 8.5–9 months under hot climate conditions. This economic assessment is based on a simple payback approach using an incremental cost formulation, where the photovoltaic system replaces the conventional concrete roof, reducing the effective investment. This study introduces a reproducible 3D transient FEM methodology for evaluating BIPV roofs under field-measured climatic boundary conditions. The framework explicitly couples geometry-resolved passive cooling, full-day thermal evolution, and temperature-dependent electrical losses, providing a physically consistent basis for assessing BIPV design alternatives in hot climates.

The cement industry contributes approximately 7–8% of global CO₂ emissions, motivating the development of sustainable supplementary materials. This study evaluates the partial replacement (10 wt.%) of Portland cement with calcium carbonate (CaCO₃) derived from oyster shells, both untreated and thermally treated at 600 °C, in non-structural mortar blocks. Structural and physicochemical characterization was performed using XRD, SEM, EDS, BET, and TGA to assess phase composition, morphology, and surface properties. Thermal treatment modified the textural characteristics of CaCO₃, reducing the crystallite size and increasing the specific surface area (from 5.8 to 25.6 m²/g), without phase transformation. Compressive strength results, relative to a reference mortar (13.6 MPa), showed comparable performance, with variations generally within ±10%, although slightly larger deviations were observed for specific particle sizes. Finer calcined particles yielded the highest strength (15.0 MPa), reinforcing the combined influence of particle size and thermal treatment. These results suggest that CaCO₃ acts primarily through a filler effect, improving particle packing and matrix interaction. Both untreated and heat-treated CaCO₃ satisfied strength requirements for non-structural applications, supporting the valorization of oyster shell waste as a sustainable material in cement-based systems.

In this paper, the gradient temperature and the thermomechanical stresses of a photovoltaic panel has been studied with and without heatsink. For this purpose, a three-dimensional analysis was carried out. Accordingly, a heat transfer analysis was developed. The numerical results show a cooling close to 26.7% with the proposed triangle fins compared with the rectangular fins studied before by another author, and the temperature distribution was determined. With this information, the stress analysis was carried out in order to find the effect on the panel due to the thermomechanical stresses. The aluminium frame was restricted to move freely. The resulting stresses field established the magnitude of the alternative stresses, resulting in a 6.7% drop compared with a reference panel. The guidelines of IEC 61215 have to be take into account. Due to the results obtained, the use of this kind of system in desert conditions is desirable because of its high operational temperature and due to the increase in heat transfer by the fins.

In this theoretical–experimental study is presented a hybridization strategy based on the application of an inverse artificial neural network model (ANNi) coupled with metaheuristic optimization algorithms to optimize the drying velocity (v_d) of an active indirect solar dryer for plantain and taro (Colocasia antiquorum). In the experimental stage, both fruits were evaluated in periods from 9:00 a.m. to 5:00 p.m. under a humid tropical climate region, varying the voltage of the air extractor fan (at 6 V, 9 V, and 12 V) to control the fan velocity. The experimental results showed that the maximum drying velocities were reached at 9 V, achieving a drying velocity of 1.5, 0.9, and 0.55 g/min, with a total drying time of 465 min for the taro, and 1.46, 1.46, and 0.36 g/min, with a total drying time of 495 min, for the plantain. As a result of the drying curves, it was observed that the drying velocity is higher in taro than in plantain. Subsequently, an artificial neural network (ANN) architecture was trained using the database generated from the solar dryer’s experimental stage. Six environmental variables and one operational variable were considered as the model’s inputs, feeding the ANN to estimate the drying velocity (v_d), obtaining a linear regression coefficient R = 0.9822 between the experimental and simulated data. A sensitivity analysis was performed to determine the impact of all the input variables. A hybrid strategy based on ANNi was developed and evaluated with three metaheuristic optimization algorithms; the best result was obtained by genetic algorithms (ANNi-GA) with an error percentage of 0.83% and an average computational time of 4.3 s. The scope of this optimization strategy was to obtain a theoretical result that allows predicting the behavior of the dryer and improving its performance for its practical application in future work through the implementation in development boards. Lastly, the optimization strategy presented is not limited to indirect solar dryers and opens a research window for evaluating other solar drying technologies.

RESUMEN Se reportan películas delgadas de ZnO y ZnO-Cu con espesores entre 220-630 nm aproximadamente y bien adheridas sobre sustratos de vidrio. La síntesis se llevó a cabo por el proceso sol gel a temperatura ambiente y depositadas mediante la técnica de centrifugado. Todas las películas de ZnO y ZnO-Cu obtenidas, presentan luminiscencia en el rango ubicado entre 520 - 550 nm con intensidades que están relacionadas al número de capas depositadas sobre el sustrato. Sin embargo, la incorporación del Cobre intensifica la emisión de fotoluminiscencia en el rango visible. La disminución en la emisión en UV del ZnO (380 nm) se atribuye a la recombinación no radiativa del proceso causado por los átomos de Cu. Por DRX, se comprobó que la incorporación de iones de Cu a la solución precursora no afectó de manera significativa la estructura cristalina de las películas (wurtzita). El análisis por espectroscopía Raman de las películas, reporta la emisión en el modo Bg y Bu' ubicado en 327 y 466 cm-1, que corresponde a CuO. Los anillos de SAED de las imágenes HRTEM de las películas de ZnO-Cu presentan difracción de CuO en el plano (020) y se corroboran los resultados mostrados en la espectroscopía Raman. Estos materiales así obtenidos, pueden tener aplicaciones en el desarrollo de dispositivos ópticos y energéticos para su uso en pantallas luminiscentes y contribuir a la generación de innovación en materiales con uso de tecnología verde.

This work shows the results obtained in the synthesis of srilankite nanoparticles, (Zr, Ti)O2, and TiO2 anatase, both catalysts presented an admix of phases, anatase/rutile, and srilankite/rutile, respectively. Their performance in the production of biodiesel through the esterification of oleic acid was evaluated. The catalysts were obtained using the sol-gel process and sulfated via the impregnation method. The samples were characterized using X-ray diffraction (XRD), scan electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and Fourier-Transform Infrared Spectroscopy (FTIR) to analyze the properties in its crystalline structure, morphology, and chemical composition. Its efficiency during the esterification reaction was measured based on the decrease in free fatty acids (FFA). FFA, oleic acid was added at different weight percentages (1%, 3%, and 5% w/w). The time of reaction was 6 hours at 55 °C and the catalyst with better performance was the sulfated Srilankite/rutile, reaching a maximum conversion of up to 90%.